GB1013498A - Improvements in or relating to polymerization method and compositions produced thereby - Google Patents

Improvements in or relating to polymerization method and compositions produced thereby

Info

Publication number
GB1013498A
GB1013498A GB2657462A GB2657462A GB1013498A GB 1013498 A GB1013498 A GB 1013498A GB 2657462 A GB2657462 A GB 2657462A GB 2657462 A GB2657462 A GB 2657462A GB 1013498 A GB1013498 A GB 1013498A
Authority
GB
United Kingdom
Prior art keywords
styrene
tert
sodium
specified
polymerizing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2657462A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foster Grant Co Inc
Original Assignee
Foster Grant Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foster Grant Co Inc filed Critical Foster Grant Co Inc
Publication of GB1013498A publication Critical patent/GB1013498A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Abstract

High impact strength polymers are produced in bead form without substantial formation of emulsion polymer by (1) bulk polymerizing a mixture of 20 to 100% of a monovinyl aromatic monomer and up to 80% of an ethylenic comonomer in the presence of a rubbery polymer of a C4-C6 diolefin to a conversion of 15 to 40% of monomer, and (2) containing polymerization to a conversion of at least 70% in suspension in an aqueous medium which contains an anionic surfactant, a polyvinyl alcohol suspending agent and an electrolyte, e.g. sodium, potassium or calcium chloride, or sodium nitrate. Rubbers specified are copolymers of butadiene and isoprene with styrene and acrylonitrile, polychloroprene and high cis-1,4-polybutadiene. Vinyl aromatic monomers specified are styrene and alkyl, aryl and halo derivatives thereof. Comonomers specified are unsaturated acids, esters, amides, nitriles, ethers, ketones and halogenated hydrocarbons. Preferred anionic surfactants are sodium stearate and sodium dodecylbenzene sulphonate. Polymerization is carried out in the presence of peroxide catalysts, preferred being di-tert.-butyl peroxide, tert.-butyl peracetate, tert.-butyl perbenzoate, and mixtures thereof. The examples describe polymerizing styrene and mixtures thereof with acrylonitrile and methyl methacrylate in the presence of a butadienestyrene copolymer, and polymerizing styrene in the presence of a polybutadiene having a cis-1,4 content of 95%.
GB2657462A 1961-07-11 1962-07-10 Improvements in or relating to polymerization method and compositions produced thereby Expired GB1013498A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US12342561A 1961-07-11 1961-07-11

Publications (1)

Publication Number Publication Date
GB1013498A true GB1013498A (en) 1965-12-15

Family

ID=22408618

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2657462A Expired GB1013498A (en) 1961-07-11 1962-07-10 Improvements in or relating to polymerization method and compositions produced thereby

Country Status (4)

Country Link
BE (1) BE620108A (en)
DE (1) DE1495687A1 (en)
GB (1) GB1013498A (en)
NL (1) NL280753A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2281380A1 (en) * 1974-08-05 1976-03-05 Monsanto Co PROCESS FOR PREPARING POLYMERIC MIXTURES
FR2356681A1 (en) * 1976-07-01 1978-01-27 Monsanto Co PROCESS FOR GRAFTING RUBBER WITH MONO-ALKENYLAROMATIC MONOMERS BY MASS POLYMERIZATION AND NEW PRODUCTS THUS OBTAINED
FR2473530A1 (en) * 1980-01-16 1981-07-17 Montedison Spa MODIFIED VINYL-AROMATIC POLYMERS HAVING IMPROVED RESISTANCE TO CRACKS UNDER SOLIDITY

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3811014A1 (en) * 1988-03-31 1989-10-19 Basf Ag IMPACT RESISTANT THERMOPLASTIC MOLDS AND THEIR USE

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2281380A1 (en) * 1974-08-05 1976-03-05 Monsanto Co PROCESS FOR PREPARING POLYMERIC MIXTURES
FR2356681A1 (en) * 1976-07-01 1978-01-27 Monsanto Co PROCESS FOR GRAFTING RUBBER WITH MONO-ALKENYLAROMATIC MONOMERS BY MASS POLYMERIZATION AND NEW PRODUCTS THUS OBTAINED
FR2473530A1 (en) * 1980-01-16 1981-07-17 Montedison Spa MODIFIED VINYL-AROMATIC POLYMERS HAVING IMPROVED RESISTANCE TO CRACKS UNDER SOLIDITY

Also Published As

Publication number Publication date
NL280753A (en)
DE1495687A1 (en) 1970-05-21
BE620108A (en)

Similar Documents

Publication Publication Date Title
GB1027724A (en) Process for manufacture of high impact polymers
GB726583A (en) Improvements in or relating to poly-component compositions of polymeric materials
ES428099A1 (en) Graft polymers and compositions of high impact strength
GB1011499A (en) Process for preparing high impact polymers
GB1013498A (en) Improvements in or relating to polymerization method and compositions produced thereby
GB884974A (en) Block copolymers
GB1040287A (en) Improvements in or relating to the manufacture of synthetic rubber compositions
GB767642A (en) Production of styrene-type polymers
GB963372A (en) Improvements in and relating to the production of thermoplastic polymeric materials
GB1110834A (en) Method of making polymeric products from stable emulsions of immiscible solutions of elastomers,thermoplastic polymers and ethylenically unsaturated monomers
GB873948A (en) Suspension polymerisation process
GB1080485A (en) Improved polymerization process
GB1009655A (en) Thermoplastic moulding compositions
GB1054301A (en) Suspension polymerisation process
GB819651A (en) Grafting of polymerizable compounds on to pre-formed polymers
US3344128A (en) Thiourea dioxide as reductant in emulsion polymerization
GB946663A (en) Graft copolymers of alkyl ª -substituted acroleins and reaction products thereof
GB867822A (en) Graft polymerisation process
GB788651A (en) Improvements in and relating to modified rubber compositions
GB1312325A (en) Solution-suspension polymerization
US3143522A (en) Method of grafting styrene onto butadiene-styrene polymer
GB1020176A (en) Acrylonitrile-styrene-rubber terpolymers
GB794400A (en) Improvements in rubber-and-resin compositions
GB818285A (en) Improvements in vulcanizable compositions
GB1327095A (en) Process for the production of olefinically unsaturated nitrile/ styrene or alkyl-styrene/diene polymers