GB1046646A - Novel interpolymers and a process for preparing the same - Google Patents
Novel interpolymers and a process for preparing the sameInfo
- Publication number
- GB1046646A GB1046646A GB2662264A GB2662264A GB1046646A GB 1046646 A GB1046646 A GB 1046646A GB 2662264 A GB2662264 A GB 2662264A GB 2662264 A GB2662264 A GB 2662264A GB 1046646 A GB1046646 A GB 1046646A
- Authority
- GB
- United Kingdom
- Prior art keywords
- linear
- polymerization
- styrene
- monomer
- acrylonitrile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Transparent polymeric moulding materials are made by polymerizing methyl methacrylate and a vinyl aromatic compound with 3 to 15%, based on monomer weight, of a linear rubber, e.g. cis-1,4-polybutadiene, linear polycyclopentadiene, linear polyisoprene, linear copolymers of butadiene with styrene, acrylonitrile or isobutylene and linear block copolymers of styrene with butadiene and isoprene. The vinyl aromatic monomers is preferably styrene, which may be replaced wholly or in part by alpha-methylstyrene, or styrenes substituted in the nucleus by chlorine or alkyl groups. Also present in the monomer mixture may be 3 to 10% by weight of acrylonitrile. Polymerization is carried out by dissolving the linear rubber in the monomer mixture, polymerizing the resulting solution to 10 to 45% conversion, then suspending the prepolymer in water and completing the polymerization. Polymerization is initiated by the use of monomer-soluble catalysts, e.g. benzoyl peroxide in the bulk polymerization stage and tert.-butyl perbenzoate in the suspension stage. The aqueous medium in the suspension stage contains a small quantity of suspending agent, e.g. hydroxyethyl cellulose.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29275863A | 1963-07-03 | 1963-07-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1046646A true GB1046646A (en) | 1966-10-26 |
Family
ID=23126056
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2662264A Expired GB1046646A (en) | 1963-07-03 | 1964-06-26 | Novel interpolymers and a process for preparing the same |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1046646A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4647620A (en) * | 1984-08-24 | 1987-03-03 | Doak Kenneth W | Polyblends of a copolymer of a vinyl aromatic monomer and an unsaturated dicarboxylic acid anhydride with a methyl methacrylate homopolymer or copolymer |
| EP0997483A1 (en) * | 1997-07-07 | 2000-05-03 | Nippon Steel Chemical Co., Ltd. | Process for the preparation of rubber-modified aromatic vinyl resin compositions |
-
1964
- 1964-06-26 GB GB2662264A patent/GB1046646A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4647620A (en) * | 1984-08-24 | 1987-03-03 | Doak Kenneth W | Polyblends of a copolymer of a vinyl aromatic monomer and an unsaturated dicarboxylic acid anhydride with a methyl methacrylate homopolymer or copolymer |
| EP0997483A1 (en) * | 1997-07-07 | 2000-05-03 | Nippon Steel Chemical Co., Ltd. | Process for the preparation of rubber-modified aromatic vinyl resin compositions |
| EP0997483A4 (en) * | 1997-07-07 | 2000-05-10 | Nippon Steel Chemical Co | Process for the preparation of rubber-modified aromatic vinyl resin compositions |
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