GB1055156A - Polyester compostitions - Google Patents

Polyester compostitions

Info

Publication number
GB1055156A
GB1055156A GB41746/63A GB4174663A GB1055156A GB 1055156 A GB1055156 A GB 1055156A GB 41746/63 A GB41746/63 A GB 41746/63A GB 4174663 A GB4174663 A GB 4174663A GB 1055156 A GB1055156 A GB 1055156A
Authority
GB
United Kingdom
Prior art keywords
copolyamide
diammonium
terephthalate
isophthalate
copolyamides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB41746/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Priority claimed from FR951617A external-priority patent/FR1372345A/en
Publication of GB1055156A publication Critical patent/GB1055156A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/04—Polyamides derived from alpha-amino carboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention comprises a composition which is a heterogeneous mixture of a linear fibre-forming polyester and a copolyamide having a melt viscosity not substantially greater than that of the polyester. The copolyamides advantageously constitute 1-25% of this composition, and should be soluble in, or softened by, water or water/alcohol mixtures, and have a melting point between 140 DEG and 260 DEG C., and an intrinsic viscosity (in 60/40 phenol/tetrachlorethylene at 25 DEG C.) of 0.6-2.0, with a water absorption at saturation of 7-14%. Suitable copolyamides are those of 6/66, 6/610, 66/610 or 6/66/610 types, or those containing carbocyclic structures. In general, no unit should constitute more than 95%, or less than 10% of the copolyamide. The polyesters preferably have an inherent viscosity of at least 0.4, and a melting-point between 150 DEG and 350 DEG C. The polyester and copolyamide are mixed, melted, and spun into fibres before the mixture becomes homogeneous-preferably within 30 minutes of melting. In examples, compositions are prepared from poly-(1,4 - cyclohexylene - dimethylene - terephthalate) and various 6/66 type copolyamides, from poly - (ethylene-terephthalate) or polyethylene-(terephthalate 97% sulpho-isophthalate 3%) and 66/610, 6/66/610 or caprolactam/m-xylylene diammonium adipate or tetramethylene diammonium oxalate/decamethylene diammonium oxalate copolyamides, from polyethylene-(terephthate 90%, isophthalate 10%) and a caprolactam/1,4 - cyclohexylene dimethylene diammonium isophthalate copolyamide, and from a poly-1,4-cyclohexylene dimethylene-(terephthalate/ succinate) or a polypentamethylene - (4,41 - sulphonyldibenzoate/succinate) and a 1,4-cyclohexylene dimethylene diammonium isophthalate/hexamethylene diammonium adipate copolyamide.
GB41746/63A 1962-10-24 1963-10-23 Polyester compostitions Expired GB1055156A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US1220128XA 1962-10-24 1962-10-24
US23289562A 1962-10-24 1962-10-24
FR951617A FR1372345A (en) 1962-10-24 1963-10-24 Polyester composition providing fibers with improved dyeability

Publications (1)

Publication Number Publication Date
GB1055156A true GB1055156A (en) 1967-01-18

Family

ID=29219277

Family Applications (1)

Application Number Title Priority Date Filing Date
GB41746/63A Expired GB1055156A (en) 1962-10-24 1963-10-23 Polyester compostitions

Country Status (2)

Country Link
DE (1) DE1220128B (en)
GB (1) GB1055156A (en)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE623009A (en) *
DE1068888B (en) * 1959-11-12
GB815179A (en) * 1956-03-05 1959-06-17 Rohm & Haas Polyesters and condensation products thereof with aminoplasts
US2981713A (en) * 1957-10-28 1961-04-25 Fairbanks Company Polyester molding composition

Also Published As

Publication number Publication date
DE1220128B (en) 1966-06-30

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