GB1012488A - Improvements in or relating to detergent compositions - Google Patents
Improvements in or relating to detergent compositionsInfo
- Publication number
- GB1012488A GB1012488A GB32481/62A GB3248162A GB1012488A GB 1012488 A GB1012488 A GB 1012488A GB 32481/62 A GB32481/62 A GB 32481/62A GB 3248162 A GB3248162 A GB 3248162A GB 1012488 A GB1012488 A GB 1012488A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phosphoric acid
- sodium
- ash
- alkyl
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/30—Alkali metal phosphates
- C01B25/301—Preparation from liquid orthophosphoric acid or from an acid solution or suspension of orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
- C11D3/062—Special methods concerning phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
Abstract
A method of preparing a dry, free-flowing detergent composition comprises dispersing a phosphoric acid in a body of dry, solid particles of an alkali metal carbonate containing material in a proportion in which the M2CO3 : H3PO4 mol. ratio is at least 1.5 : 1 (M being the alkali metal), agitating the mixture while maintaining it at a temperature not substantially in excess of 104 DEG C., and recovering the resulting dry, free-flowing product characterized by an M2O : P2O5 mol. ratio greater than 3 : 1 and a pH as a 1% w/v. aqueous solution, greater than 7.5. The composition contains at least one phosphate having the formula: MxHyPO4.aH2O where x and y are positive integers greater than 0, the sum of which is 3 and a is a number from 0 to 2, e.g. Na2HPO4, NaH2PO4 and at least one alkali metal carbonate, bicarbonate, sesquicarbonate or a mixture thereof. Specified phosphoric acids are ortho-, pyro-, meta-, and tripolyphosphoric acids, and phospholeum, a concentrated phosphoric acid having a P2O5 content equivalent to 105% H3PO4. When the latter is reacted with soda ash the product contains Na4P2O7. "Light" and "Dense" ash are the preferred alkali metal carbonate-containing materials reacted with phosphoric acid. Non-ionic, cationic and anionic organic surfactants, which may be either in liquid or in solid form, may be added to the detergent composition together with the phosphoric acid. Exemplified non-ionic surfactants are alkyl aryl polyether alcohol, alkyl aryl polyethylene glycol ether, polyoxyethylene ether, polyoxyethylenethioether, polyoxyethylene ester of mixed fatty and resin acids, fatty alkylol amine condensates, alkyl aryl polyethylene glycol, alkyl polyoxyethylene alcohol, polyethanolamine fatty acid condensate, amino fatty ester, aromatic polyglycol ether condensate, polyethylene glycol tert-dodecyl thioether, and a secondary amide of lauric acid. Specified anionic surfactants are alkyl aryl sulfonates, decyl benzene sodium sulfonate, sodium lorol sulfoacetate, alkyl sulfates, sodium lorol sulfate, triethanolamine salt of alcohol sulfates, N-octadecyl disodium sulfo-succinamate, fatty amide sulfate, sodium palmitoyl methylaurate, amidoalkane sulphonates, sodium oleyl p-anisidine sulfonate, a mixture of an alkyl aryl sulfonate and an alkanolamide, lauroyl imidazolene, sodium dodecyl toluene sulfonate, and the sodium salt of alkyl aryl polyether sulfate. Cationic surfactants exemplified comprise quaternary ammonium halides, alkyl imidazolenes, alkanol alkyl imidazolenes, CH3(CH2)n-COOCH2CH2 <FORM:1012488/C4-C5/1> and lauryl pyridinium chloride. Solid and liquid alkali metal silicates may also be added to the "light" ash after phosphoric acid has been added thereto. Specification 1,005,400 is referred to.ALSO:A method of preparing a dry, free-flowing detergent composition comprises dispersing a phosphoric acid in a body of dry solid particles of an alkali-metal-carbonate-containing material in a proportion in which the M2CO3: H3PO4 mole ratio (M being alkali metal) is at least 1.5 : 1, agitating the mixture while maintaining it at a temperature not substantially in excess of 104 DEG C., and recovering the resulting dry free-flowing product characterized by an M2O : P2O5 mole ratio greater than 3 : 1 and a pH, as a 1% w/v aqueous solution, greater than 7.5. The composition contains at least one phosphate having the formula MxHyPO4.aH2O, where x and y are positive integers greater than 0, the sum of which is 3 and a is a number from 0 to 2, e.g. Na2HPO4 or NaH2PO4, and at least one alkal metal carbonate, bicarbonate, sesquicarbonate or a mixture thereof. Specified phosphoric acids which may be used are ortho-, pyro-, meta-, and tripoly-phosphoric acids, and phospholeum, a concentrated phosphoric acid having a P2O5 content equivalent to 105% H3PO4. When the latter is reacted with soda ash, the product contains Na4P2O7, tetrasodium pyrophosphate. The preferred alkali-metal-carbonate-containing materials reacted with the phosphoric acid are sodium carbonates known as "light ash" and "dense ash." In a typical example (Example 20), phospholeum is added to granular light ash in a Na2CO3 : H3PO4 mole ratio o 2 : 1 to give a product having a Na2O : P2O5 ratio of 4 : 1. Specification 1,005,400 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US133773A US3223646A (en) | 1961-08-25 | 1961-08-25 | Dry free-flowing detergent composition and method of preparation |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1012488A true GB1012488A (en) | 1965-12-08 |
