GB1075305A - Liquid aluminium chloride catalyst - Google Patents

Liquid aluminium chloride catalyst

Info

Publication number
GB1075305A
GB1075305A GB52641/64A GB5264164A GB1075305A GB 1075305 A GB1075305 A GB 1075305A GB 52641/64 A GB52641/64 A GB 52641/64A GB 5264164 A GB5264164 A GB 5264164A GB 1075305 A GB1075305 A GB 1075305A
Authority
GB
United Kingdom
Prior art keywords
ester
specified
octadecene
decene
olefines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB52641/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of GB1075305A publication Critical patent/GB1075305A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/125—Halogens; Compounds thereof with scandium, yttrium, aluminium, gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/60—Catalytic processes with halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C07C2527/126—Aluminium chloride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Olefines are polymerized in the presence of a liquid catalyst comprising aluminium halide and an aliphatic ester containing 4 or more carbon atoms per mol such that the ratio AlX3/ester > 1/1. Specified olefines are ethylene, butene-1, isobutene, hexene, octene-2, 2-ethylhexene-1, decene-2, decene-1, undecene-1, dodecene-1, hexadecene-1, octadecene-1, octadecene-9, eicosene, tricosene-1, tetracosene-1 and triacontene-1.ALSO:A polymerisation catalyst comprises a normally liquid aliphatic ester of a fatty acid containing a total of at least 4C per ester molecule having dissolved therein more than 1 mole of aluminium halide per mole of ester. AlCl3, AlBr3, AlI3 and AlF3 are all specified, the first mentioned being preferred. Specified esters are ethyl acetate, ethyl propionate, ethyl palmitate, butyl oleate, and methyl caprylate.
GB52641/64A 1963-12-30 1964-12-29 Liquid aluminium chloride catalyst Expired GB1075305A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US33439463A 1963-12-30 1963-12-30

Publications (1)

Publication Number Publication Date
GB1075305A true GB1075305A (en) 1967-07-12

Family

ID=23307004

Family Applications (1)

Application Number Title Priority Date Filing Date
GB52641/64A Expired GB1075305A (en) 1963-12-30 1964-12-29 Liquid aluminium chloride catalyst

Country Status (3)

Country Link
DE (1) DE1520900C3 (en)
FR (1) FR1433373A (en)
GB (1) GB1075305A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2552337A1 (en) * 1974-12-03 1976-06-16 Lion Fat Oil Co Ltd METHOD FOR MANUFACTURING LIQUID POLYOLEFINS
DE2616146A1 (en) * 1975-04-15 1976-10-28 Lion Fat Oil Co Ltd Process for the preparation of olefin oligomers
DE2617403A1 (en) * 1975-04-22 1976-11-04 Lion Fat Oil Co Ltd PROCESS FOR PRODUCING LIQUID POLYOLEFINO OILS
DE2633745A1 (en) * 1975-07-29 1977-02-10 Lion Fat Oil Co Ltd METHOD FOR PRODUCING POLYOLEFINOELS
DE2633710A1 (en) * 1975-07-29 1977-02-24 Lion Fat Oil Co Ltd METHOD FOR PRODUCING POLYOLEFINOELS
DE2837235A1 (en) * 1977-08-31 1979-03-08 Lion Fat Oil Co Ltd METHOD OF MANUFACTURING OLEFINOLIGOMERS AND THE CATALYST USED THEREOF
US4650917A (en) * 1985-08-19 1987-03-17 Mobil Oil Corporation Method for upgrading olefinic lubes

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3725498A (en) * 1963-12-30 1973-04-03 Mobil Oil Corp Recyclable liquid aluminum chloride and bromide complexes
GB1388224A (en) * 1972-09-08 1975-03-26 Mobil Oil Corp Aluminium halide-carboxylic acid ester catalysts

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2552337A1 (en) * 1974-12-03 1976-06-16 Lion Fat Oil Co Ltd METHOD FOR MANUFACTURING LIQUID POLYOLEFINS
DE2616146A1 (en) * 1975-04-15 1976-10-28 Lion Fat Oil Co Ltd Process for the preparation of olefin oligomers
DE2617403A1 (en) * 1975-04-22 1976-11-04 Lion Fat Oil Co Ltd PROCESS FOR PRODUCING LIQUID POLYOLEFINO OILS
DE2633745A1 (en) * 1975-07-29 1977-02-10 Lion Fat Oil Co Ltd METHOD FOR PRODUCING POLYOLEFINOELS
DE2633710A1 (en) * 1975-07-29 1977-02-24 Lion Fat Oil Co Ltd METHOD FOR PRODUCING POLYOLEFINOELS
DE2837235A1 (en) * 1977-08-31 1979-03-08 Lion Fat Oil Co Ltd METHOD OF MANUFACTURING OLEFINOLIGOMERS AND THE CATALYST USED THEREOF
US4650917A (en) * 1985-08-19 1987-03-17 Mobil Oil Corporation Method for upgrading olefinic lubes

Also Published As

Publication number Publication date
DE1520900A1 (en) 1970-04-30
FR1433373A (en) 1966-04-01
DE1520900B2 (en) 1977-11-10
DE1520900C3 (en) 1978-07-13

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