GB1148966A - Liquid olefins of high molecular weight obtained by polymerisation of propylene - Google Patents

Liquid olefins of high molecular weight obtained by polymerisation of propylene

Info

Publication number
GB1148966A
GB1148966A GB3485367A GB3485367A GB1148966A GB 1148966 A GB1148966 A GB 1148966A GB 3485367 A GB3485367 A GB 3485367A GB 3485367 A GB3485367 A GB 3485367A GB 1148966 A GB1148966 A GB 1148966A
Authority
GB
United Kingdom
Prior art keywords
propylene
high molecular
molecular weight
polymerisation
weight obtained
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3485367A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1148966A publication Critical patent/GB1148966A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C07C2/70—Catalytic processes with acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/10—Chlorides
    • C07C2527/11—Hydrogen chloride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/12—Fluorides
    • C07C2527/1213—Boron fluoride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C07C2527/126—Aluminium chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,148,966. Oligomerizing propylene ; alkylation. ESSO RESEARCH & ENG. CO. 28 July, 1967 [4 Aug., 1966], No. 34853/67. Heading CSE. High molecular weight oligomers (e.g. averaging C 24 or higher) are prepared by contacting propylene containing 0À04-0À07 weight per cent water (relative to the propylene) with anhydrous BF 3 catalyst under conditions of temperature and pressure such that the propylene and catalyst are both liquid and are miscible with the oligomer formed, the weight ratio of water to BF 3 being not more than 0À14. The ratio BF 3 : propylene may be 0À5-0À8 weight per cent. The oligomers so prepared may be used to alkylate benzene, toluene or o-xylene in the presence of a Friedel-Crafts catalyst, e.g. AlCl 3 .
GB3485367A 1966-08-04 1967-07-28 Liquid olefins of high molecular weight obtained by polymerisation of propylene Expired GB1148966A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR72131A FR1500178A (en) 1966-08-04 1966-08-04 High molecular weight liquid olefins obtained by polymerization of propylene

Publications (1)

Publication Number Publication Date
GB1148966A true GB1148966A (en) 1969-04-16

Family

ID=8614894

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3485367A Expired GB1148966A (en) 1966-08-04 1967-07-28 Liquid olefins of high molecular weight obtained by polymerisation of propylene

Country Status (4)

Country Link
DE (1) DE1643930A1 (en)
FR (1) FR1500178A (en)
GB (1) GB1148966A (en)
NL (1) NL6710666A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2531207A1 (en) * 1974-07-17 1976-02-05 Exxon Research Engineering Co PROCESS FOR MANUFACTURING A PARAFFINIC BASE OIL
WO1989001001A1 (en) * 1987-07-30 1989-02-09 The Lubrizol Corporation Lower alkene polymers
US4982026A (en) * 1987-07-30 1991-01-01 The Lubrizol Corporation Lower alkene polymers
US5268520A (en) * 1987-07-30 1993-12-07 The Lubrizol Corporation Lower alkene polymers

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2531207A1 (en) * 1974-07-17 1976-02-05 Exxon Research Engineering Co PROCESS FOR MANUFACTURING A PARAFFINIC BASE OIL
US4078010A (en) 1974-07-17 1978-03-07 Exxon Research & Engineering Co. Hydrogenated olefine oligomers
WO1989001001A1 (en) * 1987-07-30 1989-02-09 The Lubrizol Corporation Lower alkene polymers
JPH02500277A (en) * 1987-07-30 1990-02-01 ザ　ルブリゾル　コーポレーション lower alkene polymer
US4973789A (en) * 1987-07-30 1990-11-27 The Lubrizol Corporation Lower alkene polymers
US4982026A (en) * 1987-07-30 1991-01-01 The Lubrizol Corporation Lower alkene polymers
US5268520A (en) * 1987-07-30 1993-12-07 The Lubrizol Corporation Lower alkene polymers
JP2577468B2 (en) 1987-07-30 1997-01-29 ザ ルブリゾル コーポレーション Lower alkene polymer

Also Published As

Publication number Publication date
DE1643930A1 (en) 1971-07-29
NL6710666A (en) 1968-02-05
FR1500178A (en) 1967-11-03

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