FR3106523B1 - Matériau composite thermodurcissable et procédé d’impression associé - Google Patents

Matériau composite thermodurcissable et procédé d’impression associé Download PDF

Info

Publication number
FR3106523B1
FR3106523B1 FR2000807A FR2000807A FR3106523B1 FR 3106523 B1 FR3106523 B1 FR 3106523B1 FR 2000807 A FR2000807 A FR 2000807A FR 2000807 A FR2000807 A FR 2000807A FR 3106523 B1 FR3106523 B1 FR 3106523B1
Authority
FR
France
Prior art keywords
composite material
printing process
thermosetting composite
particles
thermosetting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2000807A
Other languages
English (en)
Other versions
FR3106523A1 (fr
Inventor
Davide Beneventi
Didier Chaussy
Khaoula Bouzidi
Alessandro Gandini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Institut Polytechnique de Grenoble
Original Assignee
Centre National de la Recherche Scientifique CNRS
Institut Polytechnique de Grenoble
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Institut Polytechnique de Grenoble filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR2000807A priority Critical patent/FR3106523B1/fr
Priority to CN202180011106.XA priority patent/CN115244103A/zh
Priority to PCT/EP2021/051761 priority patent/WO2021151893A1/fr
Priority to EP21702014.8A priority patent/EP4097165A1/fr
Priority to US17/794,948 priority patent/US20230347584A1/en
Publication of FR3106523A1 publication Critical patent/FR3106523A1/fr
Application granted granted Critical
Publication of FR3106523B1 publication Critical patent/FR3106523B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/125—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one oxygen atom in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/165—Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00—Processes of additive manufacturing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/005—Lignin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2086/00—Use of specific polymers obtained by polycondensation or polyaddition, not provided for in a single one of main groups B29K2059/00 - B29K2085/00, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16—Fillers
    • B29K2105/162—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2401/00—Use of cellulose, modified cellulose or cellulose derivatives, e.g. viscose, as filler
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2507/00—Use of elements other than metals as filler
    • B29K2507/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/13—Morphological aspects
    • C08G2261/135—Cross-linked structures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/334—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/70—Post-treatment
    • C08G2261/76—Post-treatment crosslinking

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Composite Materials (AREA)
  • Civil Engineering (AREA)
  • Ceramic Engineering (AREA)

Abstract

Matériau composite thermodurcissable et procédé d’impression associé. L’invention concerne un matériau composite thermodurcissable (1) et son procédé d’impression 3D par extrusion, le matériau composite thermodurcissable (1) comprenant un polymère furanique formant une matrice thermodurcissable (10), un solvant (12), et un matériau (11) formé de particules choisies parmi des particules micrométriques, des particules nanométriques, voire un mélange de particules micrométrique et de particules nanométriques, ces particules étant à base d’un composé comprenant plus de 40 % en masse de carbone. Le matériau composite thermodurcissable (1) et son procédé d’impression 3D permettent d’obtenir un objet (3) présentant des tolérances dimensionnelles comprises entre 2,5 et 5% par rapport au modèle numérique, et une résistance aux hautes températures allant jusqu’à 300°C. Le matériau composite thermodurcissable (1) et son procédé d’impression 3D représentent une alternative biosourcée et de coût réduit par rapport aux polymères thermoplastiques synthétiques et leur procédé d’impression usuels. Figure pour l’abrégé : Fig. 2A
FR2000807A 2020-01-28 2020-01-28 Matériau composite thermodurcissable et procédé d’impression associé Active FR3106523B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR2000807A FR3106523B1 (fr) 2020-01-28 2020-01-28 Matériau composite thermodurcissable et procédé d’impression associé
CN202180011106.XA CN115244103A (zh) 2020-01-28 2021-01-26 热固性复合材料及相关打印方法
PCT/EP2021/051761 WO2021151893A1 (fr) 2020-01-28 2021-01-26 Matériau composite thermodurcissable et procédé d'impression associé
EP21702014.8A EP4097165A1 (fr) 2020-01-28 2021-01-26 Matériau composite thermodurcissable et procédé d'impression associé
US17/794,948 US20230347584A1 (en) 2020-01-28 2021-01-26 Thermosetting composite material and associated printing method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2000807A FR3106523B1 (fr) 2020-01-28 2020-01-28 Matériau composite thermodurcissable et procédé d’impression associé
FR2000807 2020-01-28

Publications (2)

Publication Number Publication Date
FR3106523A1 FR3106523A1 (fr) 2021-07-30
FR3106523B1 true FR3106523B1 (fr) 2023-07-28

Family

ID=70008940

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2000807A Active FR3106523B1 (fr) 2020-01-28 2020-01-28 Matériau composite thermodurcissable et procédé d’impression associé

Country Status (5)

Country Link
US (1) US20230347584A1 (fr)
EP (1) EP4097165A1 (fr)
CN (1) CN115244103A (fr)
FR (1) FR3106523B1 (fr)
WO (1) WO2021151893A1 (fr)

