FR3114101B1 - Composition d’adhésif acrylique avec un copolymère d’éthylène/acide - Google Patents

Composition d’adhésif acrylique avec un copolymère d’éthylène/acide Download PDF

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Publication number
FR3114101B1
FR3114101B1 FR2009334A FR2009334A FR3114101B1 FR 3114101 B1 FR3114101 B1 FR 3114101B1 FR 2009334 A FR2009334 A FR 2009334A FR 2009334 A FR2009334 A FR 2009334A FR 3114101 B1 FR3114101 B1 FR 3114101B1
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FR
France
Prior art keywords
adhesive composition
ethylene
sensitive adhesive
acid copolymer
aqueous pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2009334A
Other languages
English (en)
Other versions
FR3114101A1 (fr
Inventor
Joseph B Binder
Sehban N Ozair
David L Malotky
Saswati Pujari
Isabelle Uhl
Vinita Yadav
Moglia Robert S Mogliarobert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Rohm and Haas Co
Original Assignee
Dow Global Technologies LLC
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC, Rohm and Haas Co filed Critical Dow Global Technologies LLC
Priority to FR2009334A priority Critical patent/FR3114101B1/fr
Priority to TW110133925A priority patent/TW202212518A/zh
Priority to ARP210102545A priority patent/AR123506A1/es
Priority to CN202180062292.XA priority patent/CN116057087A/zh
Priority to US18/245,435 priority patent/US20230340302A1/en
Priority to PCT/US2021/050242 priority patent/WO2022060718A1/fr
Priority to MX2023003012A priority patent/MX2023003012A/es
Priority to EP21778327.3A priority patent/EP4214249A1/fr
Priority to JP2023516765A priority patent/JP2023545912A/ja
Publication of FR3114101A1 publication Critical patent/FR3114101A1/fr
Application granted granted Critical
Publication of FR3114101B1 publication Critical patent/FR3114101B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/385—Acrylic polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/062—Copolymers with monomers not covered by C09J133/06
    • C09J133/066—Copolymers with monomers not covered by C09J133/06 containing -OH groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/414—Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of a copolymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Adhesive Tapes (AREA)

Abstract

La présente invention concerne une composition aqueuse d’adhésif sensible à la pression. Dans un mode de réalisation, la composition aqueuse d’adhésif sensible à la pression comprend (A) une dispersion acrylique composée de particules (i) d’un polymère acrylique ayant une température de transition vitreuse (Tg) inférieure à -20 °C, et (ii) d’un tensioactif. La composition aqueuse d’adhésif sensible à la pression comprend également (B) une dispersion d’éthylène-acide composée (i) de particules d’un copolymère d’éthylène-acide présentant de 3 % en poids à moins de 50 % en poids d’un comonomère acide et un indice de fluidité à chaud de 1 g/10 min à 100 g/10 min, et (ii) d’un dispersant et/ou d’un agent de neutralisation. L’invention concerne en outre des articles avec la composition aqueuse d’adhésif sensible à la pression.
FR2009334A 2020-09-15 2020-09-15 Composition d’adhésif acrylique avec un copolymère d’éthylène/acide Active FR3114101B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR2009334A FR3114101B1 (fr) 2020-09-15 2020-09-15 Composition d’adhésif acrylique avec un copolymère d’éthylène/acide
TW110133925A TW202212518A (zh) 2020-09-15 2021-09-11 具有乙烯／酸共聚物之丙烯酸類黏著劑組合物
CN202180062292.XA CN116057087A (zh) 2020-09-15 2021-09-14 具有乙烯/酸共聚物的丙烯酸类粘合剂组合物
US18/245,435 US20230340302A1 (en) 2020-09-15 2021-09-14 Acrylic-Based Adhesive Composition with Ethylene/Acid Copolymer
ARP210102545A AR123506A1 (es) 2020-09-15 2021-09-14 Composición adhesiva a base de acrílico con copolímero de etileno y ácido
PCT/US2021/050242 WO2022060718A1 (fr) 2020-09-15 2021-09-14 Composition adhésive à base d'acrylique avec un copolymère éthylène/acide
MX2023003012A MX2023003012A (es) 2020-09-15 2021-09-14 Composicion adhesiva a base de acrilico con copolimero de etileno/acido.
EP21778327.3A EP4214249A1 (fr) 2020-09-15 2021-09-14 Composition adhésive à base d'acrylique avec un copolymère éthylène/acide
JP2023516765A JP2023545912A (ja) 2020-09-15 2021-09-14 エチレン／酸コポリマーを有するアクリル系接着剤組成物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2009334 2020-09-15
FR2009334A FR3114101B1 (fr) 2020-09-15 2020-09-15 Composition d’adhésif acrylique avec un copolymère d’éthylène/acide

