FR3111353B1 - Compositions de moulage à base de polyamide, de fibres de carbone et de billes de verre creuses et leur utilisation - Google Patents

Compositions de moulage à base de polyamide, de fibres de carbone et de billes de verre creuses et leur utilisation Download PDF

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Publication number
FR3111353B1
FR3111353B1 FR2006209A FR2006209A FR3111353B1 FR 3111353 B1 FR3111353 B1 FR 3111353B1 FR 2006209 A FR2006209 A FR 2006209A FR 2006209 A FR2006209 A FR 2006209A FR 3111353 B1 FR3111353 B1 FR 3111353B1
Authority
FR
France
Prior art keywords
carbon fibers
glass beads
hollow glass
polyamide
molding compositions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2006209A
Other languages
English (en)
Other versions
FR3111353A1 (fr
Inventor
Mathieu Sabard
Fabrice Glasson
Cristian Tittoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR2006209A priority Critical patent/FR3111353B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to EP21737719.1A priority patent/EP4165133A1/fr
Priority to CN202180042545.7A priority patent/CN115916900A/zh
Priority to JP2022575733A priority patent/JP2023529886A/ja
Priority to KR1020237000983A priority patent/KR20230023738A/ko
Priority to US18/001,138 priority patent/US20230212393A1/en
Priority to PCT/FR2021/051056 priority patent/WO2021255372A1/fr
Publication of FR3111353A1 publication Critical patent/FR3111353A1/fr
Application granted granted Critical
Publication of FR3111353B1 publication Critical patent/FR3111353B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C08K7/28—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/12—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of short lengths, e.g. chopped filaments, staple fibres or bristles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16—Fillers
    • B29K2105/165—Hollow fillers, e.g. microballoons or expanded particles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/40—Polyamides containing oxygen in the form of ether groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

La présente invention concerne une composition de moulage, comprenant en poids : (A) de 38 à 79,5 % d’au moins un polyamide aliphatique semi-cristallin, (B) de 10 à 20% de fibres de carbone, (C) de 5 à 20% de billes de verre creuses; et (D) de 5,5 à 20% d’au moins un modifiant choc présentant un module de flexion inférieur à 200 MPa, en particulier inférieur à 100 MPa, tel que mesuré selon la norme ISO 178 :2010, à 23°C (E) de 0 à 2% en poids, de préférence 0,1 à 1% en poids d’au moins un additif, la somme des proportions de chaque constituant (A) + (B) + (C) + (D) + (E) de ladite composition étant égale à 100%.
FR2006209A 2020-06-15 2020-06-15 Compositions de moulage à base de polyamide, de fibres de carbone et de billes de verre creuses et leur utilisation Active FR3111353B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR2006209A FR3111353B1 (fr) 2020-06-15 2020-06-15 Compositions de moulage à base de polyamide, de fibres de carbone et de billes de verre creuses et leur utilisation
CN202180042545.7A CN115916900A (zh) 2020-06-15 2021-06-14 基于聚酰胺、碳纤维和中空玻璃珠的模塑组合物及其用途
JP2022575733A JP2023529886A (ja) 2020-06-15 2021-06-14 ポリアミド、炭素繊維および中空のガラスビーズがベースの成形組成物およびその使用
KR1020237000983A KR20230023738A (ko) 2020-06-15 2021-06-14 폴리아미드, 탄소 섬유 및 중공 유리 비드에 기초한 성형 조성물 및 이의 용도
EP21737719.1A EP4165133A1 (fr) 2020-06-15 2021-06-14 Compositions de moulage à base de polyamide, de fibres de carbone et de billes de verre creuses et leur utilisation
US18/001,138 US20230212393A1 (en) 2020-06-15 2021-06-14 Molding compositions based on polyamide, on carbon fibers and on hollow glass beads and use thereof
PCT/FR2021/051056 WO2021255372A1 (fr) 2020-06-15 2021-06-14 Compositions de moulage a base de polyamide, de fibres de carbone et de billes de verre creuses et leur utilisation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2006209A FR3111353B1 (fr) 2020-06-15 2020-06-15 Compositions de moulage à base de polyamide, de fibres de carbone et de billes de verre creuses et leur utilisation
FR2006209 2020-06-15

Publications (2)

Publication Number Publication Date
FR3111353A1 FR3111353A1 (fr) 2021-12-17
FR3111353B1 true FR3111353B1 (fr) 2022-11-11

Family

ID=72356181

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2006209A Active FR3111353B1 (fr) 2020-06-15 2020-06-15 Compositions de moulage à base de polyamide, de fibres de carbone et de billes de verre creuses et leur utilisation

Country Status (7)

Country Link
US (1) US20230212393A1 (fr)
EP (1) EP4165133A1 (fr)
JP (1) JP2023529886A (fr)
KR (1) KR20230023738A (fr)
CN (1) CN115916900A (fr)
FR (1) FR3111353B1 (fr)
WO (1) WO2021255372A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115551941A (zh) * 2020-05-12 2022-12-30 索尔维特殊聚合物美国有限责任公司 热塑性聚合物组合物

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2629090B1 (fr) 1988-03-24 1990-11-23 Atochem Copolymere greffe a base d'alpha-mono-olefine, son procede de fabrication, son application a la fabrication d'alliages thermoplastiques, alliages thermoplastiques obtenus
GB9018144D0 (en) 1990-08-17 1990-10-03 Unilever Plc Polymerisation process
JP3425449B2 (ja) 1993-03-22 2003-07-14 旭化成株式会社 軽量強化樹脂組成物
FR2846332B1 (fr) 2002-10-23 2004-12-03 Atofina Copolymeres transparents a blocs polyamides et blocs polyethers
US7056975B2 (en) 2003-05-27 2006-06-06 Ube Industries, Ltd. Thermoplastic resin composition having improved resistance to hydrolysis
WO2005092961A2 (fr) 2004-03-22 2005-10-06 3M Innovative Properties Company Composite thermoplastique rempli et renforce par des fibres
JP2007119669A (ja) 2005-10-31 2007-05-17 Ube Ind Ltd ポリアミド樹脂組成物
JP2013010847A (ja) 2011-06-29 2013-01-17 Toray Ind Inc 炭素繊維強化樹脂組成物およびその成形品
EP3135731B1 (fr) * 2015-08-31 2017-11-01 Ems-Patent Ag Masses moulees en polyamide et corps de formage ainsi fabriques
CN105820565A (zh) * 2016-05-25 2016-08-03 祥兴(福建)箱包集团有限公司 一种碳纤维增强尼龙复合拉杆箱脚轮
WO2020094624A1 (fr) 2018-11-06 2020-05-14 Ems-Patent Ag Masse moulée de polyamide, corps moulé formé avec celle-ci ainsi que possibilités d'utilisation
CN110105753A (zh) * 2019-03-22 2019-08-09 祥兴(福建)箱包集团有限公司 一种拉杆箱脚轮用碳纤增强尼龙复合材料及其制备方法
CN111040440B (zh) * 2019-12-26 2022-10-28 广州市聚赛龙工程塑料股份有限公司 一种低密度高耐磨尼龙复合材料及其制备方法和应用

Also Published As

Publication number Publication date
EP4165133A1 (fr) 2023-04-19
WO2021255372A1 (fr) 2021-12-23
KR20230023738A (ko) 2023-02-17
US20230212393A1 (en) 2023-07-06
JP2023529886A (ja) 2023-07-12
CN115916900A (zh) 2023-04-04
FR3111353A1 (fr) 2021-12-17

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