GB1037647A - Surface-active sulpho-betaines - Google Patents

Surface-active sulpho-betaines

Info

Publication number
GB1037647A
GB1037647A GB2669263A GB2669263A GB1037647A GB 1037647 A GB1037647 A GB 1037647A GB 2669263 A GB2669263 A GB 2669263A GB 2669263 A GB2669263 A GB 2669263A GB 1037647 A GB1037647 A GB 1037647A
Authority
GB
United Kingdom
Prior art keywords
acid
salts
carbon atoms
stage
branched
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2669263A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of GB1037647A publication Critical patent/GB1037647A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D291/00—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms
    • C07D291/02—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms not condensed with other rings
    • C07D291/06—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/92—Sulfobetaines ; Sulfitobetaines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Detergent Compositions (AREA)

Abstract

Surface-active suphobetaines containing hydroxyl groups ar obtained by reacting tertiary monoamines containing at least one hydrophobic residue, a residue containing at lest 8 carbon atoms, straight-or branched-chain and possibly substituted, with epichlorohydrin in the presence of water and base-binding agents, and reacting the quaternary ammonium salts containing a chlorohydrin group with salts of sulphurous acid. The formation of the quaternary ammonium salt and the reaction of the quaternary ammonium salt containing a chlorohydrin group with salts of sulphurous acid may be carried out in two separate stages, or in one stage by use of acid salts of sulphurous acid as base-binding agents. Specified tertiary monoamines are those of the formula <FORM:1037647/C2/1> wherein Q and, if desired, also R2 represent hydrophobic straight- or branched-chain aliphatic, cycloaliphatic or araliphatic hydrocarbon residues containing 8-22 carbon atoms; R1 and, if desired, R2, represent straight- or branched-chain aliphatic, cycloaliphatic or araliphatic hydrocarbon residues each containing not more than 7 carbon atoms which may be linked with one another directly or via an intermediate hetero atom, and when Q and R2 represent hydrophobic residues, the sum of the carbon atoms contained therein should not exceed 36. In the two-stage process, the first stage is preferably carried out at between 0 DEG and 100 DEG C. and in aqueous solution at a pH not higher than 8, and the second stage is preferably carried out by reaction with sodium sulphite at between 40 DEG and 200 DEG C. Specified acid salts of sulphurous acid for use in the one stage process are sodium bisulphite and sodium pyrosulphite. Other base-binding agents which may be used are mineral acids, e.g. hydrochloric acid, sulphuric acid, phosphoric acid or acid salts thereof; and organic carboxylic or sulphonic acids. Examples are given in which the starting amine is dimethyl-dodecylamine, -hexadecylamine, -n-octylamine or -coconut-alkylamine. Reference has been directed by the Comptroller to Specification 989,495.
GB2669263A 1962-07-06 1963-07-05 Surface-active sulpho-betaines Expired GB1037647A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEH46298A DE1257779B (en) 1962-07-06 1962-07-06 Process for the production of surface-active sulfobetaines

Publications (1)

Publication Number Publication Date
GB1037647A true GB1037647A (en) 1966-08-03

Family

ID=7156053

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2669263A Expired GB1037647A (en) 1962-07-06 1963-07-05 Surface-active sulpho-betaines

Country Status (3)

Country Link
CH (1) CH462172A (en)
DE (1) DE1257779B (en)
GB (1) GB1037647A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0213054A2 (en) * 1985-05-09 1987-03-04 Sherex Chemical Company, Inc. Alkaline tolerant sulfobetaine amphoteric surfactants
CN106032353A (en) * 2015-03-17 2016-10-19 山东大明精细化工有限公司 Amphoteric sulfobetaine surfactant preparation method

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE651733C (en) * 1934-09-27 1937-10-25 I G Farbenindustrie Akt Ges Process for the preparation of nitrogen- and sulfur-containing condensation products from aliphatic halosulfonic acids and tertiary amines
DE668490C (en) * 1936-09-18 1938-12-05 I G Farbenindustrie Akt Ges Process for the production of nitrogen- and sulfur-containing condensation products
DE1018421B (en) * 1952-10-03 1957-10-31 Boehme Fettchemie Gmbh Process for the preparation of sulfobetaines

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0213054A2 (en) * 1985-05-09 1987-03-04 Sherex Chemical Company, Inc. Alkaline tolerant sulfobetaine amphoteric surfactants
EP0213054A3 (en) * 1985-05-09 1987-10-14 Sherex Chemical Company, Inc. Alkaline tolerant sulfobetaine amphoteric surfactants
CN106032353A (en) * 2015-03-17 2016-10-19 山东大明精细化工有限公司 Amphoteric sulfobetaine surfactant preparation method

Also Published As

Publication number Publication date
DE1257779B (en) 1968-01-04
CH462172A (en) 1968-09-15

Similar Documents

Publication Publication Date Title
GB1037647A (en) Surface-active sulpho-betaines
DK230082A (en) CARBACYCLINES PROCEDURES FOR THEIR PREPARATION AND THEIR USE AS A MEDICINE
GB1387175A (en) Salts of iodomethanesulphonic acid
GB1489803A (en) Aminoacetamides and a process for their preparation
GB1021521A (en) Thiomethylphosphinic acids and salts thereof
GB934292A (en) Process for the preparation of heterocyclic compounds
KR870010065A (en) Phosphoric Acid Ester and Process for Preparing the Same
GB986071A (en) Improvements in or relating to n-alkane sulphonic acids
GB946303A (en) Novel steroids and process for their manufacture
GB1310236A (en) Morpholine derivatives
SU502862A1 (en) The method of producing propylene chlorohydrin
GB680952A (en) Improvements in new morphine derivatives and production thereof
GB1085083A (en) Improvements in or relating to benzimidazoles and the manufacture thereof
GB1020100A (en) Preparation of hydroxyalkane sulphonic acid salts and of sultones therefrom
GB927423A (en) Dipiperazine sulphate solutions and method therefor
GB1062386A (en) Process for preparing pyrazinyl phosphorothioates
GB730139A (en) Improvements in or relating to the preparation of halogenated substituted pteridines
GB1049770A (en) Production of omega aminoketocarboxylic acids
GB1010759A (en) Bis-triazinylamino-stilbene brightening agents
GB821309A (en) Preparation of a tetracycline-urea compound
GB1021385A (en) Derivatives of 2-oxo-2h-1,4-benzoxazine
GB672164A (en) A process for the manufacture of pentaenes
GB481557A (en) Manufacture of isocyclic compounds
GB1017989A (en) Benzene-sulphonyl-ureas
GB790167A (en) Method of producing an organic salt of 1-phenyl-2-aminopropane and organic salt obtained by this method