GB1085139A - Stabilization of plastics - Google Patents

Stabilization of plastics

Info

Publication number
GB1085139A
GB1085139A GB2262265A GB2262265A GB1085139A GB 1085139 A GB1085139 A GB 1085139A GB 2262265 A GB2262265 A GB 2262265A GB 2262265 A GB2262265 A GB 2262265A GB 1085139 A GB1085139 A GB 1085139A
Authority
GB
United Kingdom
Prior art keywords
hydroxy
phosphoric triamide
tris
polyvinyl chloride
oxydiethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2262265A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of GB1085139A publication Critical patent/GB1085139A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005Stabilisers against oxidation, heat, light, ozone

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Rigid polyvinyl chloride is stabilized against light by incorporating therein 0.1 to 2.0 weight per cent, based on the polymer, of each of (a) a phosphoric triamide OP(NR2)3 where R is a C1-6 alkyl group, or two R's on a single nitrogen atom together form a tetra- or penta-methylene or oxydiethylene group; and (b) an ultra-violet stabilizer selected from substituted 2-hydroxy-benzophenones, 2(2-hydroxyphenyl) benzotriazoles, phenolic esters, triazines, benzothiazoles, benzylidene malonic esters and arylaminoethylenes. Many suitable stabilizer components are listed and examples describe the stabilization of rigid polyvinyl chloride containing conventional heat stabilizers such as organotin mercaptides and optionally tridecyl phosphite, and light stabilizers comprising tris-(oxydiethylene) phosphoric triamide or hexamethyl phosphoric triamide; and 2-hydroxy-4-methoxybenzophenone, 2(2 - hydroxy - 5 - methylphenyl) benzotriazole, N-methyl-p-methoxyanilinomethylenemalonitrile, 2 - (2 - methoxyphenylimino) - 3 - ethyl benzothiazole, diphenylmethylenemalonitrile, 2,4,6 - tris - (2-hydroxy - 4 - octyloxyphenyl) - s - triazine, phenyl salicylate or diethyl p-methoxybenzylidenemalonate.
GB2262265A 1964-07-30 1965-05-27 Stabilization of plastics Expired GB1085139A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US38639664A 1964-07-30 1964-07-30
US38640064A 1964-07-30 1964-07-30
US38638364A 1964-07-30 1964-07-30
US38643364A 1964-07-30 1964-07-30

Publications (1)

Publication Number Publication Date
GB1085139A true GB1085139A (en) 1967-09-27

Family

ID=27503261

Family Applications (3)

Application Number Title Priority Date Filing Date
GB1737567A Expired GB1086677A (en) 1964-07-30 1965-05-27 Stabilisation of pvc
GB1737667A Expired GB1086678A (en) 1964-07-30 1965-05-27 Stabilisation of pvc
GB2262265A Expired GB1085139A (en) 1964-07-30 1965-05-27 Stabilization of plastics

Family Applications Before (2)

Application Number Title Priority Date Filing Date
GB1737567A Expired GB1086677A (en) 1964-07-30 1965-05-27 Stabilisation of pvc
GB1737667A Expired GB1086678A (en) 1964-07-30 1965-05-27 Stabilisation of pvc

Country Status (5)

Country Link
BE (1) BE666349A (en)
CH (1) CH469033A (en)
DE (1) DE1544618A1 (en)
GB (3) GB1086677A (en)
NL (1) NL6508885A (en)

Also Published As

Publication number Publication date
NL6508885A (en) 1966-01-31
CH469033A (en) 1969-02-28
GB1086677A (en) 1967-10-11
GB1086678A (en) 1967-10-11
DE1544618A1 (en) 1970-03-19
BE666349A (en) 1966-01-03

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