GB1148966A - Liquid olefins of high molecular weight obtained by polymerisation of propylene - Google Patents
Liquid olefins of high molecular weight obtained by polymerisation of propyleneInfo
- Publication number
- GB1148966A GB1148966A GB3485367A GB3485367A GB1148966A GB 1148966 A GB1148966 A GB 1148966A GB 3485367 A GB3485367 A GB 3485367A GB 3485367 A GB3485367 A GB 3485367A GB 1148966 A GB1148966 A GB 1148966A
- Authority
- GB
- United Kingdom
- Prior art keywords
- propylene
- high molecular
- molecular weight
- polymerisation
- weight obtained
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title abstract 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title abstract 6
- 239000007788 liquid Substances 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 238000012935 Averaging Methods 0.000 abstract 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 abstract 1
- 230000029936 alkylation Effects 0.000 abstract 1
- 238000005804 alkylation reaction Methods 0.000 abstract 1
- 229940078552 o-xylene Drugs 0.000 abstract 1
- 230000003606 oligomerizing effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
- C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
- C07C2/70—Catalytic processes with acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
- C07C2527/10—Chlorides
- C07C2527/11—Hydrogen chloride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
- C07C2527/12—Fluorides
- C07C2527/1213—Boron fluoride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
- C07C2527/126—Aluminium chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,148,966. Oligomerizing propylene ; alkylation. ESSO RESEARCH & ENG. CO. 28 July, 1967 [4 Aug., 1966], No. 34853/67. Heading CSE. High molecular weight oligomers (e.g. averaging C 24 or higher) are prepared by contacting propylene containing 0À04-0À07 weight per cent water (relative to the propylene) with anhydrous BF 3 catalyst under conditions of temperature and pressure such that the propylene and catalyst are both liquid and are miscible with the oligomer formed, the weight ratio of water to BF 3 being not more than 0À14. The ratio BF 3 : propylene may be 0À5-0À8 weight per cent. The oligomers so prepared may be used to alkylate benzene, toluene or o-xylene in the presence of a Friedel-Crafts catalyst, e.g. AlCl 3 .
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR72131A FR1500178A (en) | 1966-08-04 | 1966-08-04 | High molecular weight liquid olefins obtained by polymerization of propylene |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1148966A true GB1148966A (en) | 1969-04-16 |
Family
ID=8614894
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3485367A Expired GB1148966A (en) | 1966-08-04 | 1967-07-28 | Liquid olefins of high molecular weight obtained by polymerisation of propylene |
Country Status (4)
Country | Link |
---|---|
DE (1) | DE1643930A1 (en) |
FR (1) | FR1500178A (en) |
GB (1) | GB1148966A (en) |
NL (1) | NL6710666A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2531207A1 (en) * | 1974-07-17 | 1976-02-05 | Exxon Research Engineering Co | PROCESS FOR MANUFACTURING A PARAFFINIC BASE OIL |
WO1989001001A1 (en) * | 1987-07-30 | 1989-02-09 | The Lubrizol Corporation | Lower alkene polymers |
US4982026A (en) * | 1987-07-30 | 1991-01-01 | The Lubrizol Corporation | Lower alkene polymers |
US5268520A (en) * | 1987-07-30 | 1993-12-07 | The Lubrizol Corporation | Lower alkene polymers |
-
1966
- 1966-08-04 FR FR72131A patent/FR1500178A/en not_active Expired
-
1967
- 1967-07-26 DE DE19671643930 patent/DE1643930A1/en active Pending
- 1967-07-28 GB GB3485367A patent/GB1148966A/en not_active Expired
- 1967-08-02 NL NL6710666A patent/NL6710666A/xx unknown
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2531207A1 (en) * | 1974-07-17 | 1976-02-05 | Exxon Research Engineering Co | PROCESS FOR MANUFACTURING A PARAFFINIC BASE OIL |
US4078010A (en) | 1974-07-17 | 1978-03-07 | Exxon Research & Engineering Co. | Hydrogenated olefine oligomers |
WO1989001001A1 (en) * | 1987-07-30 | 1989-02-09 | The Lubrizol Corporation | Lower alkene polymers |
JPH02500277A (en) * | 1987-07-30 | 1990-02-01 | ザ ルブリゾル コーポレーション | lower alkene polymer |
US4973789A (en) * | 1987-07-30 | 1990-11-27 | The Lubrizol Corporation | Lower alkene polymers |
US4982026A (en) * | 1987-07-30 | 1991-01-01 | The Lubrizol Corporation | Lower alkene polymers |
US5268520A (en) * | 1987-07-30 | 1993-12-07 | The Lubrizol Corporation | Lower alkene polymers |
JP2577468B2 (en) | 1987-07-30 | 1997-01-29 | ザ ルブリゾル コーポレーション | Lower alkene polymer |
Also Published As
Publication number | Publication date |
---|---|
DE1643930A1 (en) | 1971-07-29 |
NL6710666A (en) | 1968-02-05 |
FR1500178A (en) | 1967-11-03 |
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