Publications (2)

Publication Number Publication Date
FR3114101A1 FR3114101A1 (fr) 2022-03-18
FR3114101B1 true FR3114101B1 (fr) 2023-11-03

Family

ID=74859962

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2009334A Active FR3114101B1 (fr) 2020-09-15 2020-09-15 Composition d’adhésif acrylique avec un copolymère d’éthylène/acide

Country Status (9)

Country Link
US (1) US20230340302A1 (fr)
EP (1) EP4214249A1 (fr)
JP (1) JP2023545912A (fr)
CN (1) CN116057087A (fr)
AR (1) AR123506A1 (fr)
FR (1) FR3114101B1 (fr)
MX (1) MX2023003012A (fr)
TW (1) TW202212518A (fr)
WO (1) WO2022060718A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102382699B1 (ko) * 2019-12-20 2022-04-04 주식회사 포스코 전기강판 접착 코팅 조성물, 전기강판 적층체 및 이의 제조 방법

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4912169A (en) 1987-10-14 1990-03-27 Rohm And Haas Company Adhesive compositions containing low molecular weight polymer additives
JP2642149B2 (ja) * 1988-07-13 1997-08-20 株式会社クラレ 感圧性接着剤
JPH04253784A (ja) * 1991-02-05 1992-09-09 Hoechst Gosei Kk 感圧性接着剤
US6657011B2 (en) 2000-09-14 2003-12-02 Rohm And Haas Company Adhesive compositions containing low molecular weight polymeric additives
KR20140019360A (ko) * 2011-03-01 2014-02-14 듀폰-미츠이 폴리케미칼 가부시키가이샤 감압형 점착 필름 또는 시트, 표면 보호 필름 또는 시트, 및 물품의 표면을 보호하기 위하여 사용하는 방법
US9605188B2 (en) * 2012-02-06 2017-03-28 Basf Se Aqueous polymer dispersion suitable for application as tackifier for adhesives and preparable by emulsion polymerization based on C1 to C20 alkyl (meth)acrylates
US10160891B2 (en) * 2012-02-08 2018-12-25 Honeywell International Inc. High performance water-based tackified acrylic pressure sensitive adhesives
US20160145806A1 (en) * 2013-03-20 2016-05-26 Byeong Seok RHEE Method for preparing environmentally friendly paper coating agent by using water dispersible resin of ethylene-(meth)acrylic acid polymer, and use thereof
EP3131859B1 (fr) * 2014-04-15 2021-08-11 Honeywell International Inc. Compositions adhésives aqueuses à haute performance et applications
US20200079979A1 (en) * 2017-03-13 2020-03-12 Rohm And Haas Company Water-based pressure sensitive adhesive compositions and methods of making same
BR112020004247B1 (pt) * 2017-09-05 2023-12-12 Rohm And Haas Company Composição adesiva sensível à pressão e método para preparar uma composição adesiva sensível à pressão
CN113508166A (zh) * 2018-12-27 2021-10-15 3M创新有限公司 可热熔加工的(甲基)丙烯酸酯基医用粘合剂

Also Published As

Publication number Publication date
CN116057087A (zh) 2023-05-02
US20230340302A1 (en) 2023-10-26
AR123506A1 (es) 2022-12-07
TW202212518A (zh) 2022-04-01
MX2023003012A (es) 2023-04-10
JP2023545912A (ja) 2023-11-01
FR3114101A1 (fr) 2022-03-18
WO2022060718A1 (fr) 2022-03-24
EP4214249A1 (fr) 2023-07-26

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