GB1048157A - Soluble and fusible polymers and copolymers of p-and/or m-diisopropenylbenzene and a method of preparing the same - Google Patents

Soluble and fusible polymers and copolymers of p-and/or m-diisopropenylbenzene and a method of preparing the same

Info

Publication number
GB1048157A
GB1048157A GB3642264A GB3642264A GB1048157A GB 1048157 A GB1048157 A GB 1048157A GB 3642264 A GB3642264 A GB 3642264A GB 3642264 A GB3642264 A GB 3642264A GB 1048157 A GB1048157 A GB 1048157A
Authority
GB
United Kingdom
Prior art keywords
mixture
diisopropenylbenzene
polymerization
benzene
polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3642264A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rutgerswerke und Teerverwertung AG
Ruetgers Germany GmbH
Original Assignee
Ruetgerswerke AG
Rutgerswerke und Teerverwertung AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ruetgerswerke AG, Rutgerswerke und Teerverwertung AG filed Critical Ruetgerswerke AG
Publication of GB1048157A publication Critical patent/GB1048157A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/34—Monomers containing two or more unsaturated aliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/32—Monomers containing only one unsaturated aliphatic radical containing two or more rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Soluble and fusible polymers of di-isopropenyl benzene are made by effecting the polymerization in the presence of an organolithium catalyst and (a) an oxy-alkylated monohydric mononuclear or polynuclear phenol and/or (b) an oxyalkylated polyhydric mononuclear or polynuclear phenol and/or (c) polyglycols of the general formula HO-CH2(CH2-O-CH2)n-CH2OH in which n is greater than 5, and which may be etherified or esterified. The polymerization may be started at a temperature greater than +10 DEG C. and continued at a temperature below +10 DEG C. The polymerization may be effected in the presence of other monomers such as styrene, alpha-methystyrene, 1-isopropyl-4-isopropenyl benzene, acenaphthylene, vinyl pyridene methacrylic acid esters, acrylonitrile, or butadiene. The polymerization is preferably effected in a solvent such as benzene, toluene, heptane, xylene, or cumene. Exemplified monomers are p-di-isopropenylbenzene, m-di-isopropenyl benzene, mixtures of m and p-diisopropenyl benzene, a mixture of styrene and m-diisopropenylbenzene, a mixture of alphamethylstyrene and p-diisopropenylbenzene, a mixture of methylmethacrylate and p-diisopropenylbenzene, a mixture in which the acrylate is replaced by butadiene, a mixture in which butadiene is replaced by vinylpyridene, a mixture of p-diisopropenylbenzene and acenaphthylene, a mixture of p-diisopropenylbenzene and acrylonitrile, a mixture of p-diisopropenyl and 1-isopropyl-4-diisopropenylbenzene, and a mixture of diisopropenylbenzene and methylpentadiene. The polymers are recovered by treating the polymerizate with methanol containing acetic acid, washing the product with methanol, and drying under vacuum. The polymers may be converted to the hard, infusible state by heating if desired, in presence of a peroxide.
GB3642264A 1963-09-10 1964-09-04 Soluble and fusible polymers and copolymers of p-and/or m-diisopropenylbenzene and a method of preparing the same Expired GB1048157A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DER36081A DE1219682B (en) 1963-09-10 1963-09-10 Process for the production of polymers and copolymers of diisopropenylbenzene
DER37344A DE1223555B (en) 1963-09-10 1964-02-29 Process for the production of polymers and copolymers of diisopropenylbenzene

Publications (1)

Publication Number Publication Date
GB1048157A true GB1048157A (en) 1966-11-09

Family

ID=25991699

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3642264A Expired GB1048157A (en) 1963-09-10 1964-09-04 Soluble and fusible polymers and copolymers of p-and/or m-diisopropenylbenzene and a method of preparing the same

Country Status (6)

Country Link
AT (1) AT257923B (en)
BE (1) BE652876A (en)
CH (1) CH448535A (en)
DE (2) DE1219682B (en)
GB (1) GB1048157A (en)
NL (1) NL123611C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0128851A2 (en) * 1983-05-12 1984-12-19 The Goodyear Tire & Rubber Company Poly-diisopropenyl benzene synthesis

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4403088A (en) * 1982-08-05 1983-09-06 The Goodyear Tire & Rubber Company Plastic resin prepared from meta or para-diisopropenylbenzene and method of preparation

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL240545A (en) * 1956-02-29

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0128851A2 (en) * 1983-05-12 1984-12-19 The Goodyear Tire & Rubber Company Poly-diisopropenyl benzene synthesis
EP0128851A3 (en) * 1983-05-12 1986-07-02 The Goodyear Tire & Rubber Company Poly-diisopropenyl benzene synthesis

Also Published As

Publication number Publication date
AT257923B (en) 1967-10-25
DE1219682B (en) 1966-06-23
CH448535A (en) 1967-12-15
NL123611C (en) 1967-08-15
DE1223555B (en) 1966-08-25
BE652876A (en) 1964-12-31
NL6410366A (en) 1965-03-11

Similar Documents

Publication Publication Date Title
ES289481A1 (en) Branched polymers prepared from monolithium-terminated polymers and compounds having at least three reactive sites
ES317873A1 (en) Procedure for the production of thermoplastic polymer compositions of high resistance to the shock. (Machine-translation by Google Translate, not legally binding)
GB1238191A (en)
GB1048157A (en) Soluble and fusible polymers and copolymers of p-and/or m-diisopropenylbenzene and a method of preparing the same
GB1015209A (en) Catalyst-containing, hardenable, storable polyester moulding masses
GB1527154A (en) Unsaturated epoxides as coupling agents for carbon fibres and unsaturated matrix resins
GB850363A (en) Alkenyl aromatic polymers
US2643995A (en) Emulsion polymerization process
US3110706A (en) Production of polymers by anionic polymerization in solution
GB1005307A (en) Process for recovering latex solids
DK126597B (en) Process for the preparation of high melt index solid ethylene polymers by polymerization in the presence of a chromium oxide polymerization catalyst.
GB677594A (en) Process for polymerizing alpha-methyl styrene
ES264939A1 (en) A process to prepare a polymer resistant to solvents (Machine-translation by Google Translate, not legally binding)
US3035027A (en) Cross-linking copolymers of n-carbamylmaleimide
GB1042625A (en) Process for the production of polycyclohexadiene-1,3
ES445369A1 (en) Acrylonitrile polymer solutions
GB875558A (en) Process for the production of eupolyoxymethylenes
ES364321A1 (en) Procedure for raising the molecular weight of a reactive polymer, derived in part from at least one vinylidene monomer. (Machine-translation by Google Translate, not legally binding)
GB1066667A (en) Preparation of random copolymers
JPS5543111A (en) Improved preparation of syrup
GB946696A (en) A novel per-ester and its use in the cross-linking and polymerisation of unsaturated polyester resin masses
GB1076897A (en) Process for preparing high molecular homo-polymerizates and co-polymerizates of alpha-methyl-styrene
GB1191056A (en) Improvements in the Manufacture of Materials Comprising Wood Impregnated with Synthetic Polymers
ES382338A1 (en) A procedure for preparing a polyester resin. (Machine-translation by Google Translate, not legally binding)
GB894767A (en) Polymerisation process