GB932810A - Improvements in the treatment of highly crystalline regenerated cellulose fibres - Google Patents
Improvements in the treatment of highly crystalline regenerated cellulose fibresInfo
- Publication number
- GB932810A GB932810A GB4119661A GB4119661A GB932810A GB 932810 A GB932810 A GB 932810A GB 4119661 A GB4119661 A GB 4119661A GB 4119661 A GB4119661 A GB 4119661A GB 932810 A GB932810 A GB 932810A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formaldehyde
- regenerated cellulose
- resin
- agent
- methylol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004627 regenerated cellulose Substances 0.000 title abstract 11
- 229920003043 Cellulose fiber Polymers 0.000 title abstract 4
- 238000011282 treatment Methods 0.000 title abstract 4
- 229920005989 resin Polymers 0.000 abstract 12
- 239000011347 resin Substances 0.000 abstract 12
- 239000003795 chemical substances by application Substances 0.000 abstract 11
- 239000003431 cross linking reagent Substances 0.000 abstract 9
- -1 1,2-propylene ureas Chemical class 0.000 abstract 6
- 230000008961 swelling Effects 0.000 abstract 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 5
- 229920000877 Melamine resin Polymers 0.000 abstract 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 239000004744 fabric Substances 0.000 abstract 3
- VGGLHLAESQEWCR-UHFFFAOYSA-N N-(hydroxymethyl)urea Chemical class NC(=O)NCO VGGLHLAESQEWCR-UHFFFAOYSA-N 0.000 abstract 2
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 2
- 229920003180 amino resin Polymers 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 235000013877 carbamide Nutrition 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 2
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 abstract 2
- QYXHJMXBZWOTJN-UHFFFAOYSA-N formaldehyde;guanidine Chemical compound O=C.NC(N)=N QYXHJMXBZWOTJN-UHFFFAOYSA-N 0.000 abstract 2
- XVVGGZUZOITHPH-UHFFFAOYSA-N formaldehyde;prop-2-enal Chemical compound O=C.C=CC=O XVVGGZUZOITHPH-UHFFFAOYSA-N 0.000 abstract 2
- YIBPLYRWHCQZEB-UHFFFAOYSA-N formaldehyde;propan-2-one Chemical compound O=C.CC(C)=O YIBPLYRWHCQZEB-UHFFFAOYSA-N 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000000314 lubricant Substances 0.000 abstract 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 2
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- 239000005871 repellent Substances 0.000 abstract 2
- 230000002940 repellent Effects 0.000 abstract 2
- 229920002050 silicone resin Polymers 0.000 abstract 2
- HVTHJRMZXBWFNE-UHFFFAOYSA-J sodium zincate Chemical compound [OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Zn+2] HVTHJRMZXBWFNE-UHFFFAOYSA-J 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- 238000009988 textile finishing Methods 0.000 abstract 2
- 235000005074 zinc chloride Nutrition 0.000 abstract 2
- 239000011592 zinc chloride Substances 0.000 abstract 2
- 229920000742 Cotton Polymers 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 abstract 1
- 229920000297 Rayon Polymers 0.000 abstract 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 239000010446 mirabilite Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000004745 nonwoven fabric Substances 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
- 238000009987 spinning Methods 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
- D06M11/40—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table combined with, or in absence of, mechanical tension, e.g. slack mercerising
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Abstract
Never dried regenerated cellulose fibres having a degree of crystallinity above 50% are treated whilst under tension first with a swelling agent for the regenerated cellulose and then with a cross-linking agent for the regenerated cellulose. The swelling agent, which is preferably applied at a temperature of 15 DEG -40 DEG C. for 15-50 seconds at a concentration of 5-80% by weight, may be an alkali metal hydroxide, zinc chloride or sodium zincate. The cross-linking agent may be formaldehyde, a "reactant type" resin, e.g. methylated methylol urea, N-methylol-N-alkyl triazones, N-methylol-N-alkyl melamines and methylated or unmethylated methylol ethylene-or 1,2-propylene ureas, an aminoplast resin precondensate, e.g. urea-formaldehyde, melamine-formaldehyde, dicyandiamide-formaldehyde and guanidine-formaldehyde condensates and combinations thereof and methylol-amineepihalohydrin compounds, a formaldehyde-acrolein resin, an acetone-formaldehyde resin or a polyepoxy resin. The cross-linking agent may be applied as an aqueous solution or dispersion containing 4-25% by weight of the agent, 10-50% of a catalyst based on the weight of the agent and other textile finishing agents, e.g. hand builders, lubricants and water repellents such as silicone resins. After treatment with the cross-linking agent the fibres may be squeezed and dried at a temperature below 100 DEG C. for 20 seconds-2 hours and, when a heat hardenable resin is used, cured by heating. The regenerated cellulose fibres having a degree of crystallinity above 50% may be produced by spinning unaged viscose into a zinc-free bath containing less than 30 g./l. H2SO4 and less than 50 g./l. Glaubers