FR3076745B1 - Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante - Google Patents
Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante Download PDFInfo
- Publication number
- FR3076745B1 FR3076745B1 FR1850246A FR1850246A FR3076745B1 FR 3076745 B1 FR3076745 B1 FR 3076745B1 FR 1850246 A FR1850246 A FR 1850246A FR 1850246 A FR1850246 A FR 1850246A FR 3076745 B1 FR3076745 B1 FR 3076745B1
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- France
- Prior art keywords
- hydrosilylation
- dehydrogening
- catalysts
- nanoparticles useful
- nanoparticles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003054 catalyst Substances 0.000 title abstract 3
- 239000002105 nanoparticle Substances 0.000 title abstract 3
- 238000006459 hydrosilylation reaction Methods 0.000 title abstract 2
- 238000006884 silylation reaction Methods 0.000 title abstract 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
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- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
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Abstract
La présente invention concerne des nanoparticules utilisables comme catalyseurs, notamment comme catalyseurs d'hydrosilylation et de silylation déshydrogénante. Plus spécifiquement, la présente invention concerne des nanoparticules d'au moins un métal de transition au degré d'oxydation 0, choisi parmi les métaux des colonnes 8, 9 et 10 du tableau périodique des éléments, et comprenant au moins un ligand carbonyle.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1850246A FR3076745B1 (fr) | 2018-01-12 | 2018-01-12 | Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante |
KR1020207023073A KR102408313B1 (ko) | 2018-01-12 | 2019-01-11 | 하이드로실릴화 및 탈수소 실릴화 촉매로서 유용한 나노입자 |
PCT/FR2019/050054 WO2019138194A1 (fr) | 2018-01-12 | 2019-01-11 | Catalyseurs de nanoparticules de complexes co de métaux zerovalents pour l'hydrosilylation] et la silylation deshydrogenante |
JP2020559032A JP7003293B2 (ja) | 2018-01-12 | 2019-01-11 | ヒドロシリル化及び脱水素化シリル化触媒として有用なナノ粒子 |
CN201980008074.0A CN111936231B (zh) | 2018-01-12 | 2019-01-11 | 可以用作硅氢加成反应和脱氢硅烷化催化剂的零价金属co络合物的纳米颗粒 |
US16/961,643 US11633728B2 (en) | 2018-01-12 | 2019-01-11 | Nanoparticles of CO complexes of zero-valent metals that can be used as hydrosilylation and dehydrogenative silylation catalysts |
EP19703165.1A EP3737497A1 (fr) | 2018-01-12 | 2019-01-11 | Catalyseurs de nanoparticules de complexes co de métaux zerovalents pour l'hydrosilylation] et la silylation deshydrogenante |
US18/123,609 US20230264183A1 (en) | 2018-01-12 | 2023-03-20 | Nanoparticles of co complexes of zero-valent metals that can be used as hydrosilylation and dehydrogenative silylation catalysts |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1850246 | 2018-01-12 | ||
FR1850246A FR3076745B1 (fr) | 2018-01-12 | 2018-01-12 | Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3076745A1 FR3076745A1 (fr) | 2019-07-19 |
FR3076745B1 true FR3076745B1 (fr) | 2021-11-05 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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FR1850246A Active FR3076745B1 (fr) | 2018-01-12 | 2018-01-12 | Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante |
Country Status (7)
Country | Link |
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US (2) | US11633728B2 (fr) |
EP (1) | EP3737497A1 (fr) |
JP (1) | JP7003293B2 (fr) |
KR (1) | KR102408313B1 (fr) |
CN (1) | CN111936231B (fr) |
FR (1) | FR3076745B1 (fr) |
WO (1) | WO2019138194A1 (fr) |
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US20230076525A1 (en) * | 2019-12-18 | 2023-03-09 | Dow Silicones Corporation | Selective preparation of vinyl- and ethyl-functionalized chlorosilanes |
EP4077339A1 (fr) * | 2019-12-18 | 2022-10-26 | Dow Silicones Corporation | Particules de catalyseur et procédés de silylation déshydrogénante |
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US4252672A (en) * | 1979-12-04 | 1981-02-24 | Xerox Corporation | Preparation of colloidal iron dispersions by the polymer-catalyzed decomposition of iron carbonyl and iron organocarbonyl compounds |
US4252674A (en) * | 1979-12-04 | 1981-02-24 | Xerox Corporation | Preparation of colloidal cobalt dispersions by the polymer-catalyzed decomposition of cobalt carbonyl and cobalt organocarbonyl compounds |
US4705765A (en) * | 1985-12-19 | 1987-11-10 | General Electric Company | Hydrosilylation catalyst, method for making and use |
JPH07316175A (ja) * | 1994-05-25 | 1995-12-05 | Nippon Paint Co Ltd | ルテニウムカルボニル金属クラスター錯体 |
DE102004059375A1 (de) | 2004-12-09 | 2006-06-22 | Consortium für elektrochemische Industrie GmbH | Auf nanoskaligem Titandioxid geträgerte Platin-Katalysatoren, deren Verwendung in der Hydrosilylierung, ein Hydrosilylierungsverfahren mit solchen Katalysatoren und Zusammensetzungen enthaltend solche Katalysatoren |
US20090182091A1 (en) | 2006-02-16 | 2009-07-16 | Kaneka Corporation | Curable composition |
WO2014133017A1 (fr) * | 2013-03-01 | 2014-09-04 | 国立大学法人九州大学 | Complexe mononucléaire du fer et réaction de synthèse organique faisant appel à celui-ci |
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2018
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2019
- 2019-01-11 EP EP19703165.1A patent/EP3737497A1/fr active Pending
- 2019-01-11 WO PCT/FR2019/050054 patent/WO2019138194A1/fr unknown
- 2019-01-11 US US16/961,643 patent/US11633728B2/en active Active
- 2019-01-11 CN CN201980008074.0A patent/CN111936231B/zh active Active
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CN111936231B (zh) | 2023-10-27 |
KR102408313B1 (ko) | 2022-06-15 |
JP7003293B2 (ja) | 2022-02-10 |
CN111936231A (zh) | 2020-11-13 |
US11633728B2 (en) | 2023-04-25 |
WO2019138194A1 (fr) | 2019-07-18 |
FR3076745A1 (fr) | 2019-07-19 |
EP3737497A1 (fr) | 2020-11-18 |
KR20200129091A (ko) | 2020-11-17 |
JP2021510349A (ja) | 2021-04-22 |
US20230264183A1 (en) | 2023-08-24 |
US20200353454A1 (en) | 2020-11-12 |
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