FR3030256A1 - COMPOSITOR IN THE FORM OF REVERSE EMULSION COMPRISING PARTICLES OF POLYMER, AT LEAST ONE SURFACTANT AND WATER - Google Patents

Abstract

The subject of the present invention is a composition in the form of a water-in-oil emulsion comprising particles of at least one polymer stabilized on the surface with a stabilizing agent, the polymer of the particles being an alkyl (meth) acrylate polymer. C1-C4, the stabilizing agent being a polymer of isobornyl (meth) acrylate chosen from isobornyl (meth) acrylate homopolymer and random copolymers of isobornyl (meth) acrylate and (meth) acrylate C1-C4 alkyl present in a weight ratio of isobornyl (meth) acrylate / C1-C4 alkyl (meth) acrylate greater than 4; at least one hydrocarbon oil; at least one surfactant; and water. It also relates to a process for the makeup and / or care of human keratin materials, in which the composition according to any one of the preceding claims is applied.

Description

The present invention relates to compositions intended for the makeup and / or care of human keratin materials, such as the skin, the lips, and the like. BACKGROUND OF THE INVENTION The present invention relates to compositions for the makeup and / or care of human keratin materials, such as the skin, the lips, and the like. in the form of inverse emulsions and comprising particles of surface stabilized polymer at least one hydrocarbon oil, at least one surfactant and water.

These compositions are well known and if they have specific properties depending on their use, there has been a very clear trend over the last few years in the development of compositions whose performance is improved. This avoids, on the one hand, having to reapply the composition too often and, on the other hand, it reduces the transfers on supports with which the masked areas would come into contact (clothes, cups, etc.) or else their elimination by the action of external agents (sebum, food, rain, etc.). This is why the compositions for which this property is sought generally comprise at least one film-forming agent. The latter is often a polymer, being in a solubilized or dispersed form in one of the phases of the composition. It allows the latter, once applied, to form after drying, a more cohesive and tenacious film on the support. There are makeup products whose performance is considerably improved but the deposit they form, once dried, is very uncomfortable. In particular, it causes in fact feelings of tugging and dryness of the lips. It is therefore not uncommon to apply a second composition on the first which brings the behavior of the color, either spontaneously (with the application of a lip balm) is recommended with the first composition (with the application of a so-called "top coat" composition, in this case, for the two compositions, we speak of "double gesture" compositions). This second composition, often transparent, brings brilliance and especially comfort. These products represent a very clear improvement in the behavior of the composition and color on the lips, but their implementation is complex because of the need to implement two steps to obtain the result.

Another problem encountered with the use of such film-forming agents lies in the fact that they are the cause of discomfort in use. First, it is not uncommon for their presence in compositions to make them more sticky and often more difficult to apply. It is therefore in search of compositions which comprise at least one film-forming agent, which make it possible to deposit a comfortable, non-tacky film having good strength, in particular good resistance to oils.

The subject of the invention is therefore a composition in the form of a water-in-oil emulsion comprising particles of at least one polymer stabilized on the surface with a stabilizing agent, the polymer of the particles being an alkyl (meth) acrylate polymer. at Cl-04, the stabilizing agent being a polymer of isobornyl (meth) acrylate selected from isobornyl (meth) acrylate homopolymer and random copolymers of isobornyl (meth) acrylate and (meth) C1-C4 alkyl acrylate present in a weight ratio of isobornyl (meth) acrylate / C1-C4 alkyl (meth) acrylate greater than 4; at least one hydrocarbon oil; at least one surfactant; and water.

The subject of the invention is also a process for making up and / or caring for keratin materials, in particular the skin and the lips, comprising applying said composition. But other advantages will appear more clearly on reading the description and examples that follow. Note that in the following description, unless otherwise indicated, the terminals indicated for a domain are included in this area. The expressions "at least one" and "several" are used interchangeably.

