FR3115793B1 - Procédé de carbonisation hydrothermale. - Google Patents

Procédé de carbonisation hydrothermale. Download PDF

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Publication number
FR3115793B1
FR3115793B1 FR2011305A FR2011305A FR3115793B1 FR 3115793 B1 FR3115793 B1 FR 3115793B1 FR 2011305 A FR2011305 A FR 2011305A FR 2011305 A FR2011305 A FR 2011305A FR 3115793 B1 FR3115793 B1 FR 3115793B1
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FR
France
Prior art keywords
production rate
hydrothermal carbonization
biomass
reactor
organic matter
Prior art date
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Active
Application number
FR2011305A
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English (en)
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FR3115793A1 (fr
Inventor
Jean-Louis Bourdais
Marlène Choo-Kun
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Suez International SAS
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Suez Groupe SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suez Groupe SAS filed Critical Suez Groupe SAS
Priority to FR2011305A priority Critical patent/FR3115793B1/fr
Priority to EP21801138.5A priority patent/EP4240818A1/fr
Priority to US18/033,507 priority patent/US20230323225A1/en
Priority to AU2021373274A priority patent/AU2021373274A1/en
Priority to CN202180072313.6A priority patent/CN116507697A/zh
Priority to PCT/EP2021/080464 priority patent/WO2022096484A1/fr
Publication of FR3115793A1 publication Critical patent/FR3115793A1/fr
Application granted granted Critical
Publication of FR3115793B1 publication Critical patent/FR3115793B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00—Treating solid fuels to improve their combustion
    • C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
    • C10L9/086—Hydrothermal carbonization
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J1/00—Production of fuel gases by carburetting air or other gases without pyrolysis
    • C10J1/26—Production of fuel gases by carburetting air or other gases without pyrolysis using raised temperatures or pressures
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/10—Treatment of sludge; Devices therefor by pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/122—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using filter presses
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/02—Temperature
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/03—Pressure
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/44—Time
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C10J2300/0923—Sludge, e.g. from water treatment plant
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1612—CO2-separation and sequestration, i.e. long time storage
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/183—Non-continuous or semi-continuous processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/58—Control or regulation of the fuel preparation of upgrading process
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/60—Measuring or analysing fractions, components or impurities or process conditions during preparation or upgrading of a fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Mechanical Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Treatment Of Sludge (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

L’invention concerne un procédé de carbonisation hydrothermale de biomasse contenant de la matière organique, ledit procédé comprenant : - l’injection de la biomasse, d’un fluide caloporteur et d’un réactif dans un réacteur (1), - la mise en circulation d’un mélange constitué par la biomasse, le fluide caloporteur et le réactif sous des conditions de pression et températures spécifiques permettant la transformation de la matière organique par carbonisation hydrothermale. L’invention consiste en ce que : 1) on détermine le taux de production de gaz émis Te lors de la réaction de carbonisation hydrothermale ; 2) on compare ledit taux de production de gaz émis Te déterminé avec une valeur de taux de production de gaz de consigne prédéfinie Tc, et3) on ajuste au moins l’un des paramètres de pilotage de la réaction choisi parmi la température au sein du réacteur (1), la quantité de réactif injecté, et le temps de résidence dans le réacteur, pour ajuster le taux de production de gaz émis Te, de sorte que la valeur de ce taux de production de gaz émis Te tend à être égale à la valeur du taux de production de gaz de consigne Tc. Application au traitement de la biomasse contenant de la matière organique. Figure 1.
FR2011305A 2020-11-04 2020-11-04 Procédé de carbonisation hydrothermale. Active FR3115793B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR2011305A FR3115793B1 (fr) 2020-11-04 2020-11-04 Procédé de carbonisation hydrothermale.
EP21801138.5A EP4240818A1 (fr) 2020-11-04 2021-11-03 Procédé de carbonisation hydrothermale
US18/033,507 US20230323225A1 (en) 2020-11-04 2021-11-03 Hydrothermal carbonisation method
AU2021373274A AU2021373274A1 (en) 2020-11-04 2021-11-03 Hydrothermal carbonisation method
CN202180072313.6A CN116507697A (zh) 2020-11-04 2021-11-03 水热碳化方法
PCT/EP2021/080464 WO2022096484A1 (fr) 2020-11-04 2021-11-03 Procédé de carbonisation hydrothermale

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2011305 2020-11-04
FR2011305A FR3115793B1 (fr) 2020-11-04 2020-11-04 Procédé de carbonisation hydrothermale.

Publications (2)

Publication Number Publication Date
FR3115793A1 FR3115793A1 (fr) 2022-05-06
FR3115793B1 true FR3115793B1 (fr) 2023-11-24

Family

ID=74347271

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2011305A Active FR3115793B1 (fr) 2020-11-04 2020-11-04 Procédé de carbonisation hydrothermale.

Country Status (6)

Country Link
US (1) US20230323225A1 (fr)
EP (1) EP4240818A1 (fr)
CN (1) CN116507697A (fr)
AU (1) AU2021373274A1 (fr)
FR (1) FR3115793B1 (fr)
WO (1) WO2022096484A1 (fr)

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008047883B4 (de) * 2008-09-18 2011-06-01 Agrokraft Gmbh Vorrichtung und Verfahren zur Behandlung von Biomasse
DE102014103346A1 (de) 2014-03-12 2015-09-17 Ava-Co2 Schweiz Ag Verfahren und Vorrichtung zur Durchführung einer hydrothermalen Karbonisierungsreaktion und Verwendung eines Sensors oder Analysegeräts hierfür
AU2016275154A1 (en) * 2015-06-11 2017-12-07 Tyton Biosciences, Llc Process and system for producing pulp, energy, and bioderivatives from plant-based and recycled materials
CA3004429A1 (fr) * 2015-11-10 2017-05-18 Board Of Regents Of The Nevada System Of Higher Education, On Behalf Of The University Of Nevada, Reno Systeme de traitement hydrothermique de biomasse humide
DE102016125286A1 (de) 2016-12-21 2018-06-21 Universität Rostock Verfahren zur herstellung von biokohle
ES2797113T3 (es) 2017-02-20 2020-12-01 Htcycle Ag Procedimiento para llevar a cabo una reacción de carbonización hidrotermal
CN107699306B (zh) * 2017-10-30 2020-04-03 中国科学院广州能源研究所 一种高氮生物质废弃物作为燃料利用的提质脱氮改性方法

Also Published As

Publication number Publication date
CN116507697A (zh) 2023-07-28
EP4240818A1 (fr) 2023-09-13
AU2021373274A1 (en) 2023-05-18
WO2022096484A1 (fr) 2022-05-12
US20230323225A1 (en) 2023-10-12
FR3115793A1 (fr) 2022-05-06

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