FR3048964A1 - - Google Patents

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Publication number
FR3048964A1
FR3048964A1 FR1652290A FR1652290A FR3048964A1 FR 3048964 A1 FR3048964 A1 FR 3048964A1 FR 1652290 A FR1652290 A FR 1652290A FR 1652290 A FR1652290 A FR 1652290A FR 3048964 A1 FR3048964 A1 FR 3048964A1
Authority
FR
France
Prior art keywords
reactor
gas
hydrogen
catalyst
displacement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR1652290A
Other languages
English (en)
French (fr)
Other versions
FR3048964B1 (fr
Inventor
Francis Humblot
Paul-Guillaume Schmitt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1652290A priority Critical patent/FR3048964B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to PT177152303T priority patent/PT3429959T/pt
Priority to EP23163868.5A priority patent/EP4219393A3/fr
Priority to EP17715230.3A priority patent/EP3429959B1/fr
Priority to FIEP17715230.3T priority patent/FI3429959T3/fi
Priority to CN201780017449.0A priority patent/CN108778986A/zh
Priority to US16/084,393 priority patent/US20190077659A1/en
Priority to JP2018548700A priority patent/JP7258553B2/ja
Priority to PL17715230.3T priority patent/PL3429959T3/pl
Priority to PCT/FR2017/050574 priority patent/WO2017158276A1/fr
Priority to ES17715230T priority patent/ES2945993T3/es
Publication of FR3048964A1 publication Critical patent/FR3048964A1/fr
Priority to JP2021165242A priority patent/JP2022017276A/ja
Priority to US18/131,211 priority patent/US20230303391A1/en
Application granted granted Critical
Publication of FR3048964B1 publication Critical patent/FR3048964B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1614—Controlling the temperature
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1628—Controlling the pressure
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Industrial Gases (AREA)
FR1652290A 2016-03-17 2016-03-17 Procede de production de gaz de synthese enrichi en hydrogene Active FR3048964B1 (fr)

Priority Applications (13)

Application Number Priority Date Filing Date Title
FR1652290A FR3048964B1 (fr) 2016-03-17 2016-03-17 Procede de production de gaz de synthese enrichi en hydrogene
ES17715230T ES2945993T3 (es) 2016-03-17 2017-03-14 Proceso para la producción de gas de síntesis enriquecido en hidrógeno
EP17715230.3A EP3429959B1 (fr) 2016-03-17 2017-03-14 Procédé de production de gaz de synthèse enrichi en hydrogène
FIEP17715230.3T FI3429959T3 (fi) 2016-03-17 2017-03-14 Menetelmä vetyrikastetun synteesikaasun valmistamiseksi
CN201780017449.0A CN108778986A (zh) 2016-03-17 2017-03-14 用于制备富氢合成气的方法
US16/084,393 US20190077659A1 (en) 2016-03-17 2017-03-14 Process for the production of hydrogen-enriched synthesis gas
PT177152303T PT3429959T (pt) 2016-03-17 2017-03-14 Método para a produção de gás de síntese enriquecido em hidrogénio
PL17715230.3T PL3429959T3 (pl) 2016-03-17 2017-03-14 Sposób wytwarzania gazu syntezowego wzbogaconego w wodór
PCT/FR2017/050574 WO2017158276A1 (fr) 2016-03-17 2017-03-14 Procédé de production de gaz de synthèse enrichi en hydrogène
EP23163868.5A EP4219393A3 (fr) 2016-03-17 2017-03-14 Procédé de production de gaz de synthèse enrichi en hydrogène
JP2018548700A JP7258553B2 (ja) 2016-03-17 2017-03-14 水素富化合成ガスの製造方法
JP2021165242A JP2022017276A (ja) 2016-03-17 2021-10-07 水素富化合成ガスの製造方法
US18/131,211 US20230303391A1 (en) 2016-03-17 2023-04-05 Process for the production of hydrogen-enriched synthesis gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1652290A FR3048964B1 (fr) 2016-03-17 2016-03-17 Procede de production de gaz de synthese enrichi en hydrogene

Publications (2)

Publication Number Publication Date
FR3048964A1 true FR3048964A1 (enExample) 2017-09-22
FR3048964B1 FR3048964B1 (fr) 2023-06-09

Family

ID=56322067

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1652290A Active FR3048964B1 (fr) 2016-03-17 2016-03-17 Procede de production de gaz de synthese enrichi en hydrogene

Country Status (10)

Country Link
US (2) US20190077659A1 (enExample)
EP (2) EP4219393A3 (enExample)
JP (2) JP7258553B2 (enExample)
CN (1) CN108778986A (enExample)
ES (1) ES2945993T3 (enExample)
FI (1) FI3429959T3 (enExample)
FR (1) FR3048964B1 (enExample)
PL (1) PL3429959T3 (enExample)
PT (1) PT3429959T (enExample)
WO (1) WO2017158276A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3048964B1 (fr) * 2016-03-17 2023-06-09 Arkema France Procede de production de gaz de synthese enrichi en hydrogene
CN114471589A (zh) * 2020-10-27 2022-05-13 中国石油化工股份有限公司 催化剂、耐硫变换催化反应的方法和甲烷的制备方法
US20250230044A1 (en) * 2024-01-15 2025-07-17 Black & Veatch Holding Company Stable qualified clean hydrogen production process and system