Hydrocarbon Oil The composition according to the invention comprises a hydrocarbon oil. This oil can be volatile (vapor pressure greater than or equal to 0.13 Pa measured at 25 ° C) or non-volatile (vapor pressure less than 0.13 Pa, measured at 25 ° C). Preferably, the hydrocarbon oil is volatile. The hydrocarbon oil is an oil (non-aqueous compound) that is liquid at room temperature (25 ° C). Hydrocarbon oil is understood to mean an oil formed essentially or even consisting of carbon and hydrogen atoms, and possibly oxygen, nitrogen, and not containing silicon or fluorine atoms. It may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups. The hydrocarbon-based oil may be chosen from: hydrocarbon-based oils containing from 8 to 16 carbon atoms, and 2 in particular: - 08-016 branched alkanes, for instance 08-016 isoalkanes of petroleum origin (also known as isoparaffins), isododecane (also called 2,2,4,4,6-pentamethylheptane), isodecane, isohexadecane and for example the oils sold under the trade names Isopars' or permetyls, - linear alkanes, by examples such as n-dodecane (012) and ntétradécane (014) sold by Sasol respectively under the references PARAFOL 12-97 and PARAFOL 14-97, as well as their mixtures, the mixture undecane-tridecane, mixtures of n-undecane (C11) and n-tridecane (013) obtained in Examples 1 and 2 of Application WO2008 / 155059 from Cognis, and mixtures thereof. short chain esters (having from 3 to 8 carbon atoms in total) such as ethyl acetate, methyl acetate, propyl acetate, n-butyl acetate - hydrocarbon oils of vegetable origin, such as triglycerides consisting of esters of fatty acids and glycerol, the fatty acids of which may have chain lengths varying from 04 to 024, the latter being linear or branched, saturated or unsaturated; these oils are in particular triglycerides of heptanoic acid or octanoic acid, or else the oils of wheat germ, sunflower, grape seed, sesame, maize, apricot, castor, shea, avocado, olive, soya, sweet almond, palm, rapeseed, cotton, hazelnut, macadamia, jojoba, alfalfa, poppy, pumpkin, squash, black currant, evening primrose, millet, barley, quinoa, rye, safflower, bancoulier, passionflower, muscat rose; shea butter; or alternatively caprylic / capric acid triglycerides, such as those sold by Stéarineries Dubois or those sold under the names Miglyol 810®, 812® and 818® by the company Dynamit Nobel, synthetic ethers having from 10 to 40 carbon atoms. carbon; linear or branched hydrocarbons of mineral or synthetic origin, such as petroleum jelly, polydecenes, hydrogenated polyisobutene such as Parleam O, squalane, paraffin oils, and mixtures thereof; synthetic esters, such as oils; of formula R1000R2in which R1 represents the residue of a linear or branched fatty acid having 1 to 40 carbon atoms and R2 represents a particularly branched hydrocarbon chain containing from 1 to 40 carbon atoms, provided that R1 + R2 is 10, as per For example, purcellin oil (cetostearyl octanoate), isopropyl myristate, isopropyl palmitate, 012-015 alcohol benzoates, hexyl laurate, diisopropyl adipate, isononanoate, and the like. isononyl, 2-ethyl-hexyl palmitate, isostearyl isostearate, 2-hexyl-decyl laurate, 3-octyl decyl palmitate, 2-octyl-dodecyl myristate, heptanoates, octanoates, decanoates or ricino alcohols or polyhydric alcohols such as propylene glycol dioctanoate; hydroxyl esters such as isostearyl lactate, di-isostearyl malate, 2-octyl-dodecyl lactate; polyol esters and pentaerythritol esters, branched-chain and / or unsaturated carbon-chain liquid fatty alcohols having from 12 to 26 carbon atoms, such as octyl dodecanol, isostearyl alcohol and oleic alcohol, 2-hexyldecanol, 2-butyloctanol, and 2-undecylpentadecanol, - their mixture. More particularly, the hydrocarbon oil content (s) varies from 20 to 75% by weight, preferably from 20 to 60% by weight, even more preferably from 20 to 50% by weight, relative to the weight of the composition. This hydrocarbon oil may be provided in whole or in part with the surface-stabilized polymer particles, in particular when they are introduced into the composition, in the form of a previously prepared dispersion, of surface-stabilized polymer particles. In this case, the hydrocarbon oil present in the composition represents at least the non-aqueous medium of the dispersion of surface-stabilized polymer particles.

Advantageously, the hydrocarbon oil is apolar (thus formed only of carbon and hydrogen atoms). The hydrocarbon oil is preferably chosen from hydrocarbon oils having from 8 to 16 carbon atoms, more preferably from 12 to 16 carbon atoms, in particular the apolar oils, described above.

Preferentially, the hydrocarbon oil is isododecane. More particularly, the content of isododecane ranges from 20 to 75% by weight, preferably from 20 to 60% by weight, even more preferably from 20 to 50% by weight, relative to the weight of the composition. Preferably the hydrocarbon oil (s), in particular isododecane, is (are) the only oil (s) of the composition, or is (are) present (s). ) at a majority weight content relative to the other oil (s) possibly present in the composition. According to a particular embodiment of the invention, if the composition contains one or more non-volatile oils, their content advantageously does not exceed 20% by weight, preferably does not exceed 15% by weight, more particularly does not exceed 10% by weight. % by weight, preferably 5% by weight relative to the weight of the composition, better less than 2% by weight relative to the weight of the composition, or is free of non-volatile oil (s). 4 Polymer Particles The composition according to the invention also comprises particles, generally spherical, of at least one surface-stabilized polymer. Preferably, the particles are introduced into the composition in the form of a dispersion of generally spherical particles of at least one surface-stabilized polymer in an oily medium, advantageously containing at least one hydrocarbon-based oil, as defined previously. . The polymer of the particles is a C.sub.1-4 alkyl (meth) acrylate polymer. The C.sub.1-4 alkyl (meth) acrylate monomers may be chosen from methyl (meth) acrylate, (meth) ethyl acrylate, n-propyl (meth) acrylate, isopropyl (meth) acrylate, n-butyl (meth) acrylate, tert-butyl (meth) acrylate.

Advantageously, a C 1 -C 4 alkyl acrylate monomer is used. Preferably, the polymer of the particles is a polymer of methyl acrylate and / or ethyl acrylate. The polymer of the particles may furthermore comprise an ethylenically unsaturated acid monomer or of their anhydride, chosen in particular from ethylenically unsaturated acidic monomers comprising at least one carboxylic, phosphoric or sulphonic acid function, such as crotonic acid, itaconic acid, fumaric acid, maleic acid, maleic anhydride, styrenesulfonic acid, vinylbenzoic acid, vinylphosphoric acid, acrylic acid, methacrylic acid, acrylamidopropanesulfonic acid, acid acrylamidoglycolic acid, and their salts. Preferably, the ethylenically unsaturated acidic monomer is selected from (meth) acrylic acid, maleic acid and maleic anhydride.

The salts may be chosen from alkali metal salts, for example sodium and potassium; alkaline earth metal salts, for example calcium, magnesium, strontium, metal salts, for example zinc, aluminum, manganese, copper; ammonium salts of formula NH4; quaternary ammonium salts; organic amine salts, such as, for example, the salts of methylamine, dimethylamine, trimethylamine, triethylamine, ethylamine, 2-hydroxyethylamine, bis (2-hydroxyethyl) amine, tri- (2- hydroxyethyl) amine; lysine salts, arginine. The polymer of the particles can thus comprise, or consist essentially of, from 80 to 100% by weight of (C 1 -C 4) alkyl (meth) acrylate and from 0 to 20% by weight of ethylenically unsaturated acidic monomer, by relative to the total weight of the polymer.

