GB1076760A - Process for the treatment of textiles or paper and other products of the paper making system with aminoplasts - Google Patents

Process for the treatment of textiles or paper and other products of the paper making system with aminoplasts

Info

Publication number
GB1076760A
GB1076760A GB32440/64A GB3244064A GB1076760A GB 1076760 A GB1076760 A GB 1076760A GB 32440/64 A GB32440/64 A GB 32440/64A GB 3244064 A GB3244064 A GB 3244064A GB 1076760 A GB1076760 A GB 1076760A
Authority
GB
United Kingdom
Prior art keywords
acid
salt
aminoplast
sulphate
acetate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB32440/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
West Point Manufacturing Co
Original Assignee
West Point Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by West Point Manufacturing Co filed Critical West Point Manufacturing Co
Publication of GB1076760A publication Critical patent/GB1076760A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423Amino-aldehyde resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paper (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

Aminoplasts applied to textile materials and paper from an aqueous liquid are cured on the treated material in the presence of a curing agent which is a synergistic mixture of at least one acid having a dissociation constant greater than 10-6 and at least one salt which shows an acid reaction in aqueous medium and which is a salt of ammonia, an amine or a metal with an inorganic or organic acid, by heating the treated material to an elevated temperature so that curing is effected before the treated material is dried. The aminoplast may be a condensate of formaldehyde with melamine, aguanamine, urea, ethylene urea, propylene urea, thiourea, guanidine, biuret, dicyandiamide, ureas, ethylene imine or propylene imine and may be etherified with methyl or ethyl alcohol. The acid may be formic, sulphamic, glycolic, oxalic, citric, diglycolic, tartaric, sulphurous or orthophosphoric acid and the salt may be of hydrochloric, sulphuric, thiosulphuric, sulphurous, sulphamic, phosphoric, phosphorous, fluoboric, nitric, nitrous, carboxylic or sulphonic acids, e.g. ammonium chloride, sulphate, sulphite, bisulphite, thiosulphate, phosphates, sulphamate, nitrate, acetate and citrate, 2-aminopropanol hydrochloride, magnesium chloride, sulphate and dihydrogen phosphate, aluminium chloride, acetate or sulphate, zinc chloride, acetate, nitrate and fluoborate and calcium, barium, ferric, stannic and chromic chlorides. The treating composition may also contain water repellents, e.g. fatty derivatives of melamine formaldehyde resins, fire retardants, hand modifiers, softeners, wetting agents, e.g. polyethylene oxide condensates of nonyl phenol, epoxidized triglyceride, dyes, pigments or agents imparting resistance to biological growth and actinic degradation. In examples melamine formaldehyde resins are used in conjunction with MgCl2 or Zn fluoborate and formic or citric acid, and optionally polyethoxylated nonyl phenol and/or an epoxidized triglyceride.ALSO:Textiles, paper and other products of the paper making system, i.e. paperboard, cardboard and tissue are shrinkproofed, and creaseproofed by impregnating them with an aqueous liquid containing at least one aminoplast precondensate and treating them with a curing agent comprising a synergistic mixture of at least one acid having a dissociation constant greater than 10-6 and at least one salt which shows an acid reaction in aqueous medium and which is a salt of ammonia, an amine or a metal with an inorganic or organic acid, and curing the aminoplast by heating to an elevated temperature before the treated material has dried. The aminoplast may be a condensate of an formaldehyde with melamine, a guanamine, urea, ethylene urea, propylene urea, thiourea, guanidine, biuret, dicyandiamide, urons, ethylene imine or propylene imine and may be etherified with methyl or ethyl alcohol. The acid may be formic, sulphamic, glycolic, oxalic, citric, diglycolic, tartaric, sulphurous or orthophosphoric and the salt may be an ammonium, amine or metal salt of hydrochloric, sulphuric, thiosulphuric, sulphurous, sulphamic, phosphoric, phosphorous, fluoboric, nitric, nitrous, carboxylic or sulphonic acids, e.g. ammonium chloride, sulphate, sulphite, bisulphite, thiosulphate, phosphates, sulphamate, nitrate, acetate and citrate, 2-aminopropanol hydrochloride, magnesium chloride, sulphate and dihydrogen phosphate, aluminium chloride, acetate or sulphate, zinc chloride, acetate, nitrate and fluoborate and calcium, barium, ferric, stannic and chromic chlorides. The aminoplast precondensate, salt and acid may be applied to the material treated from the same aqueous solution or separately, either the salt or acid being applied with the aminoplast precondensate or the salt and acid being applied after the aminoplast precondensate. The aminoplast may be cured by steaming for from 15 seconds to 5 minutes, by drying at 220 DEG - 250 DEG F or by holding the treated material in the wet state at for example 90 DEG - 100 DEG F for three hours if desired while covered with a polyethylene cover. After curing the treated material may be washed with water which may contain a surface active