GB1077454A - Process for the oxidation of cycloalkanes - Google Patents

Process for the oxidation of cycloalkanes

Info

Publication number
GB1077454A
GB1077454A GB27700/63A GB2770063A GB1077454A GB 1077454 A GB1077454 A GB 1077454A GB 27700/63 A GB27700/63 A GB 27700/63A GB 2770063 A GB2770063 A GB 2770063A GB 1077454 A GB1077454 A GB 1077454A
Authority
GB
United Kingdom
Prior art keywords
oxidation
cycloalkanes
ester
borate ester
cycloalkanols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27700/63A
Inventor
Cyril Gardner
John Fraser Prescott
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB27700/63A priority Critical patent/GB1077454A/en
Priority to NL6407917A priority patent/NL6407917A/xx
Priority to FR981574A priority patent/FR1405545A/en
Publication of GB1077454A publication Critical patent/GB1077454A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/316—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with oxides of nitrogen or nitrogen-containing mineral acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process for the liquid phase oxidation of cycloalkanes to product mixtures containing cycloalkanols with gases containing molecular oxygen is characterized in that a borate ester of an alcohol corresponding to the cycloalkane is introduced into the reaction zone before or during the oxidation, such ester being formed outside the oxidation zone. An example describes the production of cyclohexanol from cyclohexane, the borate ester being cyclohexyl metaborate.
GB27700/63A 1963-07-12 1963-07-12 Process for the oxidation of cycloalkanes Expired GB1077454A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB27700/63A GB1077454A (en) 1963-07-12 1963-07-12 Process for the oxidation of cycloalkanes
NL6407917A NL6407917A (en) 1963-07-12 1964-07-10
FR981574A FR1405545A (en) 1963-07-12 1964-07-10 Process for the oxidation of cycloalkanes using gases containing molecular oxygen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB27700/63A GB1077454A (en) 1963-07-12 1963-07-12 Process for the oxidation of cycloalkanes

Publications (1)

Publication Number Publication Date
GB1077454A true GB1077454A (en) 1967-07-26

Family

ID=10263873

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27700/63A Expired GB1077454A (en) 1963-07-12 1963-07-12 Process for the oxidation of cycloalkanes

Country Status (2)

Country Link
GB (1) GB1077454A (en)
NL (1) NL6407917A (en)

Also Published As

Publication number Publication date
NL6407917A (en) 1965-01-13

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