According to a first embodiment of the invention, the polymer consists essentially of a polymer of one or more C 1 -C 4 alkyl (meth) acrylate monomers. According to a second embodiment of the invention, the polymer consists essentially of a copolymer of (meth) acrylate Cl-04 and (meth) acrylic acid or maleic anhydride. The polymer of the particles may be chosen from: homopolymers of methyl acrylate homopolymers of ethyl acrylate copolymers methyl acrylate / ethyl acrylate copolymers methyl acrylate / ethyl acrylate / acrylic acid copolymers acrylate methyl acrylate / ethyl acrylate / maleic anhydride methyl acrylate / acrylic acid copolymers ethyl acrylate / acrylic acid copolymers methyl acrylate / maleic anhydride copolymers ethyl acrylate / maleic anhydride copolymers. Advantageously, the polymer of the particles is a non-crosslinked polymer. The polymer of the particles preferably has a number average molecular weight of from 2,000 to 10,000,000, preferably from 150,000 to 500,000. In the case of particle dispersion, the polymer of the particles may be present in the dispersion in a certain amount. ranging from 21% to 58.5% by weight, based on the total weight of the dispersion, preferably ranging from 36 to 42% by weight. The stabilizing agent is a polymer of isobornyl (meth) acrylate selected from isobornyl (meth) acrylate homopolymer and random copolymers of isobornyl (meth) acrylate and alkyl (meth) acrylate in Cl-04 present in a weight ratio of isobornyl (meth) acrylate / C1-C4 alkyl (meth) acrylate greater than 4, preferably greater than 4.5, and still more preferably greater than or equal to 5. Advantageously, said weight ratio ranges from 4.5 to 19, preferably from 5 to 19 and more particularly from 5 to 12. Advantageously, the stabilizing agent is chosen from: homopolymers of isobornyl acrylate, random copolymers of isobornyl acrylate / methyl acrylate 6 random copolymers of isobornyl acrylate / methyl acrylate / ethyl acrylate random copolymers of isobornyl methacrylate / methyl acrylate according to the weight ratio described above. Preferably, the stabilizing agent is soluble in the hydrocarbon oil (s), in particular soluble in isododecane. The stabilizing polymer preferably has a number average molecular weight of from 10,000 to 400,000, preferably from 20,000 to 200,000.

The stabilizer is in contact with the surface, in particular polymer particles, and thus makes it possible to stabilize these particles at the surface for maintaining these particles in dispersion in the non-aqueous medium of the dispersion. According to a theory that can not limit the scope of the present invention, the inventors theorize that the surface stabilization of the C 1 -C 4 alkyl (meth) acrylate polymer particles results from an adsorption phenomenon of surface of the stabilizing agent on the C1-C4 alkyl (meth) acrylate polymer particles. Advantageously, the stabilizing + polymer group of the particles, in particular present in the dispersion, comprises from 10 to 50% by weight of polymerized isobornyl (meth) acrylate and from 50 to 90% by weight of alkyl (meth) acrylate. in polymerized Cl-04, relative to the total weight of the stabilizer + polymer set of the particles. Preferably, the stabilizing + polymer group of the particles, in particular present in the dispersion comprises from 15 to 30% by weight of polymerized isobornyl (meth) acrylate and from 70 to 85% by weight of alkyl (meth) acrylate in polymerized Cl-04, relative to the total weight of the stabilizer + polymer set of the particles. When the polymer particles are made into the composition in the form of a previously prepared dispersion, the oily medium of this polymer dispersion comprises a first hydrocarbon oil. Reference may be made to what has been said above about this oil in terms of its nature. Advantageously, the hydrocarbon oil is apolar and preferably selected from hydrocarbon oils having from 8 to 16 carbon atoms, in particular apolar oils, described above. Preferentially, the hydrocarbon oil is isododecane. The polymer particles, in particular in the dispersion, preferably have a mean size, especially in number, ranging from 50 to 500 nm, in particular ranging from 75 to 400 nm, and better still from 100 to 250 nm. In general, a dispersion of surface-stabilized polymer particles suitable for the invention may be prepared in the following manner, given by way of example. The polymerization can be carried out in dispersion, that is to say by precipitation of the polymer being formed, with protection of the particles formed with a stabilizer. In a first step, the stabilizing polymer is prepared by mixing the monomer (s) constituting the stabilizing polymer, with a radical initiator, in a solvent called synthetic solvent, and by polymerizing these monomers. In a second step, the monomer constituting the polymer is added to the stabilizing polymer formed and the polymerization of these added monomers is carried out in the presence of the radical initiator. When the non-aqueous medium is a non-volatile hydrocarbon oil, the polymerization can be carried out in an apolar organic solvent (synthetic solvent), then the nonvolatile hydrocarbon oil (which must be miscible with the said synthesis solvent) is added and the synthetic solvent. A synthesis solvent is thus chosen such that the monomers of the stabilizing polymer and the radical initiator are soluble therein, and the polymer particles obtained therein are insoluble so that they precipitate during their formation.