agent and subjected to a dry curing step in the presence of ammonium, amine, magnesium, aluminium or zinc salts of hydrochloric, phosphoric, sulphuric, nitric or fluoroboric acids. The treating solutions may also contain water repellents e.g. fatty derivatives of melamine-formaldehyde resins, fire retardants, hand modifiers, softeners, wetting agents, e.g. polyethylene oxide condensates of nonyl phenol, epoxidized triglyceride, dyes, pigments or agents imparting resistance to biological growth and actinic degradation. Yarns may be given stretch properties by wet fixation of an aminoplast in and on the highly twisted yarn followed by backtwisting of the treated yarns. Woven, non woven and knitted fabrics and yarns, threads and staple fibres in the form of spun, twisted or braided fibres roving, slivers, laps or bulk fibres of cotton, regenerated cellulose, wool, polyamide, polyester, polyolefin or acrylic fibres may be treated. The process is applicable to the treatment of towelling and fabric comprising yarns composed of a core of polyamide fibre covered with cotton. Colour may be developed in the treated materials by the use of ferric chloride in the aminoplast solution and an alkaline wash following fixation which precipitates an insoluble coloured iron compound.ALSO:A catalytic composition used in the curing of aminoplasts on textile materials and paper comprises a synergistic mixture of at least one acid having a dissociation constant greater than 10-6 and at least one salt which shows an acid reaction in aqueous medium and is a salt of ammonia, an amine or a metal with an inorganic or organic acid. The acid may be formic, sulphamic, glycolic, oxalic, citric, diglycolic, tartaric, sulphurous or orthophosphoric acid and the salt may be of hydrochloric, sulphuric, thiosulphuric, sulphurous, sulphamic, phosphoric, phosphorous, fluoboric, nitric, nitrous, carboxylic or sulphonic acids, e.g. ammonium chloride sulphate, sulphite, bisulphite, thiosulphate, phosphates, sulphamate, nitrate, acetate and citrate, 2-aminopropanol hydrochloride, magnesium chloride, sulphate and dihydrogen phosphate, aluminium chloride, acetate or sulphate, zinc chloride, acetate, nitrate and fluoborate and calcium, barium, ferric, stannic and chromic chlorides.ALSO:Textiles paper and other products of the paper making system, i.e. paperboard, cardboard and tissue, are rendered resistant to attack by bacteria by impregnating them with an aqueous liquid containing at least one aminoplast precondensate and treating them with a curing agent comprising a synergistic mixture of at least one acid having a dissociation constant greater than 10-6 and at least one salt which shows an acid reaction in aqueous medium and which is a salt of ammonia, an amine or a metal with an inorganic or organic acid, and curing the aminoplast by heating to an elevated temperature before the treated material is dried. The aminoplast may be a condensate of an formaldehyde with melamine, a guanamine, urea, ethylene urea, propylene urea, thiourea, guanidine, biuret, dicyandiamide, urons, ethylene imine or propylene imine and may be etherified with methyl or ethyl alcohol. The acid may be formic, sulphamic, glycolic, oxalic, citric, diglycolic, tartaric, sulphurous or orthophosphoric and the salt may be an ammonium, amine or metal salt of hydrochloric, sulphuric, thiosulphuric, sulphurous, sulphamic, phosphoric, phosphorous, fluoboric, nitric, nitrous, carboxylic or sulphonic acids, e.g. ammonium chloride, sulphate, sulphite, bisulphite, thiosulphate, phosphates, sulphamate, nitrate, acetate and citrate, 2-aminopropanol hydrochloride, magnesium chloride, sulphate and dihydrogen phosphate, aluminium chloride, acetate or sulphate, zinc chloride, acetate, nitrate and fluoborate and calcium, barium, ferric, stannic and chromic chlorides. The aminoplast precondensate, salt and acid may be applied to the material treated from the same aqueous solution or separately, either the salt or acid being applied with the aminoplast precondensate or the salt and acid being applied after the aminoplast precondensate. The aminoplast may be cured by steaming for from 15 seconds to 5 minutes, by drying at 220 DEG -250 DEG F or by holding the treated material in the wet state at for example 90 DEG -100 DEG F for three hours if desired while covered with a polyethylene cover. After curing the treated material may be washed with water which may contain a surface active agent and subjected to a dry curing step in the presence of ammonium, amine, magnesium, aluminium or zinc salts of hydrochloric, phosphoric, sulphuric, nitric or fluoroboric acids. The treating solution may also contain water repellents, e.g. fatty derivatives of melamineformaldehyde resins. Woven, non woven and knitted fabrics and yarns, threads and staple fibres in the form of spun, twisted or braided fibres roving, slivers, laps or bulk fibres of cotton, regenerated cellulose, wool, polyamide, polyester, polyolefin or acrylic fibres may be treated.
GB32440/64A 1963-08-14 1964-08-10 Process for the treatment of textiles or paper and other products of the paper making system with aminoplasts Expired GB1076760A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US30195263A 1963-08-14 1963-08-14