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB642245A (en) * 1946-11-12 1950-08-30 Masonite Corp Fibre board and the like containing resins
JP2008247963A (ja) * 2007-03-29 2008-10-16 Mitsubishi Motors Corp リグノセルロース系材料成形体及びその成形方法
DE102014007584A1 (de) * 2014-05-26 2015-11-26 Voxeljet Ag 3D-Umkehrdruckverfahren und Vorrichtung
CA2978556C (fr) * 2015-03-02 2022-02-15 Graphene 3D Lab Inc. Composites thermoplastiques comprenant des polymeres greffes a base de polyethylene oxyde (peo) hydrosolubles utiles pour une fabrication additive tridimensionnelle
CN107227190A (zh) * 2016-03-25 2017-10-03 淄博金安型煤有限公司 生物质型煤用粘合剂及其制备方法
JP2018015955A (ja) * 2016-07-27 2018-02-01 ケーエスエム株式会社 ３ｄプリンター用樹脂組成物
WO2018038769A1 (fr) * 2016-08-22 2018-03-01 Board Of Regents, The University Of Texas System Polymères thermodurcis pouvant être traités à l'état fondu, procédé de synthèse associé et d'utilisation dans l'impression par fabrication de filaments fusionnés
CN106832168B (zh) * 2017-01-17 2019-03-08 石家庄世易糠醛糠醇有限公司 基于石墨烯呋喃树脂的3d打印材料及其制备方法、用途
EP3375819A1 (fr) * 2017-03-13 2018-09-19 TIGER Coatings GmbH & Co. KG Utilisation d'une composition de poudre de polymère thermodurcissable
US11607838B2 (en) * 2018-07-11 2023-03-21 Mimaki Engineering Co., Ltd. Liquid ejecting apparatus, liquid ejecting method, and ink

Also Published As

Publication number Publication date
FR3106523A1 (fr) 2021-07-30
US20230347584A1 (en) 2023-11-02
WO2021151893A1 (fr) 2021-08-05
CN115244103A (zh) 2022-10-25
EP4097165A1 (fr) 2022-12-07

Similar Documents

Publication Publication Date Title
O'Connor et al. Low‐pressure additive manufacturing of continuous fiber‐reinforced polymer composites
Torrado Perez et al. Fracture surface analysis of 3D-printed tensile specimens of novel ABS-based materials
RU2465140C2 (ru) Способ обработки композиционного материала
FR3106523B1 (fr) Matériau composite thermodurcissable et procédé d’impression associé
DK0466618T3 (da) Hybridtråd til kompositmaterialer med termoplastisk matrice samt fremgangsmåde til fremstilling af denne
CN1621551A (zh) 烧结用原料粉末或者烧结用造粒粉末及其烧结体
US20190078243A1 (en) Method for producing a fiber matrix semi-finished product
Yao et al. Ring‐opening metathesis copolymerization of dicyclopentadiene and cyclopentene through reaction injection molding process
US6818085B2 (en) Fiber-reinforced structural component
FR3075788B1 (fr) Procede de fabrication d'une piece en materiau composite a matrice ceramique
US20090234061A1 (en) Process for Producing a Fluororesin Sheet Containing a Filler and a Fluororesin Sheet Containing a Filler
CN109438866B (zh) 3d打印用碳纤维/abs复合材料及其制备方法
WO2019034777A1 (fr) Composite multi-matériau et procédé de fabrication
Zhang et al. Difference in mechanical properties between plastic and metal molds for injection molding a talc reinforced rubber modified polypropylene
MX2021010037A (es) Compuesto de fundicion termoendurecible, cuerpo moldeado producido a partir del mismo y procedimiento para producir el cuerpo moldeado.
DE102020203614A1 (de) Gleitteil
WO2015074651A1 (fr) Procédé de production d'un revêtement glissant
DE102015208980A1 (de) Eine evakuierbare Form für Faserverbundkunststoff-Bauteile
EP1868805B1 (fr) Procede de fabrication de composants polymeres metallises dans le moule
EP4169688A1 (fr) Procédé de production de préimprégné et procédé de moulage de matériau composite
CN116376252B (zh) 一种3d打印用高介电聚乳酸复合材料及其制备方法
KR100419990B1 (ko) 폴리페닐렌 설파이드계 열가소성 수지 조성물의 제조방법
CN114746254A (zh) 具有改善的耐磨性的部件
JP2017202640A (ja) 繊維強化熱可塑性樹脂構造体の製造方法
TW201825731A (zh) 切股氈及利用該切股氈的樹脂纖維複合材料

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

PLSC Publication of the preliminary search report

Effective date: 20210730

PLFP Fee payment

Year of fee payment: 3

PLFP Fee payment

Year of fee payment: 4

PLFP Fee payment

Year of fee payment: 5