GB1079975A - Improvements in and relating to materials of high strength and resistance to molten metals and slags at elevated temperatures - Google Patents

Improvements in and relating to materials of high strength and resistance to molten metals and slags at elevated temperatures

Info

Publication number
GB1079975A
GB1079975A GB2430/65A GB243065A GB1079975A GB 1079975 A GB1079975 A GB 1079975A GB 2430/65 A GB2430/65 A GB 2430/65A GB 243065 A GB243065 A GB 243065A GB 1079975 A GB1079975 A GB 1079975A
Authority
GB
United Kingdom
Prior art keywords
phase
contain
volume
weight
slags
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2430/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Metallwerk Plansee AG
Metallwerk Plansee GmbH
Original Assignee
Metallwerk Plansee AG
Metallwerk Plansee GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AT59264A external-priority patent/AT247628B/en
Priority claimed from AT882964A external-priority patent/AT251900B/en
Application filed by Metallwerk Plansee AG, Metallwerk Plansee GmbH filed Critical Metallwerk Plansee AG
Publication of GB1079975A publication Critical patent/GB1079975A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/001Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides
    • C22C32/0015Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides with only single oxides as main non-metallic constituents
    • C22C32/0031Matrix based on refractory metals, W, Mo, Nb, Hf, Ta, Zr, Ti, V or alloys thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/041Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds for vertical casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/059Mould materials or platings
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Powder Metallurgy (AREA)

Abstract

A sintered cermet comprises W and/or Mo and an oxide ceramic phase consisting predominantly of ZrO2, the cubic phase of which is stabilized by additions such as 4 to 10% by weight of CaO or MgO. The metal phase comprises 20 to 85% by volume of the composition and may contain Cr up to 50% by weight of the metal content. The oxide phase may contain up to 50% of its volume of HfO and/or TiO2 and/or ThO2. Sintering of the compacted powders is carried out at 1700 DEG -2100 DEG C. and thermocouple sheaths, casting nozzles and tun dish stoppers may be made from the cermet.ALSO:A sintered cermet comprises W and/or Mo and an oxide ceramic phase consisting predominantly of ZrO2, the cubic phase of which is stabilized by additions such as 4 to 10% by weight of CaO or MgO. The metal phase comprises 20 to 85% by volume of the composition and may contain Cr up to 50% by weight of the metal content. The oxide phase may contain up to 50% of its volume of HfO and/or TiO2 and/or ThO2. Sintering of the compacted powders is carried out at 1700-2100 DEG C.
GB2430/65A 1964-01-27 1965-01-20 Improvements in and relating to materials of high strength and resistance to molten metals and slags at elevated temperatures Expired GB1079975A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT59264A AT247628B (en) 1964-01-27 1964-01-27 Material for parts that are exposed to the corrosive attack of metal melts, especially iron and steel melts
AT882964A AT251900B (en) 1964-10-19 1964-10-19 Heat-resistant material with high resistance to metal melts, especially iron and steel melts

Publications (1)

Publication Number Publication Date
GB1079975A true GB1079975A (en) 1967-08-16

Family

ID=25593256

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2430/65A Expired GB1079975A (en) 1964-01-27 1965-01-20 Improvements in and relating to materials of high strength and resistance to molten metals and slags at elevated temperatures

Country Status (10)

Country Link
JP (1) JPS4917847B1 (en)
BE (1) BE658761A (en)
CH (1) CH463122A (en)
DE (1) DE1483260B2 (en)
ES (1) ES308107A1 (en)
FR (1) FR1421858A (en)
GB (1) GB1079975A (en)
LU (1) LU47855A1 (en)
NL (1) NL6500524A (en)
SE (1) SE315417C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4406699A (en) * 1981-06-09 1983-09-27 Beck David E High-temperature electrically conductive ceramic composite and method for making same
GB2287252A (en) * 1994-02-24 1995-09-13 Toshiba Kk Corrosion-resistant material for contact with high temperature molten metal andmethod for production thereof.
CN113943156A (en) * 2021-12-20 2022-01-18 中南大学 Method for preparing HfO2-ThO2 ultrahigh-temperature oxide composite ceramic in large scale

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103926013A (en) * 2013-01-15 2014-07-16 宝山钢铁股份有限公司 Protective sleeve of high-temperature thermocouple for sintering

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4406699A (en) * 1981-06-09 1983-09-27 Beck David E High-temperature electrically conductive ceramic composite and method for making same
GB2287252A (en) * 1994-02-24 1995-09-13 Toshiba Kk Corrosion-resistant material for contact with high temperature molten metal andmethod for production thereof.
US5590392A (en) * 1994-02-24 1996-12-31 Kabushiki Kaisha Toshiba Corrosion-resistant material for contact with high temperature molten metal and method for production thereof
GB2287252B (en) * 1994-02-24 1998-04-29 Toshiba Kk Corrosion-resistant material for contact with high temperature molten metal and method for production thereof
CN113943156A (en) * 2021-12-20 2022-01-18 中南大学 Method for preparing HfO2-ThO2 ultrahigh-temperature oxide composite ceramic in large scale
CN113943156B (en) * 2021-12-20 2022-05-17 中南大学 Method for preparing HfO2-ThO2 ultrahigh-temperature oxide composite ceramic in large scale

Also Published As

Publication number Publication date
FR1421858A (en) 1965-12-17
ES308107A1 (en) 1965-06-16
SE315417C (en) 1974-11-07
CH463122A (en) 1968-09-30
BE658761A (en) 1965-05-17
SE315417B (en) 1969-09-29
LU47855A1 (en) 1965-05-26
DE1483260A1 (en) 1971-03-04
NL6500524A (en) 1965-07-28
DE1483260B2 (en) 1971-03-04
JPS4917847B1 (en) 1974-05-04

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