Publications (1)

Publication Number Publication Date
GB1076760A true GB1076760A (en) 1967-07-19

Family

ID=23165621

Family Applications (1)

Application Number Title Priority Date Filing Date
GB32440/64A Expired GB1076760A (en) 1963-08-14 1964-08-10 Process for the treatment of textiles or paper and other products of the paper making system with aminoplasts

Country Status (11)

Country Link
JP (1) JPS4930877B1 (en)
AT (1) AT303672B (en)
BE (1) BE651769A (en)
CH (2) CH1013964A4 (en)
DE (1) DE1469504A1 (en)
ES (1) ES303452A1 (en)
FR (1) FR1517679A (en)
GB (1) GB1076760A (en)
NL (1) NL6409366A (en)
NO (1) NO123605B (en)
SE (1) SE324551B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111115784A (en) * 2020-01-10 2020-05-08 杨琼 Degradation agent for degrading nitrite in aquaculture water by using compound nitrification inhibitor and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1248840A (en) * 1968-10-03 1971-10-06 Cotton Inc Wet fixation of resins in fiber systems for durable press products

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111115784A (en) * 2020-01-10 2020-05-08 杨琼 Degradation agent for degrading nitrite in aquaculture water by using compound nitrification inhibitor and preparation method thereof

Also Published As

Publication number Publication date
ES303452A1 (en) 1965-02-01
FR1517679A (en) 1968-03-22
DE1469504A1 (en) 1970-07-30
SE324551B (en) 1970-06-08
CH542955A (en) 1973-03-15
AT303672B (en) 1972-12-11
JPS4930877B1 (en) 1974-08-16
NL6409366A (en) 1965-02-15
BE651769A (en) 1964-12-01
NO123605B (en) 1971-12-20
CH1013964A4 (en) 1973-03-15

Similar Documents

Publication Publication Date Title
GB890515A (en) Preventing odours in filamentary or sheet material treated with thermosetting aldehyde resins
US2530261A (en) Fireproofing and creaseproofing of cellulose and protein textiles
US3138802A (en) Process for imparting durable creases, wrinkle resistance and shape retention to cellulosic textile articles
US2441859A (en) Treatment of textile materials with aldehydes
US2846337A (en) Magnesium chloride catalyst for modified urea resins
US2898238A (en) Process for treating textiles with ethylene urea-formaldehyde reaction products
US2828228A (en) Textile fire retardant treatment
US3374107A (en) Process for the treatment of textiles with aminoplasts
GB1076760A (en) Process for the treatment of textiles or paper and other products of the paper making system with aminoplasts
GB842402A (en) Process for fixing aminoplasts in the wet state on fibrous materials
US2602018A (en) Monomethylol dimethyl hydantoin and dimethylol urea to shrinkproof and creaseproof cellulose fabrics
US3128147A (en) Process for treating polynosic fibers and products obtained thereby
US3039167A (en) Method for improving the properties of fabrics containing cross-linked regenerated cellulose material
GB871105A (en) Improvements in the incorporation of thermosetting synthetic resins in linen textilefabrics
US3709716A (en) Wet fixation of modifying agents on fibrous systems by heating in aqueous salt solution
US2484599A (en) Process of reducing the shrinkage and felting tendencies of protein textile materials
GB932810A (en) Improvements in the treatment of highly crystalline regenerated cellulose fibres
GB1069644A (en) Improvements in or relating to the treatment of polypyrrolidone fibres
US3043718A (en) Compositions, textiles treated therewith, and processes for the treatment thereof
JP2000096442A (en) Finishing of cellulosic textile fabric
GB968534A (en) Improvements in or relating to means for imparting durable pleats, creases or other predetermined deformations in slivers yarns or fabrics consisting of or containing wool or other keratinous fibres
GB938989A (en) Insolubilisation of further-polymerisable methylol-phosphorus polymeric materials
US3617192A (en) Crosslinking of cellulosic materials with products produced by the reaction of alkyl sulfonamides and formaldehyde under alkaline conditions
US2091567A (en) Noncrumpling fabric and process of making the same
US2702258A (en) Hydrous oxide containing resinous compositions