FR3119621B1 - Nouveau procede de fabrication des composants de la pheromone de la mineuse de la tomate - Google Patents
Nouveau procede de fabrication des composants de la pheromone de la mineuse de la tomate Download PDFInfo
- Publication number
- FR3119621B1 FR3119621B1 FR2101323A FR2101323A FR3119621B1 FR 3119621 B1 FR3119621 B1 FR 3119621B1 FR 2101323 A FR2101323 A FR 2101323A FR 2101323 A FR2101323 A FR 2101323A FR 3119621 B1 FR3119621 B1 FR 3119621B1
- Authority
- FR
- France
- Prior art keywords
- pheromone
- miner
- tomato
- manufacturing
- components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000003016 pheromone Substances 0.000 title abstract 3
- 235000007688 Lycopersicon esculentum Nutrition 0.000 title 1
- 240000003768 Solanum lycopersicum Species 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 241001389006 Tuta absoluta Species 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 239000007818 Grignard reagent Substances 0.000 abstract 1
- DMPBOULTBKYSQE-BAHYSTIISA-N [(1E,3E,5E)-tetradeca-1,3,5-trienyl] acetate Chemical compound CCCCCCCC\C=C\C=C\C=C\OC(C)=O DMPBOULTBKYSQE-BAHYSTIISA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 150000004795 grignard reagents Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- -1 pentene-1,5-diyl Chemical group 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/12—Acetic acid esters
- C07C69/14—Acetic acid esters of monohydroxylic compounds
- C07C69/145—Acetic acid esters of monohydroxylic compounds of unsaturated alcohols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P17/00—Pest repellants
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
La présente invention concerne Procédé de synthèse de phéromone de formule générale choisie dans le groupe comprenant les composés (I) et (I’), seuls ou en mélange : (I) (I’) comprenant la réaction du diacétate de (2E)-pentène-1,5-diyle avec au moins un réactif de Grignard en présence d’un catalyseur à base de cuivre. Le procédé selon l’invention s’applique particulièrement à la synthèse sélective de la phéromone de la mineuse de la tomate (Tuta absoluta) comprenant : le (3E,8Z,11Z)-tetradecatrien-1-yl acetate et le (3E,8Z)-tetradecadien-1-yl acetate.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2101323A FR3119621B1 (fr) | 2021-02-11 | 2021-02-11 | Nouveau procede de fabrication des composants de la pheromone de la mineuse de la tomate |
EP22708978.6A EP4291169A1 (fr) | 2021-02-11 | 2022-02-11 | Nouveau procede de fabrication des composants de la pheromone de la mineuse de la tomate |
PCT/FR2022/050251 WO2022171965A1 (fr) | 2021-02-11 | 2022-02-11 | Nouveau procede de fabrication des composants de la pheromone de la mineuse de la tomate |
CN202280014720.6A CN116916898A (zh) | 2021-02-11 | 2022-02-11 | 制造番茄潜叶虫信息素成分的新方法 |
US18/276,763 US20240140902A1 (en) | 2021-02-11 | 2022-02-11 | Novel method for manufacturing tomato leafminer pheromone components |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2101323 | 2021-02-11 | ||
FR2101323A FR3119621B1 (fr) | 2021-02-11 | 2021-02-11 | Nouveau procede de fabrication des composants de la pheromone de la mineuse de la tomate |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3119621A1 FR3119621A1 (fr) | 2022-08-12 |
FR3119621B1 true FR3119621B1 (fr) | 2023-09-29 |
Family
ID=75339917
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR2101323A Active FR3119621B1 (fr) | 2021-02-11 | 2021-02-11 | Nouveau procede de fabrication des composants de la pheromone de la mineuse de la tomate |
Country Status (5)
Country | Link |
---|---|
US (1) | US20240140902A1 (fr) |
EP (1) | EP4291169A1 (fr) |
CN (1) | CN116916898A (fr) |
FR (1) | FR3119621B1 (fr) |
WO (1) | WO2022171965A1 (fr) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5680009B2 (ja) | 2012-03-13 | 2015-03-04 | 信越化学工業株式会社 | 5−アセトキシ−(e3)−3−ペンテニル−メトキシメチルエーテルを用いた(e3)−3−アルケニルアセタートの製造方法 |
FR3032600B1 (fr) | 2015-02-18 | 2020-04-03 | Melchior Material And Life Science France | Particules contenant des pheromones et procede de fabrication |
-
2021
- 2021-02-11 FR FR2101323A patent/FR3119621B1/fr active Active
-
2022
- 2022-02-11 CN CN202280014720.6A patent/CN116916898A/zh active Pending
- 2022-02-11 WO PCT/FR2022/050251 patent/WO2022171965A1/fr active Application Filing
- 2022-02-11 EP EP22708978.6A patent/EP4291169A1/fr active Pending
- 2022-02-11 US US18/276,763 patent/US20240140902A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
FR3119621A1 (fr) | 2022-08-12 |
US20240140902A1 (en) | 2024-05-02 |
EP4291169A1 (fr) | 2023-12-20 |
CN116916898A (zh) | 2023-10-20 |
WO2022171965A1 (fr) | 2022-08-18 |
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Year of fee payment: 2 |
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PLSC | Publication of the preliminary search report |
Effective date: 20220812 |
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PLFP | Fee payment |
Year of fee payment: 4 |