salt at a temperature below 30 DEG C. and drawing the fibres produced in the bath at a progressively increasing speed until regeneration is complete. Specifications 730,226, 732,573, 796,815, 872,656, 878,655 and 930,132 are referred to.ALSO:The dimensional stability of textile fibres of regenerated cellulose having a degree of crystallinity above 50% is improved by treating them under tension first with a swelling agent for the regenerated cellulose and then with a cross linking agent for the regenerated cellulose. The swelling agent, which is preferably applied at a temperature of 15 DEG -40 DEG C. for 15-50 seconds at a concentration of 5-80% by weight, may be an alkali metal hydroxide, zinc chloride or sodium zincate. The cross-linking agent may be formaldehyde, a "reactant type" resin, e.g. methylated methylol urea, N-methylol, N-alkyl triazones, N-methylol, N-alkyl melamines and methylated or unmethylated methylol ethyleneor 1,2-propylene ureas, an aminoplast resin precondensate, e.g. urea formaldehyde, melamine formaldehyde, dicyandiamide-formaldehyde and guanidine-formaldehyde condensates and combustions thereof and methylol-amino-epihalo-hydrin compounds, a formaldehyde-acrolein resin, an acetone-formaldehyde resin or a polyepoxy resin. The cross-linking agent may be applied as an aqueous solution or dispersion containing 4-25% by weight of the agent, 10-50% of a catalyst based on the weight of the agent and other textile finishing agents, e.g. hand builders, lubricants and water repellents such as silicone resins. After treatment with the crosslinking agent the fibres may be squeezed and dried at a temperature below 100 DEG C. for 20 seconds-2 hours and, when a heat hardenable resin is used, cured by heating. Between the swelling and cross-linking treatments the fibres may be washed, dried and processed, e.g. made up into yarn, fabric or garments, or "Sanforized" (Registered Trade Mark). Continuous filaments, yarns or woven, knitted or non-woven fabrics made wholly from the highly crystalline regenerated cellulose or from blends containing at least 50% by weight of the highly crystalline regenerated cellulose with cotton, nylon, polyester, acrylic, polyethylene or polypropylene fibres or up to 15% by weight of normal regenerated cellulose fibre may be treated. As shown in the drawing, fabric 1 may be passed through a bath 3 containing the swelling agent to a stenter frame 9 where it is sprayed with water from spray heads 10 and 11 while it is stretched in the direction of the welt. It is then passed through a water bath 14, an acid bath 17 containing a weak acid, e.g. 0,5%-1,5% acetic acid and a water bath 20 to bath 25 where it is treated while still under tension with a solution of the cross-linking agent. Excess solution is removed by squeeze rollers 28 and the fabric is then dried and if desired cured by passage through oven 29. Specifications 730,226, 732,573, 796,815, 872,656, 878,655 and 930,132 are referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US70247A US3128147A (en) | 1959-09-30 | 1960-11-18 | Process for treating polynosic fibers and products obtained thereby |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB932810A true GB932810A (en) | 1963-07-31 |
Family
ID=22094107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4119661A Expired GB932810A (en) | 1960-11-18 | 1961-11-17 | Improvements in the treatment of highly crystalline regenerated cellulose fibres |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE610457A (en) |
| CH (1) | CH1339261D (en) |
| GB (1) | GB932810A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008000828A1 (en) * | 2006-06-30 | 2008-01-03 | Momentive Performance Materials Gmbh & Co. Kg | Method for producing cellulose fibers with reduced crystallinity |
| WO2009102913A3 (en) * | 2008-02-15 | 2010-07-15 | Playtex Products, Llc | Tampon including crosslinked cellulose fibers and improved synthesis processes for producing same |
-
0
- CH CH1339261D patent/CH1339261D/xx unknown
-
1961
- 1961-11-17 GB GB4119661A patent/GB932810A/en not_active Expired
- 1961-11-17 BE BE610457A patent/BE610457A/en unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008000828A1 (en) * | 2006-06-30 | 2008-01-03 | Momentive Performance Materials Gmbh & Co. Kg | Method for producing cellulose fibers with reduced crystallinity |
| WO2009102913A3 (en) * | 2008-02-15 | 2010-07-15 | Playtex Products, Llc | Tampon including crosslinked cellulose fibers and improved synthesis processes for producing same |
| CN101938964A (en) * | 2008-02-15 | 2011-01-05 | 普拉泰克斯产品有限公司 | The improvement synthetic method that comprises the cotton sliver of cross-linked cellulose fibres and be used to produce these cross-linked cellulose fibres |
| CN103173881A (en) * | 2008-02-15 | 2013-06-26 | 普拉泰克斯产品有限公司 | Method for forming crosslinked cellulose fibers |
| CN103173881B (en) * | 2008-02-15 | 2015-09-16 | 倍得适产品有限责任公司 | For the formation of the method for cross-linked cellulose fibres |
Also Published As
| Publication number | Publication date |
|---|---|
| CH1339261D (en) | |
| BE610457A (en) | 1962-03-16 |
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