FR3088338B1 - Procede de reformage en lit fixe utilisant un catalyseur de forme particuliere - Google Patents

Procede de reformage en lit fixe utilisant un catalyseur de forme particuliere Download PDF

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Publication number
FR3088338B1
FR3088338B1 FR1871420A FR1871420A FR3088338B1 FR 3088338 B1 FR3088338 B1 FR 3088338B1 FR 1871420 A FR1871420 A FR 1871420A FR 1871420 A FR1871420 A FR 1871420A FR 3088338 B1 FR3088338 B1 FR 3088338B1
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France
Prior art keywords
fixed bed
catalyst
bed reforming
reforming process
shaped catalyst
Prior art date
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Application number
FR1871420A
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English (en)
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FR3088338A1 (fr
Inventor
Bogdan Harbuzaru
Sylvie Lacombe
Jacques Lavy
Christophe Vallee
Kevin Debolt
Goff Pierre-Yves Le
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1871420A priority Critical patent/FR3088338B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to KR1020217013125A priority patent/KR20210076028A/ko
Priority to BR112021004765-4A priority patent/BR112021004765A2/pt
Priority to EP19787286.4A priority patent/EP3877084A1/fr
Priority to US17/292,158 priority patent/US20210388272A1/en
Priority to PCT/EP2019/078574 priority patent/WO2020094378A1/fr
Priority to JP2021524050A priority patent/JP2022506608A/ja
Priority to CN201980073277.8A priority patent/CN113242765A/zh
Publication of FR3088338A1 publication Critical patent/FR3088338A1/fr
Application granted granted Critical
Publication of FR3088338B1 publication Critical patent/FR3088338B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/24—Chlorinating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/001—Calcining
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Nanotechnology (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

Procédé de reformage en lit fixe d’une charge hydrocarbonée comprenant des hydrocarbures n-paraffiniques, naphténiques et aromatiques, à une température comprise entre 400 et 700°C, une pression comprise entre 0,1 et 4 MPa, et un débit massique de charge traitée par unité de masse de catalyseur et par heure compris entre 0,1 et 10 h-1, par mise en contact de ladite charge avec un catalyseur comprenant du platine, un métal promoteur choisi dans le groupe formé par le rhénium et l’iridium, un halogène choisi dans le groupe formé par le fluor, le chlore, le brome et l’iode, et un support poreux d’alumine se présentant sous la forme d’un extrudé caractérisé par une longueur « l » comprise entre 1 et 10 mm, une section comportant quatre lobes dont le plus grand diamètre « D » de la section transversale dudit extrudé est compris entre 1 et 3 mm. Figure 3a à publier
FR1871420A 2018-11-08 2018-11-08 Procede de reformage en lit fixe utilisant un catalyseur de forme particuliere Active FR3088338B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR1871420A FR3088338B1 (fr) 2018-11-08 2018-11-08 Procede de reformage en lit fixe utilisant un catalyseur de forme particuliere
BR112021004765-4A BR112021004765A2 (pt) 2018-11-08 2019-10-21 processo de reforma em leito fixo utilizando um catalisador de forma particular
EP19787286.4A EP3877084A1 (fr) 2018-11-08 2019-10-21 Procede de reformage en lit fixe utilisant un catalyseur de forme particuliere
US17/292,158 US20210388272A1 (en) 2018-11-08 2019-10-21 Method for fixed-bed reforming using a catalyst having a particular form
KR1020217013125A KR20210076028A (ko) 2018-11-08 2019-10-21 특정 형태를 갖는 촉매를 이용한 고정층 개질 방법
PCT/EP2019/078574 WO2020094378A1 (fr) 2018-11-08 2019-10-21 Procede de reformage en lit fixe utilisant un catalyseur de forme particuliere
JP2021524050A JP2022506608A (ja) 2018-11-08 2019-10-21 特定形状の触媒を用いる固定床接触改質方法
CN201980073277.8A CN113242765A (zh) 2018-11-08 2019-10-21 使用具有特定形式的催化剂的固定床重整方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1871420A FR3088338B1 (fr) 2018-11-08 2018-11-08 Procede de reformage en lit fixe utilisant un catalyseur de forme particuliere