In particular, the synthesis solvent can be chosen from alkanes such as heptane or cyclohexane. When the non-aqueous medium is a volatile hydrocarbon oil, the polymerization can be carried out directly in the said oil, which thus also acts as a synthesis solvent. The monomers must also be soluble there, as well as the radical initiator, and the polymer of the particles obtained must be insoluble there. The monomers are preferably present in the synthesis solvent, before polymerization, in a proportion of 5-20% by weight. All of the monomers may be present in the solvent before the start of the reaction, or a portion of the monomers may be added as the polymerization reaction progresses. The radical initiator may be in particular azobisisobutyronitrile or tert-butylperoxy-2-ethylhexanoate. The polymerization can be carried out at a temperature ranging from 70 to 110 ° C. The polymer particles are surface-stabilized, when formed during the polymerization, by the stabilizing agent. The stabilization can be carried out by any known means, and in particular by direct addition of the stabilizing agent, during the polymerization. The stabilizer is preferably also present in the mixture prior to polymerization of the monomers of the polymer of the particles. However, it is also possible to add it continuously, especially when the monomers of the polymer of the particles are also continuously added.

It is possible to use from 10 to 30% by weight of stabilizer relative to the total weight of monomers used (stabilizer + polymer of the particles), and preferably from 15 to 25% by weight. The dispersion of polymer particles advantageously comprises from 30 to 65% by weight of solids, relative to the total weight of the dispersion, and preferably from 40 to 60% by weight. Furthermore, the composition according to the invention advantageously comprises a content of surface-stabilized polymer particles, expressed as active ingredient, of between 5 and 55% by weight, more specifically between 5 and 50% by weight. preferably between 8 and 45% by weight, more preferably between 10 and 40% by weight, relative to the weight of the composition Plasticizer According to one embodiment of the particular invention of the invention, the composition comprises at least one In the case where the polymer particles are made in the form of a dispersion, the plasticizing agent is then advantageously present in the said oily dispersion The plasticizer (s) may be chosen from n-butyl tri-citrate, tripropylene glycol monomethyl ether (INCI name: PPG-3 methyl ether), trimethyl pentaphenyl trisiloxane (sold under the name DOW CORNING PH-1555 HRI COSMETIC FLUID by Dow Cornin These plasticizers make it possible to improve the mechanical strength of the polymer film. The plasticizer may be present in a content ranging from 2 to 50% by weight, based on the total weight of the polymer of the particles, preferably from 2 to 40% by weight and even more particularly below 20% by weight. weight relative to the weight of the composition. Ethylcellulose As indicated above, the composition according to the invention may comprise at least alkylcellulose, the alkyl residue of which comprises between 2 and 6 carbon atoms, preferably between 2 and 3 carbon atoms, and better still a composition according to the invention. The invention comprises ethylcellulose. According to a particularly preferred embodiment, the alkylcellulose (preferably of which the alkyl residue comprises between 2 and 6 carbon atoms, 9 preferably ethylcellulose) may be present in a composition according to the invention in a content (in dry matter ) ranging from 1 to 8% by weight, and preferably from 2.5 to 6% by weight of alkylcellulose solids, relative to the total weight of said composition.

The alkylcellulose is a cellulose alkyl ether comprising a chain consisting of 3-anhydroglucose units linked together by acetal bonds. Each anhydroglucose unit has three replaceable hydroxyl groups, all or part of these hydroxyl groups being able to react according to the following reaction: RONa + C2H5CI ROC2H5 + NaCl, where R represents a cellulose radical. Advantageously, the alkylcellulose may be chosen from ethylcellulose and propylcellulose. According to a particularly preferred embodiment, the alkylcellulose may be ethylcellulose. It is an ethyl cellulose ether. The total substitution of the three hydroxyl groups would lead for each anhydroglucose unit to a degree of substitution of 3, in other words to an alkoxy content of 54.88%.

The ethylcellulose polymers used in a cosmetic composition according to the invention are preferably polymers having a degree of substitution with ethoxy groups ranging from 2.5 to 2.6 per anhydroglucose unit, that is to say comprising an ethoxy content ranging from at 50%.

According to a preferred embodiment, the alkylcellulose (preferably ethylcellulose) may be used in a composition of the invention in the form of particles dispersed in an aqueous phase, like a latex-type dispersion or pseudolatex. The techniques for preparing these latex dispersions are well known to those skilled in the art.

Particularly suitable as an aqueous dispersion of ethylcellulose, the product marketed by FMC Biopolymer under the name "AQUACOAT ECD-30", which consists of a dispersion of ethylcellulose stabilized with sodium lauryl sulfate and cetyl alcohol.

Water The composition according to the invention comprises water. The water content usually varies between 10 and 50% by weight relative to the weight of the composition, and preferably between 10 and 40% by weight relative to the weight of the composition. The composition according to the invention may be in the form of an oil-in-water emulsion, water-in-oil, but preferably water-in-oil. Water-soluble Compound The composition according to the invention may also comprise at least one water-soluble compound. By "water-soluble compound" is meant in the present invention a liquid compound at room temperature and miscible with water (miscibility in water greater than 50% by weight at 25 ° C and atmospheric pressure).

The water-soluble compounds that can be used in the compositions according to the invention can moreover be volatile. Among the water-soluble compounds that can be used in the compositions in accordance with the invention, there may be mentioned monoalcohols, preferably saturated, having less than 8 carbon atoms, and preferably less than 5 carbon atoms, such as ethanol, isopropanol and butanol; the linear or branched, saturated or unsaturated, linear or branched, saturated or unsaturated polyisocyanates of from 2 to 6, preferably from 3 to 6, and preferably glycerin, ethylene glycol, propylene glycol, 1,3- butylene glycol, dipropylene glycol, diglycerine, and mixtures thereof.

