GB1038285A - Diallyl esters - Google Patents
Diallyl estersInfo
- Publication number
- GB1038285A GB1038285A GB756765A GB756765A GB1038285A GB 1038285 A GB1038285 A GB 1038285A GB 756765 A GB756765 A GB 756765A GB 756765 A GB756765 A GB 756765A GB 1038285 A GB1038285 A GB 1038285A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- dicarboxylic acids
- allyl alcohol
- diallyl
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
A process for the preparation of diallyl esters of carbocyclic aromatic dicarboxylic acids comprises catalytically transesterifying a dimethyl and/or diethyl ester of the acid with at least equivalent amount of allyl alcohol calculated with reference to the methyl or ethyl ester groups in an inert atmosphere by the gradual addition of allyl alcohol at a temperature above its boiling point, with evolution and removal of the methanol or ethanol, so that a diallyl ester is formed. Aromatic dicarboxylic acids specified include isomeric phthalic acids, diphenyl dicarboxylic and naphthalene dicarboxylic acids 5-chloroisophthalic acid, methyl terephthalic acid and dichloroterephthalic acid. Transesterification catalysts specified include magnesium methoxide, metallic magnesium butyl titanate or mixtures thereof. Examples are furnished.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEC32247A DE1211625B (en) | 1964-02-26 | 1964-02-26 | Process for the preparation of diallyl esters of carbocyclic aromatic dicarboxylic acids |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1038285A true GB1038285A (en) | 1966-08-10 |
Family
ID=7020219
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB756765A Expired GB1038285A (en) | 1964-02-26 | 1965-02-22 | Diallyl esters |
Country Status (6)
Country | Link |
---|---|
AT (1) | AT250938B (en) |
BE (1) | BE660259A (en) |
CH (1) | CH446297A (en) |
DE (1) | DE1211625B (en) |
GB (1) | GB1038285A (en) |
NL (1) | NL143901B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4473702A (en) * | 1979-11-15 | 1984-09-25 | Kureha Kagaku Kogyo Kabushiki Kaisha | Method for producing diallyl ester of aromatic dicarboxylic acid |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0674239B2 (en) * | 1988-10-18 | 1994-09-21 | 昭和電工株式会社 | Novel allylic oligomer and process for producing the same |
-
1964
- 1964-02-26 DE DEC32247A patent/DE1211625B/en active Pending
- 1964-11-19 CH CH1492964A patent/CH446297A/en unknown
- 1964-11-24 AT AT992964A patent/AT250938B/en active
- 1964-12-16 NL NL6414641A patent/NL143901B/en unknown
-
1965
- 1965-02-22 GB GB756765A patent/GB1038285A/en not_active Expired
- 1965-02-25 BE BE660259D patent/BE660259A/xx unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4473702A (en) * | 1979-11-15 | 1984-09-25 | Kureha Kagaku Kogyo Kabushiki Kaisha | Method for producing diallyl ester of aromatic dicarboxylic acid |
Also Published As
Publication number | Publication date |
---|---|
NL6414641A (en) | 1965-08-27 |
NL143901B (en) | 1974-11-15 |
AT250938B (en) | 1966-12-12 |
DE1211625B (en) | 1966-03-03 |
BE660259A (en) | 1965-06-16 |
CH446297A (en) | 1967-11-15 |
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