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4243554A (en) * 1979-06-11 1981-01-06 Union Carbide Corporation Molybdenum disulfide catalyst and the preparation thereof
US4389335A (en) * 1981-04-14 1983-06-21 United Catalysts Inc. Catalyst for carbon monoxide conversion in sour gas

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GB8803767D0 (en) * 1988-02-18 1988-03-16 Ici Plc Desulphurisation
CA2094766A1 (en) * 1992-04-27 1993-10-28 Vincent A. Durante Process and catalyst for dehydrogenation of organic compounds
CN100469449C (zh) * 2003-08-22 2009-03-18 中国石油化工股份有限公司齐鲁分公司 耐硫变换催化剂的预处理方法及预处理剂
US8846564B2 (en) * 2008-09-29 2014-09-30 Clariant Corporation Process for sulfiding catalysts for a sour gas shift process
US8017545B2 (en) * 2008-12-04 2011-09-13 Uop Llc Dynamic composition for the removal of sulfur from a gaseous stream
FR2948661B1 (fr) 2009-07-31 2011-07-29 Arkema France Composition a base de sulfure organique a odeur masquee
CN103608109A (zh) * 2011-06-14 2014-02-26 国际壳牌研究有限公司 含水催化剂硫化方法
CN103773434B (zh) * 2012-10-24 2015-09-30 中国石油化工股份有限公司 一种二类活性中心柴油加氢脱硫催化剂的硫化方法
CN103801336B (zh) * 2012-11-08 2016-02-03 中国石油化工股份有限公司 一种制备硫化型加氢催化剂的方法
JP6343474B2 (ja) * 2014-03-31 2018-06-13 千代田化工建設株式会社 サワーシフト触媒のスタートアップ方法
FR3048964B1 (fr) * 2016-03-17 2023-06-09 Arkema France Procede de production de gaz de synthese enrichi en hydrogene

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4243554A (en) * 1979-06-11 1981-01-06 Union Carbide Corporation Molybdenum disulfide catalyst and the preparation thereof
US4389335A (en) * 1981-04-14 1983-06-21 United Catalysts Inc. Catalyst for carbon monoxide conversion in sour gas

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
FRANCK LABRUYE ÁRE ET AL: "Ex situ sulfidation by alkylpolysulfides: A route for the preparation of highly dispersed supported sulfides", CATALYSIS TODAY, vol. 43, 1 January 1998 (1998-01-01), pages 111 - 116, XP055308715 *
LANIECKI M ET AL: "Water-gas shift reaction over sulfided molybdenum catalysts supported on TiO2-ZrO2 mixed oxides", CATALYSIS TODAY, ELSEVIER, NL, vol. 116, no. 3, 15 August 2006 (2006-08-15), pages 400 - 407, XP027975859, ISSN: 0920-5861, [retrieved on 20060815] *
LIAN Y ET AL: "Water gas shift activity of Co-Mo/MgO-Al2O3 catalysts presulfided with ammonium sulfide", JOURNAL OF NATURAL GAS CHEMISTRY, ELSEVIER, US, CN, vol. 19, no. 1, 1 January 2010 (2010-01-01), pages 61 - 66, XP026912303, ISSN: 1003-9953, [retrieved on 20100101], DOI: 10.1016/S1003-9953(09)60037-2 *
TEXIER S ET AL: "Activation of alumina-supported hydrotreating catalysts by organosulfides: comparison with H2S and effect of different solvents", JOURNAL OF CATALYSIS, ACADEMIC PRESS, DULUTH, MN, US, vol. 223, no. 2, 25 April 2004 (2004-04-25), pages 404 - 418, XP004500283, ISSN: 0021-9517, DOI: 10.1016/J.JCAT.2004.02.011 *

Also Published As

Publication number Publication date
US20230303391A1 (en) 2023-09-28
EP3429959B1 (fr) 2023-05-03
WO2017158276A1 (fr) 2017-09-21
FI3429959T3 (fi) 2023-06-07
CN108778986A (zh) 2018-11-09
FR3048964B1 (fr) 2023-06-09
ES2945993T3 (es) 2023-07-11
JP2019513114A (ja) 2019-05-23
PT3429959T (pt) 2023-06-07
PL3429959T3 (pl) 2023-07-17
EP4219393A3 (fr) 2023-08-09
JP2022017276A (ja) 2022-01-25
JP7258553B2 (ja) 2023-04-17
EP4219393A2 (fr) 2023-08-02
US20190077659A1 (en) 2019-03-14
EP3429959A1 (fr) 2019-01-23

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