GB1388224A - Aluminium halide-carboxylic acid ester catalysts - Google Patents

Aluminium halide-carboxylic acid ester catalysts

Info

Publication number
GB1388224A
GB1388224A GB4158673A GB4158673A GB1388224A GB 1388224 A GB1388224 A GB 1388224A GB 4158673 A GB4158673 A GB 4158673A GB 4158673 A GB4158673 A GB 4158673A GB 1388224 A GB1388224 A GB 1388224A
Authority
GB
United Kingdom
Prior art keywords
ester
carboxylic acid
acid ester
halide
aluminium halide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4158673A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US00287303A external-priority patent/US3833678A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of GB1388224A publication Critical patent/GB1388224A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/60—Catalytic processes with halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
    • C07C2/22—Metal halides; Complexes thereof with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C07C2527/126—Aluminium chloride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

1388224 Aluminium halide catalyst solutions MOBIL OIL CORP 4 Sept 1973 [8 Sept 1972] 41586/73 Heading B1E [Also in Divisions C2 C3 and C5] A liquid catalyst comprises aluminium chloride a bromide dissolved in a methyl ester of n-butyric, n-valeric, n-hexanoic, isovaleric, trimethylacetic, 2-methylvaleric, 2-ethylbutyric or 2-ethylhexanoic acid in an amount greater than one mole per mole of the ester. The preferred amount of halide to ester is from 1.1 to 1.4 moles per mole of ester. The solution is formed by heating at from 30 to 50‹C. The catalysts are used in the polymerisation of olefines and the alkylation of isobutane with ethylene hydration of olefines or isomerisation of paraffins.
GB4158673A 1972-09-08 1973-09-04 Aluminium halide-carboxylic acid ester catalysts Expired GB1388224A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US00287303A US3833678A (en) 1963-12-30 1972-09-08 Stable and pumpable liquid aluminum chloride and bromide complexes

Publications (1)

Publication Number Publication Date
GB1388224A true GB1388224A (en) 1975-03-26

Family

ID=23102314

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4158673A Expired GB1388224A (en) 1972-09-08 1973-09-04 Aluminium halide-carboxylic acid ester catalysts

Country Status (8)

Country Link
JP (1) JPS581972B2 (en)
BE (1) BE804689A (en)
CA (1) CA1034970A (en)
DE (1) DE2345298C2 (en)
FR (1) FR2208711B1 (en)
GB (1) GB1388224A (en)
IT (1) IT998563B (en)
NL (1) NL181083C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1039575C (en) * 1992-12-26 1998-08-26 山东大学中利实业公司 Compound liquid AlCl3 catalyst and its preparing process
WO2014167331A1 (en) * 2013-04-10 2014-10-16 The Queen's University Of Belfast Oligomerisation process
WO2014167332A1 (en) * 2013-04-10 2014-10-16 The Queen's University Of Belfast Oligomerisation process

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5215588A (en) * 1975-07-29 1977-02-05 Lion Corp Process for polymerizing liquid olefin polymers
JPS5814407B2 (en) * 1976-05-10 1983-03-18 ライオン株式会社 Method for producing catalyst for olefin polymerization
CA1338541C (en) * 1985-06-20 1996-08-20 Joseph P. Kennedy Living catalysts, complexes and polymers therefrom
DE202015004713U1 (en) 2015-07-02 2015-07-17 Plamen Kravaev Continuously fiber-reinforced non-woven fabrics of activated carbon fibers
DE202016001344U1 (en) 2016-03-02 2016-03-16 Plamen Kravaev Template materials for the production of semi-finished carbon fiber products
DE102016003400A1 (en) 2016-03-19 2017-09-21 Plamen Kravaev Process for the production of activated textile semi-finished products from recycled carbon fibers

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1520900C3 (en) * 1963-12-30 1978-07-13 Mobil Oil Corp., New York, N.Y. (V.St.A.) Process for polymerizing olefins

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1039575C (en) * 1992-12-26 1998-08-26 山东大学中利实业公司 Compound liquid AlCl3 catalyst and its preparing process
WO2014167331A1 (en) * 2013-04-10 2014-10-16 The Queen's University Of Belfast Oligomerisation process
WO2014167332A1 (en) * 2013-04-10 2014-10-16 The Queen's University Of Belfast Oligomerisation process
US20160052838A1 (en) * 2013-04-10 2016-02-25 The Queen's University Of Belfast Oligomerisation process
US20160068622A1 (en) * 2013-04-10 2016-03-10 The Queen's Universiyt of Belfast Oligomerisation process
GB2512902B (en) * 2013-04-10 2018-10-17 Petroliam Nasional Berhad Petronas Oligomerisation Process
GB2512903B (en) * 2013-04-10 2018-10-17 Petroliam Nasional Berhad Petronas Oligomerisation Process
US10487162B2 (en) * 2013-04-10 2019-11-26 Petroliam Nasional Berhad (Petronas) Oligomerisation process
US10723673B2 (en) * 2013-04-10 2020-07-28 Petroliam Nasional Berhad (Petronas) Oligomerisation process

Also Published As

Publication number Publication date
CA1034970A (en) 1978-07-18
JPS4967896A (en) 1974-07-01
FR2208711A1 (en) 1974-06-28
JPS581972B2 (en) 1983-01-13
FR2208711B1 (en) 1980-05-23
AU5999973A (en) 1975-03-06
BE804689A (en) 1974-03-11
DE2345298C2 (en) 1982-04-22
IT998563B (en) 1976-02-20
NL7312318A (en) 1974-03-12
NL181083C (en) 1987-06-16
DE2345298A1 (en) 1974-04-04
NL181083B (en) 1987-01-16

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee