GB839808A - Process for the production of acrolein - Google Patents

Process for the production of acrolein

Info

Publication number
GB839808A
GB839808A GB19679/58A GB1967958A GB839808A GB 839808 A GB839808 A GB 839808A GB 19679/58 A GB19679/58 A GB 19679/58A GB 1967958 A GB1967958 A GB 1967958A GB 839808 A GB839808 A GB 839808A
Authority
GB
United Kingdom
Prior art keywords
cupric
cations
anions
phosphate
silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19679/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB839808A publication Critical patent/GB839808A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/186Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

Catalysts for use in the oxidation of propylene by oxygen to acrolein comprise one or more compounds of difficultly volatile, thermally stable oxygen acids of boron, phosphorus, chromium, molybdenum, tungsten or vanadium, with manganese, iron, cobalt, nickel, copper, zinc, titanium, silver, cadmium, tin, cerium, lead, bismuth, thorium or uranium. The catalysts may be used on supports such as silica gel, boron phosphate, Al phosphate, TiO2, clay or pumice. Examples are given of the process in which catalysts are used containing the following anions and cations: (a) cupric cations with phosphate; borate and phosphate; vanadate; molybdate; tungstate; or chromate anions; (b) phosphate anions with cupric and zinc; cobalt; cupric and cobalt; manganese; cupric and titanium; ferric; ferrous and cupric; nickel; nickel and cupric; stannous; plumbic; bismuth; silver; silver and cupric; thorium; cadmium and cupric; bismuth and cupric; uranium; and cerium cations; (c) cupric and manganese cations with phosphate and borate anions; (d) plumbic cations with molybdate anions; (e) silver cations with tungstate anions; (f) uranium cations with borate and phosphate anions; and (g) titanium cations with tungstate anions. Specifications 723,003 and 777,010 are referred to.ALSO:Acrolein is produced by the oxidation of propylene with molecular oxygen in the vapour phase at elevated temperature in the presence of one or more compounds of difficulty volatile, thermally stable oxygen acids of boron, phosphorus, chromium, molybdenum, tungsten or vanadium with manganese, iron, cobalt, nickel, copper, zinc, titanium, silver, cadmium, tin, cerium, lead, bismuth, thorium and uranium, as catalyst. The catalysts may be used on supports, those with neutral or acid properties being particularly suitable. The oxygen may be mixed with inert gases, e.g. air may be used as the oxygen source. The preferred temperature range for the process is 300-800 DEG C. The preferred catalysts are those containing divalent copper as cation and phosphonic acid as anion in addition to other components. Specifications 723,003 and 777,010 are referred to.
GB19679/58A 1957-06-21 1958-06-19 Process for the production of acrolein Expired GB839808A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE839808X 1957-06-21

Publications (1)

Publication Number Publication Date
GB839808A true GB839808A (en) 1960-06-29

Family

ID=6762032

Family Applications (1)

Application Number Title Priority Date Filing Date
GB19679/58A Expired GB839808A (en) 1957-06-21 1958-06-19 Process for the production of acrolein

Country Status (1)

Country Link
GB (1) GB839808A (en)

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1160838B (en) * 1960-12-01 1964-01-09 Stamicarbon Process for the production of acrolein by the catalytic oxidation of propylene
DE1160839B (en) * 1961-02-28 1964-01-09 Stamicarbon Process for the production of methacrolein by the catalytic oxidation of isobutene
DE1177628B (en) * 1961-03-06 1964-09-10 Stamicarbon N. V., Heerlen (Niederlande) Process for the production of acrolein or methakrolein by the catalytic oxidation of propylene or isobutylene.
US3173957A (en) * 1961-08-21 1965-03-16 Eastman Kodak Co Process for the preparation of acrolein
DE1196631B (en) * 1961-04-20 1965-07-15 Standard Oil Co Process for the production of unsaturated aldehydes
US3260753A (en) * 1963-10-14 1966-07-12 Eastman Kodak Co Catalytic process for preparing acrolein
US3280193A (en) * 1962-10-24 1966-10-18 Ici Ltd Catalytic production of methacrolein from isobutene
DE1241817B (en) * 1961-01-26 1967-06-08 Knapsack Ag Process for the production of acrylic acid by the oxidation of propylene
US3342869A (en) * 1962-12-26 1967-09-19 Gulf Oil Corp Novel oxidation catalyst compositions and processes
US3345417A (en) * 1962-12-26 1967-10-03 Gulf Oil Corp Novel oxidation catalyst compositions and processes
US3392196A (en) * 1964-01-20 1968-07-09 Goodrich Co B F Catalytic method of preparing unsaturated aldehydes and acids
US3401196A (en) * 1965-08-30 1968-09-10 Goodrich Co B F Catalytic process of preparing unsaturated acids and aldehydes
US3410910A (en) * 1962-10-31 1968-11-12 Montedison Spa Catalytic process for preparing unsaturated aldehydes
US3417145A (en) * 1965-10-12 1968-12-17 Rohm & Haas Method for the preparation of acrolein
US3441613A (en) * 1965-10-12 1969-04-29 Rohm & Haas Method for the preparation of acrolein
US3446753A (en) * 1962-12-26 1969-05-27 Gulf Oil Corp Novel oxidation catalyst compositions
US3456003A (en) * 1965-08-30 1969-07-15 Goodrich Co B F Method of preparing unsaturated acids and aldehydes
US3476809A (en) * 1965-09-29 1969-11-04 Atlantic Richfield Co Olefin oxidation catalyst
US3499936A (en) * 1966-04-12 1970-03-10 Gulf Research Development Co Oxidation of isobutylene to methacrylaldehyde over complex vanadium oxide catalysts
US3509069A (en) * 1965-08-30 1970-04-28 Goodrich Co B F Catalyst for preparing unsaturated acids and aldehydes
US3519688A (en) * 1967-09-29 1970-07-07 Standard Oil Co Process for the manufacture of unsaturated aldehydes from olefins
US3524823A (en) * 1965-08-30 1970-08-18 Goodrich Co B F Catalyst and method of preparing unsaturated acids and aldehydes
US3546136A (en) * 1965-08-30 1970-12-08 Goodrich Co B F Catalyst and method of preparing unsaturated acids and aldehydes

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1160838B (en) * 1960-12-01 1964-01-09 Stamicarbon Process for the production of acrolein by the catalytic oxidation of propylene
DE1241817B (en) * 1961-01-26 1967-06-08 Knapsack Ag Process for the production of acrylic acid by the oxidation of propylene
DE1160839B (en) * 1961-02-28 1964-01-09 Stamicarbon Process for the production of methacrolein by the catalytic oxidation of isobutene
DE1177628B (en) * 1961-03-06 1964-09-10 Stamicarbon N. V., Heerlen (Niederlande) Process for the production of acrolein or methakrolein by the catalytic oxidation of propylene or isobutylene.
DE1196631B (en) * 1961-04-20 1965-07-15 Standard Oil Co Process for the production of unsaturated aldehydes
US3173957A (en) * 1961-08-21 1965-03-16 Eastman Kodak Co Process for the preparation of acrolein
US3280193A (en) * 1962-10-24 1966-10-18 Ici Ltd Catalytic production of methacrolein from isobutene
US3410910A (en) * 1962-10-31 1968-11-12 Montedison Spa Catalytic process for preparing unsaturated aldehydes
US3446753A (en) * 1962-12-26 1969-05-27 Gulf Oil Corp Novel oxidation catalyst compositions
US3345417A (en) * 1962-12-26 1967-10-03 Gulf Oil Corp Novel oxidation catalyst compositions and processes
US3342869A (en) * 1962-12-26 1967-09-19 Gulf Oil Corp Novel oxidation catalyst compositions and processes
US3260753A (en) * 1963-10-14 1966-07-12 Eastman Kodak Co Catalytic process for preparing acrolein
US3392196A (en) * 1964-01-20 1968-07-09 Goodrich Co B F Catalytic method of preparing unsaturated aldehydes and acids
US3456003A (en) * 1965-08-30 1969-07-15 Goodrich Co B F Method of preparing unsaturated acids and aldehydes
US3401196A (en) * 1965-08-30 1968-09-10 Goodrich Co B F Catalytic process of preparing unsaturated acids and aldehydes
US3457303A (en) * 1965-08-30 1969-07-22 Goodrich Co B F Method of preparing unsaturated aldehydes and acids
US3467700A (en) * 1965-08-30 1969-09-16 Goodrich Co B F Method of preparing unsaturated aldehydes and acids
US3509069A (en) * 1965-08-30 1970-04-28 Goodrich Co B F Catalyst for preparing unsaturated acids and aldehydes
US3524823A (en) * 1965-08-30 1970-08-18 Goodrich Co B F Catalyst and method of preparing unsaturated acids and aldehydes
US3546136A (en) * 1965-08-30 1970-12-08 Goodrich Co B F Catalyst and method of preparing unsaturated acids and aldehydes
US3476809A (en) * 1965-09-29 1969-11-04 Atlantic Richfield Co Olefin oxidation catalyst
US3441613A (en) * 1965-10-12 1969-04-29 Rohm & Haas Method for the preparation of acrolein
US3417145A (en) * 1965-10-12 1968-12-17 Rohm & Haas Method for the preparation of acrolein
US3499936A (en) * 1966-04-12 1970-03-10 Gulf Research Development Co Oxidation of isobutylene to methacrylaldehyde over complex vanadium oxide catalysts
US3519688A (en) * 1967-09-29 1970-07-07 Standard Oil Co Process for the manufacture of unsaturated aldehydes from olefins

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