Preferably, the content of water-soluble compound (s) if the composition according to the invention comprises thereof, varies from 0.2 to 10% by weight, preferably from 0.2 to 8% by weight, relative to weight of the composition. Surfactants As indicated above, the composition comprises at least one surfactant promoting the production of an inverse emulsion (water in oil). Preferably, the composition comprises at least one surfactant whose HLB (hydrophilic / lipophilic balance) is less than 7. Preferably, the composition therefore comprises at least one hydrocarbon surfactant, silicone, or their mixture. More particularly, the surfactant is chosen from polyol fatty acid esters; alkyl or alkoxy dimethicone copolyols having a pendant alkyl or alkoxy chain or a silicone backbone having, for example, from 6 to 22 carbon atoms; polymers of the polyoxyalkylene glycol fatty acid ester type, and mixtures thereof. As regards the hydrocarbon surfactants of the polyol fatty acid ester type, mention may in particular be made of mono-, di-, tri- or sesqui-esters of fatty acids, in particular laurates, oleates, stearates, isostearates, polyols. These polyols are more particularly chosen from sorbitol, glycerol, polyglycerols and polyethylene glycols, or mixtures thereof. Mention may be made especially sorbitol mono-, di-, tri- or sesqui-oleates or stearates or glycerol, laurates glycerol or polyethylene glycol. Mention may also be made of glycerol and / or sorbitan esters and, for example, polyglyceryl-3-diisostearate sold under the name LAMEFORM TGI by Cognis, polyglyceryl-4 isostearate, such as the product sold under the name lsolan. GI 34 by Goldschmidt, sorbitan isostearate, such as the product sold under the name Arlacel 987 by ICI, sorbitan isostearate of glycerol, such as the product sold under the name Arlacel 986 by the company ICI, and their mixtures. As another hydrocarbon surfactant that may be used in the invention for obtaining an W / O emulsion, mention may be made of polymers of the polyoxyalkylenated glycol fatty acid ester type promoting water-in-oil emulsions.

The fatty acid ester of said polymer is preferably polyhydroxylated. In particular, this polymer is a block polymer, preferably of ABA structure, comprising poly (hydroxyl ester) sequences and polyethylene glycol sequences. The fatty acid ester of said emulsifying polymer as defined above generally has a chain comprising from 12 to 20 carbon atoms, preferably from 14 to 18 carbon atoms. The esters may especially be chosen from oleates, palmitates or stearates. The polyethylene glycol sequences of said emulsifying polymer as defined above preferably comprise from 4 to 50 moles of ethylene oxide, and more preferably from 20 to 40 moles of ethylene oxide. A polymeric surfactant particularly suitable for producing the compositions of the invention is the polyethylene glycol dihydroxystearate 30 OE sold under the trade name "Arlacel P 135" by the company ICI.