Family
ID=22460239
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB32481/62A Expired GB1012488A (en) | 1961-08-25 | 1962-08-23 | Improvements in or relating to detergent compositions |
Country Status (7)
Country | Link |
---|---|
US (1) | US3223646A (en) |
BE (1) | BE621716A (en) |
CA (1) | CA718382A (en) |
DE (1) | DE1467017A1 (en) |
FR (1) | FR1331295A (en) |
GB (1) | GB1012488A (en) |
NL (1) | NL282471A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4382825A (en) * | 1981-07-08 | 1983-05-10 | Amchem Products, Inc. | Alkaline cleaner for ferrous-based metal surfaces |
US6820776B2 (en) | 2001-03-13 | 2004-11-23 | Henkel Kommanditgesellschaft Auf Aktien | Device for discharging a spreadable material |
US6939070B2 (en) | 2000-11-07 | 2005-09-06 | Henkel Kommandirgesellschaft Auf Aktien | Device for receiving and dispensing a coatable material |
DE202022104348U1 (en) | 2021-12-17 | 2022-08-09 | Guangdong Shen Zhan Industry Co., Ltd. | Water-based UV curing cathodic electrophoretic coating |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3361523A (en) * | 1963-03-19 | 1968-01-02 | Monsanto Co | Method for producing phosphates |
GB1007927A (en) * | 1963-08-21 | 1965-10-22 | Holt Proucts Ltd | Improvements in or relating to the inhibition of corrosion of metals |
US3423322A (en) * | 1964-07-23 | 1969-01-21 | Stauffer Chemical Co | Tableted detergents having improved green strength |
US3425948A (en) * | 1966-01-03 | 1969-02-04 | Wyandotte Chemicals Corp | Composition and process for light-weight surfactant products |
GB1431271A (en) * | 1972-04-24 | 1976-04-07 | Unilever Ltd | Detergent compositions |
DE2820554A1 (en) * | 1978-05-11 | 1979-11-22 | Hoechst Ag | DETERGENTS AND DETERGENTS |
EP1322737A2 (en) * | 2000-09-19 | 2003-07-02 | Huntsman Petrochemical Corporation | Alkyl toluene sulfonate detergents |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2515880A (en) * | 1950-07-18 | Production of granular detergent | ||
US2351559A (en) * | 1944-06-13 | Process for the preparation of | ||
US1642244A (en) * | 1922-10-31 | 1927-09-13 | Grasselli Chemical Co | Process of making sodium phosphates |
US1648656A (en) * | 1927-01-14 | 1927-11-08 | Armour Fertilizer Works | Manufacture of disodium phosphate |
US1921505A (en) * | 1929-01-21 | 1933-08-08 | Heinz H Chesny | Low apparent density sodium carbonate |
US2017828A (en) * | 1932-05-26 | 1935-10-15 | Swann Res Inc | Process for producing disodium phosphate |
US1961127A (en) * | 1932-08-09 | 1934-06-05 | Warner Chemical Company | Making disodium phosphate |
US2502881A (en) * | 1945-10-17 | 1950-04-04 | Parker Elizabeth Weston | Household cleaning composition |
US2811419A (en) * | 1953-03-21 | 1957-10-29 | Knapsack Ag | Process for producing monomeric phosphates |
GB886217A (en) * | 1959-06-13 | 1962-01-03 | Knapsack Ag | Process for the manufacture of reaction products from phosphoric acid and sodium carbonate |
-
0
- NL NL282471D patent/NL282471A/xx unknown
- BE BE621716D patent/BE621716A/xx unknown
- CA CA718382A patent/CA718382A/en not_active Expired
-
1961
- 1961-08-25 US US133773A patent/US3223646A/en not_active Expired - Lifetime
-
1962
- 1962-08-23 GB GB32481/62A patent/GB1012488A/en not_active Expired
- 1962-08-24 DE DE19621467017 patent/DE1467017A1/en active Pending
- 1962-08-24 FR FR907717A patent/FR1331295A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4382825A (en) * | 1981-07-08 | 1983-05-10 | Amchem Products, Inc. | Alkaline cleaner for ferrous-based metal surfaces |
US6939070B2 (en) | 2000-11-07 | 2005-09-06 | Henkel Kommandirgesellschaft Auf Aktien | Device for receiving and dispensing a coatable material |
US6820776B2 (en) | 2001-03-13 | 2004-11-23 | Henkel Kommanditgesellschaft Auf Aktien | Device for discharging a spreadable material |
DE202022104348U1 (en) | 2021-12-17 | 2022-08-09 | Guangdong Shen Zhan Industry Co., Ltd. | Water-based UV curing cathodic electrophoretic coating |
Also Published As
Publication number | Publication date |
---|---|
FR1331295A (en) | 1963-06-28 |
DE1467017A1 (en) | 1969-01-23 |
BE621716A (en) | |
CA718382A (en) | 1965-09-21 |
NL282471A (en) | |
US3223646A (en) | 1965-12-14 |
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