Publications (2)

Publication Number Publication Date
FR3088338A1 FR3088338A1 (fr) 2020-05-15
FR3088338B1 true FR3088338B1 (fr) 2021-10-29

Family

ID=66041566

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1871420A Active FR3088338B1 (fr) 2018-11-08 2018-11-08 Procede de reformage en lit fixe utilisant un catalyseur de forme particuliere

Country Status (8)

Country Link
US (1) US20210388272A1 (fr)
EP (1) EP3877084A1 (fr)
JP (1) JP2022506608A (fr)
KR (1) KR20210076028A (fr)
CN (1) CN113242765A (fr)
BR (1) BR112021004765A2 (fr)
FR (1) FR3088338B1 (fr)
WO (1) WO2020094378A1 (fr)

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1391644A (fr) 1963-05-11 1965-03-05 Deutsche Erdoel Ag Procédé d'hydrolyse d'alcoolates d'aluminium en présence d'alcools
US3674680A (en) * 1970-03-09 1972-07-04 Standard Oil Co Process and catalyst for hydroprocessing a resid hydrocarbon
US3857780A (en) * 1972-05-22 1974-12-31 W Gustafson Hydroforming petroleum fractions in gas phase using shaped catalyst particles
US3990964A (en) * 1973-08-03 1976-11-09 American Cyanamid Company Hydrotreating of petroleum distillates using shaped catalyst particles
GB1474248A (en) * 1974-12-06 1977-05-18 American Cyanamid Co Hydroforming petroleum fractions in gas phase using shaped catalyst particles
US4328130A (en) * 1980-10-22 1982-05-04 Chevron Research Company Shaped channeled catalyst
US4394303A (en) * 1981-05-12 1983-07-19 Chevron Research Company Large pore shaped hydroprocessing catalysts
NZ217874A (en) * 1985-10-25 1989-01-27 Mobil Oil Corp Quadrulobe catalysts
DE3823895C1 (fr) 1988-07-14 1989-12-21 Condea Chemie Gmbh, 2212 Brunsbuettel, De
US5880051A (en) * 1996-10-23 1999-03-09 Uop Llc Reforming catalyst system with differentiated acid properties
US7115538B2 (en) * 2001-12-05 2006-10-03 Exxonmobil Chemical Patents Inc. Ethylbenzene conversion catalyst and process
MY139580A (en) * 2002-06-07 2009-10-30 Shell Int Research Shaped catalyst particles for hydrocarbon synthesis
US7297402B2 (en) * 2004-04-15 2007-11-20 Shell Oil Company Shaped particle having an asymmetrical cross sectional geometry
US7901565B2 (en) * 2006-07-11 2011-03-08 Basf Corporation Reforming sulfur-containing hydrocarbons using a sulfur resistant catalyst
US8414851B2 (en) * 2010-06-11 2013-04-09 Uop Llc Apparatus for the reduction of gasoline benzene content by alkylation with dilute ethylene
FR2966058B1 (fr) * 2010-10-15 2013-11-01 IFP Energies Nouvelles Catalyseur optimise pour le reformage catalytique
CN103521245B (zh) * 2012-07-02 2016-08-24 中国石油化工股份有限公司 一种规整条形重整催化剂及其制备方法
US9499403B2 (en) * 2013-07-10 2016-11-22 Saudi Arabian Oil Company Catalyst and process for thermo-neutral reforming of liquid hydrocarbons
FR3015309B1 (fr) * 2013-12-19 2016-01-29 IFP Energies Nouvelles Extrusion helicoidale de supports catalytiques multilobes dissymetriques
CN106622304B (zh) * 2015-11-02 2019-06-11 中国石油化工股份有限公司 一种石脑油重整催化剂，其制备方法及应用

Also Published As

Publication number Publication date
KR20210076028A (ko) 2021-06-23
JP2022506608A (ja) 2022-01-17
US20210388272A1 (en) 2021-12-16
BR112021004765A2 (pt) 2021-08-03
WO2020094378A1 (fr) 2020-05-14
CN113242765A (zh) 2021-08-10
EP3877084A1 (fr) 2021-09-15
FR3088338A1 (fr) 2020-05-15

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