As regards the silicone surfactants, surfactants of the alkyl or alkoxy dimethicone copolyol type having an alkyl or pendant alkoxy chain or a silicone backbone having, for example, from 6 to 22 carbon atoms, are particularly suitable. Advantageously, the surfactant may be a C8-C22 alkyl dimethicone copolyol, that is to say an oxypropylenated and / or oxyethylenated poly (C8-C22) alkyl dimethyl methyl siloxane. The C8-C22 alkyl dimethicone copolyol is advantageously a compound of the following formula (I): ## STR2 ## wherein CH 3 CH 3 CH 3 Si (CH 3) 3 SiO 0 SiO Si CH 3 Si (CH 3) 3ClCl 12) Wherein: PE is (-C2H40), - (C3H60) yR, wherein R is selected from hydrogen and alkyl of 1 to 4 carbon atoms, x is from 0 to 100 and 5 y ranging from 0 to 80, where x and y are not simultaneously 0 - m ranging from 1 to 40 - n ranging from 10 to 200 - o ranging from 1 to 100 - p ranging from 7 to 21 10 q ranging from 0 to 4. Preferably, in formula (I), R represents a hydrogen atom, m varies from 1 to 10; n varies from 10 to 100; o varies from 1 to 30; p is equal to 15 and q is 3. Preferably, alkyl dimethicone copolyol is used, for example cetyl dimethicone copolyol, in particular whose INCI name is CETYL PEG / PPG-10/1 DIMETHICONE, as the product marketed under the name Abil EM-90 by the company Evonik Goldschmidt. Compounds of the following formula (II) may also be used: ## STR2 ## wherein: R 1, R 2, R 3, independently of one another, represent a C1-C6 alkyl radical or a radical - (CH2) x - (OCH2Cl2-12) y - (OCH2CH2CH2) z - OR4, at least one radical R1, R2 or R3 not being an alkyl radical; R4 being hydrogen, a C1-C3 alkyl radical or a 02-04 acyl radical; A is an integer from 0 to 200; - B is an integer from 0 to 50; provided that A and B are not equal to zero at the same time; x is an integer from 1 to 6; y is an integer ranging from 1 to 30; and z is an integer from 0 to 5. According to a preferred embodiment, in the compound of formula (II), R1 = R3 = methyl radical, x is an integer from 2 to 6 and y is an integer ranging from 4 to 30. R4 is in particular hydrogen. Examples of compounds of formula (II) that may be mentioned are the compounds of formula (III): (CH 3) 35 10 - [(Cl-13) 25 10] n, - (CH 3 SiO) B - Si (CH 3) 3 (III) (CH2) 2- (OCH2CH2) y-OH wherein A is an integer from 20 to 105, B is an integer from 2 to 10 and y is an integer from 10 to 20. Mention may also be made, by way of example of silicone compounds of formula (II), of the compounds of formula (IV): ## STR2 ## y-OH (IV) in which A 'and y are integers ranging from 10 to 20. The dimethicone copolyols used are those sold under the names DC 5329, DC 7439-146, DC 2-5695, Q4-3667 by Dow Corning; KF-6013, KF-6015, KF-6016, KF-6017, KF-6028 by Shin-Etsu. Compounds DC 5329, DC 7439-146, DC 2-5695 are compounds of formula (III) wherein A is respectively 22, B is 2 and y is 12; A is 103, B is 10 and y is 12; A is 27, B is 3 and y is 12. According to one particular embodiment, the silicone surfactant may be PEG-polydimethylsiloxyethyldimethicone, especially marketed by Shin-Etsu under the reference KF-6028, PEG-10 dimethicone in particular. marketed by Shin-Etsu under the reference KF-6017, and mixtures thereof. Preferably, the composition comprises at least one silicone-type silicone surfactant 08-022 dimethicone copolyol of formula (I). More preferably, said silicone surfactant is cetyl dimethicone copolyol, in particular whose INCI name is CETYL PEG / PPG-10/1 DIMETHICONE, such as the product sold under the name Abil EM-90 by the company Evonik Goldschmidt. Preferably, according to this embodiment, the composition also comprises at least one co-surfactant chosen from alkyl esters of polyol, preferably from esters of glycerol and / or sorbitan. Preferably, the cosurfactant is selected from polyglyceryl 3-diisostearate, polyglycerol-4 isostearate, sorbitan isostearate, sorbitan and glycerol isostearate, and mixtures thereof. Preferably, the co-surfactant is polyglycerol-4 isostearate, such as the product sold under the name Isolan GI 34 by Goldschmidt. Advantageously, the content of surfactant (s) in the composition varies from 0.2. % to 10% by weight relative to the weight of the composition, or even 0.5% to 7% by weight. Mineral Thickener The composition according to the invention may also comprise at least one mineral thickener chosen from clays, optionally modified, silicas, optionally modified, or mixtures thereof. More particularly, the content of mineral thickener is 0.2 to 15% by weight, expressed as active material, preferably 0.5 to 7% by weight, relative to the weight of the composition. According to an advantageous embodiment of the invention, According to the invention, the content of mineral thickener is such that the weight ratio (expressed as active material) of polymer particles / thickener varies from 0.5 to 80, preferably from 5 to 50, and more particularly from 10 to 30. Potentially modified clays Clays are silicates containing a cation which may be chosen from calcium, magnesium, aluminum, sodium, potassium and lithium cations, and mixtures thereof. Examples of such products include clays of the smectite family, as well as the vermiculite family, stevensite, chlorites. These clays can be of natural or synthetic origin. More particularly, there may be mentioned smectites such as saponites, hectorites, montmorillonites, bentonites, beidellite and in particular synthetic hectorites (also called laponites) such as the products sold by Laporte under the name Laponite XLG, Laponite RD, Laponite RDS (these products are sodium and magnesium silicates and in particular sodium, lithium and magnesium silicates); bentonites, such as the product sold under the name Bentone HC by Rheox; magnesium and aluminum silicates, in particular hydrated silicates, such as the products sold by Vanderbilt Company under the name Veegum ultra, Veegum HS and Veegum DGT, or else calcium silicates and in particular the synthetic form sold by the company under the name Preferably, organophilic clays, more particularly modified clays, such as montmorillonite, bentonite, hectorite, attapulgite, sepiolite, and mixtures thereof are used. The clay is preferably a bentonite or a hectorite. These clays are modified with a chemical compound selected from quaternary amines, tertiary amines, amino acetates, imidazolines, amine soaps, fatty sulfates, alkyl aryl sulfonates, amine oxides, and mixtures thereof. It is thus possible to mention the hectorites modified with a quaternary amine, more specifically with a halide, such as a chloride, of 0-10 to 022 fatty acid ammonium, such as hectorite modified with di-stearyl dimethyl ammonium chloride. (CTFA name: Disteardimonium hectorite), such as, for example, that marketed under the name Bentone 38V®, Bentone 38V CG, Bentone EVV CE, by the company ELEMENTIS; stearalkonium Hectorites such as Bentone 27 V, mention may also be made of quaternium-18 bentonites such as those sold under the names Bentone 34 marketed by Elementis, Claytone 40, Tixogel VP by United catalyst by Southern Clay; stearalkonium bentonites such as those sold under the names Tixogel LG by United Catalyst, Claytone AF, Claytone APA by Southern Clay; 18-quaternium / benzalkonium bentonite such as those sold under the name Claytone HT by the company Southern Clay According to a preferred embodiment, the thickening agent is chosen from organophilic modified clays, in particular modified organophile hectorites, in particular by benzyldimethyl ammonium stearate chloride, or distearyl dimethyl ammonium chloride. According to a variant of the invention, the optionally modified clay content varies from 0.2 to 10% by weight, relative to the weight of the composition, and preferably from 0.5 to 5% by weight relative to the weight. of the composition. These percentages are expressed as active ingredient. ii) Potentially modified silicas One can also mention the optionally hydrophobic fumed silica surface with a particle size of less than 1 micron. It is indeed possible to chemically modify the surface of the silica, by chemical reaction generating a decrease in the number of silanol groups present on the surface of the silica. In particular, it is possible to substitute silanol groups with hydrophobic groups: a hydrophobic silica is then obtained. The hydrophobic groups may be: trimethylsiloxyl groups, which are especially obtained by treatment of fumed silica in the presence of hexamethyldisilazane. Silicas thus treated are called "Silica silylate" according to the CTFA (6th edition, 1995). They are for example sold under the references Aerosil R812® by the company DEGUSSA, CAB-O-SIL TS-530® by the company CABOT, dimethylsilyloxyl or polydimethylsiloxane groups, which are especially obtained by treatment of fumed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas thus treated are called "Silica dimethyl silylate" according to the CTFA (6th edition, 1995). They are for example marketed under the references Aerosil R972®, and Aerosil R974® by the company DEGUSSA, CAB-O-SIL TS-610® and CAB-O-SIL TS-720® by CABOT. In particular, the hydrophobic fumed silica has a particle size which may be nanometric to micrometric, for example from about 5 to 200 nm. The composition according to the invention comprises at least silica airgel particles. Silica aerogels are porous materials obtained by replacing (by drying) the liquid component of a silica gel with air. They are generally synthesized by a sol-gel process in a liquid medium and then usually dried by extraction of a supercritical fluid, the most commonly used being supercritical CO2. This type of drying avoids the contraction of the pores and the material. The sol-gel process and the various dryings are described in detail in Brinker CJ, and Scherer G.VV., Sol-Gel Science: New York: Academic Press, 1990. Hydrophobic silica airgel particles used in The present invention has a specific surface area per unit mass (Sm) of from 500 to 1500 m 2 / g, preferably from 600 to 1200 m 2 / g and more preferably from 600 to 800 m 2 / g, and a size expressed as a volume average diameter. (D [0.5]) ranging from 1 to 1500 μm, preferably from 1 to 1000 μm, preferably from 1 to 100 μm, in particular from 1 to 30 μm, more preferably from 5 to 25 μm, more preferably from 5 to 25 μm. at 20 μm and even better better from 5 to 15 μm. According to one embodiment, the hydrophobic silica airgel particles used in the present invention have a size expressed as a volume average diameter (D [0.5]) ranging from 1 to 30 μm, preferably from 5 to 25 μm. pm, better from 5 to 20 pm and even better from 5 to 15 pm. The specific surface area per unit mass can be determined by the nitrogen absorption method called the BET method (BRUNAUER - EMMET - TELLER) described in "The Journal of the American Chemical Society", vol. 60, page 309, February 1938 and corresponding to the international standard ISO 5794/1 (Annex D). The BET surface area corresponds to the total specific surface area of the particles under consideration. The silica airgel particle sizes can be measured by static light scattering using a MasterSizer 2000 commercial particle size analyzer from Malvern. The data is processed on the basis of Mie scattering theory. This theory, which is accurate for isotropic particles, makes it possible to determine, in the case of non-spherical particles, an "effective" diameter of particles. This theory is described in particular in Van de Hulst, HC, "Light Scattering by Small Particles," Chapters 9 and 10, VViley, New York, 1957. According to an advantageous embodiment, silica airgel particles hydrophobically used in the present invention have a specific surface per unit mass (Sm) ranging from 600 to 800 m2 / g and a size expressed in volume mean diameter (D [0.5]) ranging from 5 to 20 pm and even better better from 5 to 15 pm. The silica airgel particles used in the present invention may advantageously have a canable packed density of 0.02 g / cm 3 to 0.10 g / cm 3, preferably 0.03 g / cm 3 to 0.08 g / cm 3, preferably from 0.05g / cm3 to 0.08g / cm3.

