GB1093507A - Crystalline disodium 4, 4'-bis(4-anilino-6-morpholino-s-triazin-2-ylamino)-2, 2'-stilbene disulphonate - Google Patents

Crystalline disodium 4, 4'-bis(4-anilino-6-morpholino-s-triazin-2-ylamino)-2, 2'-stilbene disulphonate

Info

Publication number
GB1093507A
GB1093507A GB19883/66A GB1988366A GB1093507A GB 1093507 A GB1093507 A GB 1093507A GB 19883/66 A GB19883/66 A GB 19883/66A GB 1988366 A GB1988366 A GB 1988366A GB 1093507 A GB1093507 A GB 1093507A
Authority
GB
United Kingdom
Prior art keywords
crystalline
triazin
anilino
ylamino
morpholino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19883/66A
Inventor
John William Delaney
Nathan Norman Crounce
James Clark Heath
Raymond Edmund Werner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
STWB Inc
Original Assignee
Sterling Drug Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sterling Drug Inc filed Critical Sterling Drug Inc
Publication of GB1093507A publication Critical patent/GB1093507A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
    • C07D251/68—Triazinylamino stilbenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D498/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D498/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D498/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening

Abstract

Crystalline disodium 4,41 - bis - (4 - anilino-6 - morpholino - s - triazin - 2 - ylamino) - 2,21-stilbenedisulphonate may be employed as a brightening agent in detergent compositions. In Example 5, detergent compositions described contain the above crystalline derivative or its amorphous analogue and sodium lauryl sulphate, sodium dodecylbenzene sulphonate, sodium sulphate and trisodium phosphate.ALSO:Crystalline disodium 4,41-bis(4-anilino-6-morpholino-s -triazin-2-ylamino)-2,21-stilbene disulphonate may be obtained by heating the corresponding amorphous compound at 90-200 DEG C. with 0.5-5 molar proportions of aniline or morpholine (or a mixture thereof) in an aqueous medium having an initial pH of 8 to 12 until 80-100% of the amorphous starting material is in the form of crystalline needles. The amorphous starting material may be obtained by a conventional process.ALSO:Textile materials may be treated with a composition comprising crystalline disodium 4, 4\sv -bis-(4-anilino-6-morpholino-s-triazin-2-ylamino)-2, 2\sv-stilbenedisulphonate. In example 5 white cotton swatches are treated with a detergent composition comprising the above crystalline compound or its amorphous analogue, and sodium lauryl sulphate, sodium dodecylbenzene sulphonate, sodium sulphate and trisodium phosphate; examples in which the composition also contains sodium hypochlorite are also given.
GB19883/66A 1966-05-13 1966-05-05 Crystalline disodium 4, 4'-bis(4-anilino-6-morpholino-s-triazin-2-ylamino)-2, 2'-stilbene disulphonate Expired GB1093507A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEST025395 1966-05-13

Publications (1)

Publication Number Publication Date
GB1093507A true GB1093507A (en) 1967-12-06

Family

ID=7460530

Family Applications (1)

Application Number Title Priority Date Filing Date
GB19883/66A Expired GB1093507A (en) 1966-05-13 1966-05-05 Crystalline disodium 4, 4'-bis(4-anilino-6-morpholino-s-triazin-2-ylamino)-2, 2'-stilbene disulphonate

Country Status (2)

Country Link
DE (1) DE1620488A1 (en)
GB (1) GB1093507A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3716532A (en) * 1970-04-13 1973-02-13 C Tscharner Process for preparing crystalline forms of 4,4'-bis[(4-anilino-6-morpholino-1,3,5-triazin-2-yl)-amino]-stilbene-2,2'-disulfonic acid
JPS4828033A (en) * 1971-08-14 1973-04-13
US6080208A (en) * 1996-05-23 2000-06-27 Ciba Specialty Chemicals Corporation Stilbene compounds and their use
WO2004069790A2 (en) * 2003-02-10 2004-08-19 Ciba Specialty Chemicals Holding Inc. Crystalline modifications of triazinylaminostilbenes

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3716532A (en) * 1970-04-13 1973-02-13 C Tscharner Process for preparing crystalline forms of 4,4'-bis[(4-anilino-6-morpholino-1,3,5-triazin-2-yl)-amino]-stilbene-2,2'-disulfonic acid
JPS4828033A (en) * 1971-08-14 1973-04-13
JPS5439412B2 (en) * 1971-08-14 1979-11-28
US6080208A (en) * 1996-05-23 2000-06-27 Ciba Specialty Chemicals Corporation Stilbene compounds and their use
WO2004069790A2 (en) * 2003-02-10 2004-08-19 Ciba Specialty Chemicals Holding Inc. Crystalline modifications of triazinylaminostilbenes
WO2004069790A3 (en) * 2003-02-10 2005-02-17 Ciba Sc Holding Ag Crystalline modifications of triazinylaminostilbenes
CN100358876C (en) * 2003-02-10 2008-01-02 西巴特殊化学品控股有限公司 Crystalline modifications of triazinylaminostilbenes

Also Published As

Publication number Publication date
DE1620488A1 (en) 1970-04-30

Similar Documents

Publication Publication Date Title
ES510195A0 (en) "A PROCEDURE FOR MANUFACTURING AN AQUEOUS COMPOSITION FOR THE TREATMENT OF TEXTILE MATERIALS".
ES416081A1 (en) Substantially environmental-pollution-free laundry detergent composition
ES535063A0 (en) A METHOD OF PREPARING A DETERGENT COMPOSITION
GB1069654A (en) Soap compositions
ES8203827A1 (en) Meta-phenylenediamines, dyeing compositions in which they are present and the corresponding dyeing process
GB1424047A (en) Detergent compositions
FR2364965A1 (en) BLEACHING COMPOSITION
GB1370111A (en) Quaternary ammonium benzimidazole derivatives as their use as textile treatment agents
GB1236710A (en) Stable alkali metal chlorite mixtures
GB1093507A (en) Crystalline disodium 4, 4'-bis(4-anilino-6-morpholino-s-triazin-2-ylamino)-2, 2'-stilbene disulphonate
NL83998C (en)
CO5031264A1 (en) DETERGENT BAR FOR LAUNDRY CONTAINING ALUMINUM COMPOUNDS WITH IMPROVED PHYSICAL PROPERTIES
SE8302633D0 (en) FABRIC SOFTENING COMPOSITION
US3496112A (en) Fluorescent dye compositions
GB1018857A (en) Textile treatment composition
GB1021527A (en) Improvements in or relating to stilbene-cyanuric compounds
GB1243996A (en) Halogenated amino benzothiazole derivatives and antiseptic compositions containing the same
ATE41957T1 (en) PROCESS FOR BLEACHING COTTON FABRIC WITH HYPOCHLORITE AT HIGH TEMPERATURES.
GB456727A (en) Improvements in the cleaning of carpets and like textiles
DE3065627D1 (en) Detergent composition and process for its production
RU1778171C (en) Detergent for laundering
SU525766A1 (en) Composition for softening tissue
GB884777A (en) Improvements in or relating to detergent compositions
GB624051A (en) Stilbene derivatives for use in whitening textile materials
US2740688A (en) Fixing composition