GB1093507A - Crystalline disodium 4, 4'-bis(4-anilino-6-morpholino-s-triazin-2-ylamino)-2, 2'-stilbene disulphonate - Google Patents
Crystalline disodium 4, 4'-bis(4-anilino-6-morpholino-s-triazin-2-ylamino)-2, 2'-stilbene disulphonateInfo
- Publication number
- GB1093507A GB1093507A GB19883/66A GB1988366A GB1093507A GB 1093507 A GB1093507 A GB 1093507A GB 19883/66 A GB19883/66 A GB 19883/66A GB 1988366 A GB1988366 A GB 1988366A GB 1093507 A GB1093507 A GB 1093507A
- Authority
- GB
- United Kingdom
- Prior art keywords
- crystalline
- triazin
- anilino
- ylamino
- morpholino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/54—Three nitrogen atoms
- C07D251/68—Triazinylamino stilbenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D498/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D498/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
- C07D498/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
Crystalline disodium 4,41 - bis - (4 - anilino-6 - morpholino - s - triazin - 2 - ylamino) - 2,21-stilbenedisulphonate may be employed as a brightening agent in detergent compositions. In Example 5, detergent compositions described contain the above crystalline derivative or its amorphous analogue and sodium lauryl sulphate, sodium dodecylbenzene sulphonate, sodium sulphate and trisodium phosphate.ALSO:Crystalline disodium 4,41-bis(4-anilino-6-morpholino-s -triazin-2-ylamino)-2,21-stilbene disulphonate may be obtained by heating the corresponding amorphous compound at 90-200 DEG C. with 0.5-5 molar proportions of aniline or morpholine (or a mixture thereof) in an aqueous medium having an initial pH of 8 to 12 until 80-100% of the amorphous starting material is in the form of crystalline needles. The amorphous starting material may be obtained by a conventional process.ALSO:Textile materials may be treated with a composition comprising crystalline disodium 4, 4\sv -bis-(4-anilino-6-morpholino-s-triazin-2-ylamino)-2, 2\sv-stilbenedisulphonate. In example 5 white cotton swatches are treated with a detergent composition comprising the above crystalline compound or its amorphous analogue, and sodium lauryl sulphate, sodium dodecylbenzene sulphonate, sodium sulphate and trisodium phosphate; examples in which the composition also contains sodium hypochlorite are also given.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEST025395 | 1966-05-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1093507A true GB1093507A (en) | 1967-12-06 |
Family
ID=7460530
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB19883/66A Expired GB1093507A (en) | 1966-05-13 | 1966-05-05 | Crystalline disodium 4, 4'-bis(4-anilino-6-morpholino-s-triazin-2-ylamino)-2, 2'-stilbene disulphonate |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1620488A1 (en) |
GB (1) | GB1093507A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3716532A (en) * | 1970-04-13 | 1973-02-13 | C Tscharner | Process for preparing crystalline forms of 4,4'-bis[(4-anilino-6-morpholino-1,3,5-triazin-2-yl)-amino]-stilbene-2,2'-disulfonic acid |
JPS4828033A (en) * | 1971-08-14 | 1973-04-13 | ||
US6080208A (en) * | 1996-05-23 | 2000-06-27 | Ciba Specialty Chemicals Corporation | Stilbene compounds and their use |
WO2004069790A2 (en) * | 2003-02-10 | 2004-08-19 | Ciba Specialty Chemicals Holding Inc. | Crystalline modifications of triazinylaminostilbenes |
-
1966
- 1966-05-05 GB GB19883/66A patent/GB1093507A/en not_active Expired
- 1966-05-13 DE DE19661620488 patent/DE1620488A1/en active Pending
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3716532A (en) * | 1970-04-13 | 1973-02-13 | C Tscharner | Process for preparing crystalline forms of 4,4'-bis[(4-anilino-6-morpholino-1,3,5-triazin-2-yl)-amino]-stilbene-2,2'-disulfonic acid |
JPS4828033A (en) * | 1971-08-14 | 1973-04-13 | ||
JPS5439412B2 (en) * | 1971-08-14 | 1979-11-28 | ||
US6080208A (en) * | 1996-05-23 | 2000-06-27 | Ciba Specialty Chemicals Corporation | Stilbene compounds and their use |
WO2004069790A2 (en) * | 2003-02-10 | 2004-08-19 | Ciba Specialty Chemicals Holding Inc. | Crystalline modifications of triazinylaminostilbenes |
WO2004069790A3 (en) * | 2003-02-10 | 2005-02-17 | Ciba Sc Holding Ag | Crystalline modifications of triazinylaminostilbenes |
CN100358876C (en) * | 2003-02-10 | 2008-01-02 | 西巴特殊化学品控股有限公司 | Crystalline modifications of triazinylaminostilbenes |
Also Published As
Publication number | Publication date |
---|---|
DE1620488A1 (en) | 1970-04-30 |
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