In the context of the present invention, this density can be assessed according to the following protocol, called the packed density: 40 g of powder are poured into a graduated test tube; then the specimen is placed on the STAV 2003 device from STAMPF VOLUMETER; the test piece is then subjected to a series of 2500 settlements (this operation is repeated until the difference in volume between two consecutive tests is less than 2%); then the final volume Vf of compacted powder is measured directly on the test piece. The packed density is determined by the ratio m / Vf, in this case 40 / Vf (Vf being expressed in cm3 and m in g). According to a preferred embodiment, the hydrophobic silica aerogel particles used in the present invention have a specific surface area per unit volume Sv ranging from 5 to 60 m 2 / cm 3, preferably from 10 to 50 m 2 / cm 3 and better still 15 to 40 m2 / cm3. The specific surface area per unit volume is given by the relationship: Sv = Sm x a where a is the packed density expressed in g / cm 3 and Sm is the specific surface area per unit mass expressed in m2 / g, as defined above. Preferably, the hydrophobic silica aerogel particles according to the invention have an oil absorption capacity measured at VVET POINT ranging from 5 to 18 ml / g, preferably from 6 to 15 ml / g and better still from 8 to 18 ml / g. at 12 ml / g. The absorption capacity measured at VVet Point, and denoted VVp, corresponds to the amount of oil which must be added to 100 g of particles in order to obtain a homogeneous paste. It is measured according to the so-called VVet Point method or method for determining the setting of powder oil described in standard NF T 30-022. It corresponds to the quantity of oil adsorbed on the available surface of the powder and / or absorbed by the powder by measuring the VVet Point, described below: A quantity m = 2 g of powder is placed on a glass plate and then the oil (isononyl isononanoate) is added dropwise. After addition of 4 to 5 drops of oil in the powder, mixing is carried out with a spatula and oil is added until the formation of oil and powder conglomerates. From this moment, the oil is added one drop at a time and then triturated with the spatula. The addition of oil is stopped when a firm and smooth paste is obtained. This paste should be spread on the glass plate without cracks or lumps. The volume Vs (expressed in ml) of oil used is then noted. The oil intake corresponds to the ratio Vs / m. The aerogels used according to the present invention are aerogels of hydrophobic silica, preferably of silylated silica (INCI name silica silylate).

By "hydrophobic silica" is meant any silica whose surface is treated with silylating agents, for example by halogenated silanes such as alkylchlorosilanes, siloxanes, in particular dimethylsiloxanes such as hexamethyldisiloxane, or silazanes, in order to functionalize the OH groups by Si-Rn silyl groups, for example trimethylsilyl groups. Concerning the preparation of hydrophobic silica airgel particles surface-modified by silylation, reference can be made to US Pat. No. 7,470,725. Hydrophobic silica aerogels particles surface-modified with trimethylsilyl groups will preferably be used.

Examples of hydrophobic silica aerogels that can be used in the invention include, for example, the airgel marketed under the name VM-2260 (INCI name Silica silylate), by the company Dow Corning, whose particles have an average size. about 1000 microns and a specific surface area per unit mass ranging from 600 to 800 m2 / g.

