GB1037818A - Improvements in the preparation of unsaturated aldehydes - Google Patents
Improvements in the preparation of unsaturated aldehydesInfo
- Publication number
- GB1037818A GB1037818A GB43084/63D GB4308463D GB1037818A GB 1037818 A GB1037818 A GB 1037818A GB 43084/63 D GB43084/63 D GB 43084/63D GB 4308463 D GB4308463 D GB 4308463D GB 1037818 A GB1037818 A GB 1037818A
- Authority
- GB
- United Kingdom
- Prior art keywords
- preferred
- salifying
- bismuth
- heteropolyacid
- reacting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001299 aldehydes Chemical class 0.000 title abstract 3
- 229910052797 bismuth Inorganic materials 0.000 abstract 15
- 229910052714 tellurium Inorganic materials 0.000 abstract 13
- 150000001875 compounds Chemical class 0.000 abstract 11
- 229910052684 Cerium Inorganic materials 0.000 abstract 9
- 229910052776 Thorium Inorganic materials 0.000 abstract 9
- 229910052750 molybdenum Inorganic materials 0.000 abstract 9
- 229910052721 tungsten Inorganic materials 0.000 abstract 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 6
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 6
- 239000002253 acid Substances 0.000 abstract 5
- 150000003863 ammonium salts Chemical class 0.000 abstract 5
- 239000011964 heteropoly acid Substances 0.000 abstract 5
- 150000001336 alkenes Chemical class 0.000 abstract 4
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 abstract 4
- 229910052768 actinide Inorganic materials 0.000 abstract 3
- 150000001255 actinides Chemical class 0.000 abstract 3
- 150000001298 alcohols Chemical class 0.000 abstract 3
- 150000002148 esters Chemical class 0.000 abstract 3
- 150000002170 ethers Chemical class 0.000 abstract 3
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 3
- 150000002602 lanthanoids Chemical class 0.000 abstract 3
- 150000007522 mineralic acids Chemical class 0.000 abstract 3
- 150000007524 organic acids Chemical class 0.000 abstract 3
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 3
- 150000002910 rare earth metals Chemical class 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- 229910052720 vanadium Inorganic materials 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- 239000004965 Silica aerogel Substances 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 230000008020 evaporation Effects 0.000 abstract 2
- 238000001704 evaporation Methods 0.000 abstract 2
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 2
- 239000011707 mineral Substances 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- -1 examples.ALSO:Unsaturated aliphatic aldehydes Chemical class 0.000 abstract 1
- 239000007792 gaseous phase Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
- B01J27/0576—Tellurium; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2145662 | 1962-10-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1037818A true GB1037818A (en) | 1966-08-03 |
Family
ID=11182031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB43084/63D Expired GB1037818A (en) | 1962-10-31 | 1963-10-31 | Improvements in the preparation of unsaturated aldehydes |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3410910A (en:Method) |
| GB (1) | GB1037818A (en:Method) |
| NL (2) | NL143894B (en:Method) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56142262A (en) | 1980-04-08 | 1981-11-06 | Nippon Shinyaku Co Ltd | Piperazine derivative |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2373942A (en) * | 1942-01-05 | 1945-04-17 | Shell Dev | Catalytic hydroxylation of olefinic double bonds |
| US2744928A (en) * | 1952-11-28 | 1956-05-08 | Shell Dev | Oxidation of unsaturated aldehydes to acids |
| US2941007A (en) * | 1957-06-10 | 1960-06-14 | Standard Oil Co | Process for the oxidation of olefins |
| GB839808A (en) * | 1957-06-21 | 1960-06-29 | Bayer Ag | Process for the production of acrolein |
| DE1443108A1 (en:Method) * | 1960-07-01 | 1971-12-02 | ||
| US3173957A (en) * | 1961-08-21 | 1965-03-16 | Eastman Kodak Co | Process for the preparation of acrolein |
| US3168572A (en) * | 1961-10-06 | 1965-02-02 | Shell Oil Co | Production of alpha, beta-unsaturated carbonylic compounds |
-
0
- NL NL299920D patent/NL299920A/xx unknown
-
1963
- 1963-10-28 US US319534A patent/US3410910A/en not_active Expired - Lifetime
- 1963-10-30 NL NL63299920A patent/NL143894B/xx unknown
- 1963-10-31 GB GB43084/63D patent/GB1037818A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL143894B (nl) | 1974-11-15 |
| US3410910A (en) | 1968-11-12 |
| NL299920A (en:Method) |
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