FR3122182B1 - Composition de polyuréthane thermoplastique et de copolymère à blocs polyamides et à blocs polyéthers comprenant des bouts de chaîne amines - Google Patents

Composition de polyuréthane thermoplastique et de copolymère à blocs polyamides et à blocs polyéthers comprenant des bouts de chaîne amines Download PDF

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Publication number
FR3122182B1
FR3122182B1 FR2104203A FR2104203A FR3122182B1 FR 3122182 B1 FR3122182 B1 FR 3122182B1 FR 2104203 A FR2104203 A FR 2104203A FR 2104203 A FR2104203 A FR 2104203A FR 3122182 B1 FR3122182 B1 FR 3122182B1
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France
Prior art keywords
blocks
thermoplastic polyurethane
composition
copolymer
chain ends
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Application number
FR2104203A
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English (en)
French (fr)
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FR3122182A1 (fr
Inventor
Florent Abgrall
Thomas Prenveille
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Arkema France SA
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Arkema France SA
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Publication date
Priority to FR2104203A priority Critical patent/FR3122182B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to KR1020237039995A priority patent/KR20230173180A/ko
Priority to JP2023564156A priority patent/JP2024517424A/ja
Priority to CN202280040244.5A priority patent/CN117425699A/zh
Priority to US18/556,037 priority patent/US20240240018A1/en
Priority to PCT/FR2022/050771 priority patent/WO2022223936A1/fr
Priority to EP22735517.9A priority patent/EP4326819A1/fr
Publication of FR3122182A1 publication Critical patent/FR3122182A1/fr
Application granted granted Critical
Publication of FR3122182B1 publication Critical patent/FR3122182B1/fr
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/02Polyureas
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • C08L75/06Polyurethanes from polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203Polyhydroxy compounds
    • C08G18/3206Polyhydroxy compounds aliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225Polyamines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L87/00Compositions of unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
    • C08L87/005Block or graft polymers not provided for in groups C08L1/00 - C08L85/04
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2075/00Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
    • B29K2075/02Polyureas
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00Compositions for reaction injection moulding processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/40Polyamides containing oxygen in the form of ether groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Thermal Sciences (AREA)
  • Polyamides (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
FR2104203A 2021-04-22 2021-04-22 Composition de polyuréthane thermoplastique et de copolymère à blocs polyamides et à blocs polyéthers comprenant des bouts de chaîne amines Active FR3122182B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR2104203A FR3122182B1 (fr) 2021-04-22 2021-04-22 Composition de polyuréthane thermoplastique et de copolymère à blocs polyamides et à blocs polyéthers comprenant des bouts de chaîne amines
JP2023564156A JP2024517424A (ja) 2021-04-22 2022-04-22 熱可塑性ポリウレタン、ならびにアミン鎖末端を含むポリアミドブロックおよびポリエーテルブロックを有する共重合体を含有する組成物
CN202280040244.5A CN117425699A (zh) 2021-04-22 2022-04-22 含有热塑性聚氨酯与包含胺链端的具有聚酰胺嵌段和聚醚嵌段的共聚物的组合物
US18/556,037 US20240240018A1 (en) 2021-04-22 2022-04-22 Composition containing thermoplastic polyurethane and a copolymer having polyamide blocks and polyether blocks comprising amine chain ends
KR1020237039995A KR20230173180A (ko) 2021-04-22 2022-04-22 열가소성 폴리우레탄, 및 아민 사슬 말단을 포함하는 폴리에테르 블록 및 폴리아미드 블록을 갖는 공중합체를 함유하는 조성물
PCT/FR2022/050771 WO2022223936A1 (fr) 2021-04-22 2022-04-22 Composition de polyuréthane thermoplastique et de copolymère à blocs polyamides et à blocs polyéthers comprenant des bouts de chaîne amines
EP22735517.9A EP4326819A1 (fr) 2021-04-22 2022-04-22 Composition de polyuréthane thermoplastique et de copolymère à blocs polyamides et à blocs polyéthers comprenant des bouts de chaîne amines

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2104203 2021-04-22
FR2104203A FR3122182B1 (fr) 2021-04-22 2021-04-22 Composition de polyuréthane thermoplastique et de copolymère à blocs polyamides et à blocs polyéthers comprenant des bouts de chaîne amines

Publications (2)

Publication Number Publication Date
FR3122182A1 FR3122182A1 (fr) 2022-10-28
FR3122182B1 true FR3122182B1 (fr) 2023-03-24

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FR2104203A Active FR3122182B1 (fr) 2021-04-22 2021-04-22 Composition de polyuréthane thermoplastique et de copolymère à blocs polyamides et à blocs polyéthers comprenant des bouts de chaîne amines

Country Status (7)

Country Link
US (1) US20240240018A1 (https=)
EP (1) EP4326819A1 (https=)
JP (1) JP2024517424A (https=)
KR (1) KR20230173180A (https=)
CN (1) CN117425699A (https=)
FR (1) FR3122182B1 (https=)
WO (1) WO2022223936A1 (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119931020A (zh) * 2025-03-13 2025-05-06 中国科学院长春应用化学研究所 一种改性聚醚胺及其制备方法和应用、一种尼龙弹性体
CN120209254B (zh) * 2025-05-28 2025-09-05 陕西振铭时代科技有限公司 一种高耐磨的聚氨酯材料及其制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5652326A (en) 1993-03-03 1997-07-29 Sanyo Chemical Industries, Ltd. Polyetheresteramide and antistatic resin composition
FR2831175B1 (fr) 2001-10-22 2004-02-13 Salomon Sa Agent de compatibilisation de polyurethannes, materiau thermoplastique contenant un tel agent et utilisation de ce materiau pour la confection d'articles de sport
JP4193588B2 (ja) 2003-05-26 2008-12-10 宇部興産株式会社 ポリアミド系エラストマー
US7056975B2 (en) 2003-05-27 2006-06-06 Ube Industries, Ltd. Thermoplastic resin composition having improved resistance to hydrolysis
JP4161802B2 (ja) 2003-05-27 2008-10-08 宇部興産株式会社 ポリアミド組成物
US7383647B2 (en) 2005-03-10 2008-06-10 New Balance Athletic Shoe, Inc Mechanical cushioning system for footwear
CN101141894B (zh) 2005-03-10 2010-09-01 新平衡运动鞋公司 鞋的机械减震系统
JP5393036B2 (ja) 2008-02-14 2014-01-22 花王株式会社 熱可塑性樹脂組成物
JP5104457B2 (ja) * 2008-03-27 2012-12-19 宇部興産株式会社 多層構造体
JP2011126243A (ja) * 2009-12-21 2011-06-30 Ube Industries Ltd 多層構造体
JP5741139B2 (ja) 2011-03-31 2015-07-01 宇部興産株式会社 ポリウレタン樹脂組成物及びその組成物を含む耐衝撃性成形品

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Publication number Publication date
JP2024517424A (ja) 2024-04-22
CN117425699A (zh) 2024-01-19
FR3122182A1 (fr) 2022-10-28
EP4326819A1 (fr) 2024-02-28
KR20230173180A (ko) 2023-12-26
US20240240018A1 (en) 2024-07-18
WO2022223936A1 (fr) 2022-10-27

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