GB1079863A - Process for the production of hydrogen-containing gases and a catalyst for use in carrying out such process - Google Patents

Process for the production of hydrogen-containing gases and a catalyst for use in carrying out such process

Info

Publication number
GB1079863A
GB1079863A GB1612866A GB1612866A GB1079863A GB 1079863 A GB1079863 A GB 1079863A GB 1612866 A GB1612866 A GB 1612866A GB 1612866 A GB1612866 A GB 1612866A GB 1079863 A GB1079863 A GB 1079863A
Authority
GB
United Kingdom
Prior art keywords
gas
catalyst
less
produced
kcal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1612866A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Heinrich Koppers GmbH
Original Assignee
Heinrich Koppers GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Heinrich Koppers GmbH filed Critical Heinrich Koppers GmbH
Publication of GB1079863A publication Critical patent/GB1079863A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts

Abstract

Hydrogen containing gas is made by catalytically enacting petroleum hydrocarbons and steam at elevated pressure using externally heated tubes filled with catalyst having the following characteristics: Ni, 30 to 45%, MgO less than 1%, alkali metal oxides less than 0.5%, Al2O3 more than 40%; CaO, 5 to 8%, surface area more than 20 m2/gm., the process being effected with catalyst ratings of up to 2 Kg. hydrocarbons per like catalyst per hour, whereby a gas is produced, the CH4 content of which is adjustable between less than 1 vol. per cent and 55 vol. per cent solely by varying the hydrocarbon vapour/steam ratio and the outlet temperature of the gas, both as a function of the pressure used. In Example 2 a gas containing 0.8% CH4 and 71.5% H2 is produced; in Example 3 a gas having a calorific value of 4650 Kcal Nm3 containing 33.2% CH4 and 41.2% H2 is produced. In Example 4 a gas is produced which after subjection to a CO2 wash and CO methanization yields a product with a calorific value of 8050 Kcal/Nm3.ALSO:Cracking catalysts comprise 30-45% mi, less than 1% MgO, less than 0.5% alkali metal oxides, more than 40% Al2O3, 5-8% CaO, the catalyst having a surface area of more than 20m2/gm.
GB1612866A 1965-05-28 1966-05-27 Process for the production of hydrogen-containing gases and a catalyst for use in carrying out such process Expired GB1079863A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEK56247A DE1282834B (en) 1965-05-28 1965-05-28 Process for generating hydrogen-containing gases, the methane content of which can be set in the range between less than 1 and 55 percent by volume, by catalytic conversion of gasoline hydrocarbons containing less than 1 ppm of sulfur with water vapor under increased pressure

Publications (1)

Publication Number Publication Date
GB1079863A true GB1079863A (en) 1967-08-16

Family

ID=7227772

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1612866A Expired GB1079863A (en) 1965-05-28 1966-05-27 Process for the production of hydrogen-containing gases and a catalyst for use in carrying out such process

Country Status (2)

Country Link
DE (1) DE1282834B (en)
GB (1) GB1079863A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2415601A1 (en) * 1978-01-27 1979-08-24 Toyo Engineering Corp PROCESS FOR PREPARING GAS FROM HEAVY OILS

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB939213A (en) * 1959-01-26 1963-10-09 Chemetron Corp Method of making a nickel-magnesium hydrocarbon-steam reforming catalyst
FR1334081A (en) * 1962-09-11 1963-08-02 Ici Ltd Catalytic compositions for use in the steam reforming of hydrocarbons
DE1252181B (en) * 1963-05-10 1967-10-19 Imperial Chemical Industries Limited, London Process for reducing the leachability of the alkali or alkaline earth component in a catalyst useful for steam reforming

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2415601A1 (en) * 1978-01-27 1979-08-24 Toyo Engineering Corp PROCESS FOR PREPARING GAS FROM HEAVY OILS

Also Published As

Publication number Publication date
DE1282834B (en) 1968-11-14

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