Mention may also be made of aerogels marketed by Cabot under the references AEROGEL TLD 201, AEROGEL OGD 201, AEROGEL TLD 203, ENOVA® AEROGEL MT 1100 and ENOVA AEROGEL MT 1200. The airgel marketed under the name VM2270 ( INCI name Silica silylate), by Dow Corning, whose particles have an average size ranging from 5-15 microns and a specific surface area per unit mass ranging from 600 to 800 m2 / g. Preferably, when the composition comprises at least one thickening agent chosen from optionally modified silicas, they are chosen from hydrophobic silica airgel particles. According to a variant of the invention, the optionally modified silica content varies from 0.5 to 15% by weight, preferably from 1 to 7% by weight, relative to the weight of the composition. These values are expressed in weight of active ingredient.

Preferably, the mineral thickeners are chosen from lipophilic clays, in particular modified hectorites; hydrophobic treated fumed silica; Hydrophobic silica aerogels, or mixtures thereof Preferably, the composition comprises at least one organophilic modified clay or at least one hydrophobic modified silica, in particular hydrophobic silica aerogels. Additional Silicone Oils The composition according to the invention may further comprise at least one additional silicone, volatile or non-volatile oil. By "silicone oil" is meant an oil containing at least one silicon atom, and in particular containing Si-O groups. Suitable volatile volatile silicone additional oils that may be mentioned include, for example, volatile linear or cyclic silicone oils, especially those having a viscosity of 8 centistokes (8 × 10 -6 m 2 / s), especially having from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups having from 1 to 10 carbon atoms. As volatile silicone oil that can be used, mention may be made in particular of octamethylcyclotetrasiloxane, cyclopentadimethylsiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethylisiloxane, octamethyltrisiloxane and decamethyltetrasiloxane. dodecamethyl pentasiloxane and mixtures thereof.

Non-volatile silicone oils that may be mentioned include non-volatile, non-phenyl silicone oils, such as polydimethylsiloxanes (PDMSs), PDMSs comprising aliphatic groups, in particular alkyl, or alkoxy groups, which are pendant and / or at the end of the silicone chain; these groups each comprising from 2 to 24 carbon atoms. By way of example, mention may be made of cetyldimethicone sold under the commercial reference ABIL WAX 9801 by Evonik Goldschmidt. Non-volatile oils containing phenyl silicone, whether or not including one or more dimethicone fragments (- (CH 3) 2 -SiO--), are also suitable. for example phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, trimethylpentaphenyltrisiloxane, and mixtures thereof. If the composition comprises, the content of additional oil (s) silicone (s), is between 1 and 15% by weight relative to the weight of the composition. Preferably, the composition does not comprise more than 10% by weight, relative to the weight of the composition, of additional nonvolatile oil, and preferably not more than 5% by weight, relative to the weight of the composition.

Waxes The composition according to the invention may optionally comprise at least one wax. For the purposes of the present invention, the term "wax" means a lipophilic compound, solid at room temperature (25 ° C.), with a reversible solid / liquid state change, having a melting point of greater than or equal to 30 ° C. up to 120 ° C. The melting point of the wax can be measured using a differential scanning calorimeter (D.S.C.), for example the calorimeter sold under the name DSC 30 by the METLER company. The waxes may be hydrocarbon-based, fluorinated and / or silicone-based and may be of vegetable, mineral, animal and / or synthetic origin. In particular, the waxes have a melting point greater than 25 ° C. and better still greater than 45 ° C. In particular, hydrocarbon waxes such as beeswax, lanolin wax, and Chinese insect waxes can be used; rice wax, Carnauba wax, Candelilla wax, Ouricurry wax, Alfa wax, cork fiber wax, sugar cane wax, Japanese wax and sumac wax ; montan wax, microcrystalline waxes, paraffins and ozokerite; polyethylene waxes, waxes obtained by Fisher-Tropsch synthesis and waxy copolymers and their esters. Mention may also be made of waxes obtained by catalytic hydrogenation of animal or vegetable oils having linear or branched C8-C32 fatty chains. Among these, there may be mentioned hydrogenated jojoba oil, isomerized jojoba oil such as trans isomerized partially hydrogenated jojoba oil manufactured or marketed by Desert VVhale under the commercial reference ISO-JOJOBA- 500, hydrogenated sunflower oil, hydrogenated castor oil, hydrogenated coconut oil and hydrogenated lanolin oil, di- (trimethyl-1,1,1-propane) tetrastearate sold under the name " HEST 2T-4S "by the company HETERENE, di (trimethyl-1,1,1-propane) tetra-enehenate sold under the name HEST 2T-4B by the company HETERENE.

Mention may also be made of silicone waxes such as alkyl or alkoxydimeticones having from 16 to 45 carbon atoms, and polypropylsilsesquioxane waxes (as described in patent WO2005 / 100444), with in particular the compound 030-045 alkyldimethylsilyl polypropylsilsesquioxanes available. commercially available from Dow Corning under the trade name SVV-8005 030 Resin Wax; fluorinated waxes, and preferably silicone waxes. It is also possible to use the wax obtained by hydrogenation of esterified olive oil with the stearyl alcohol sold under the name "PHYTOVVAX Olive 18 L 57" or even the waxes obtained by hydrogenation of castor oil esterified with alcohol. cetyl sold under the name "PHYTOVVAX ricin 16L64 and 22L73", by the company SOPHIM. Such waxes are described in application FR-A-2792190.

If the composition comprises one or more waxes, their content represents from 0.4 to 20% by weight relative to the weight of the composition, and preferably from 0.5 to 5% by weight, relative to the weight of the composition. Pigments By pigments, white or colored particles, inorganic (inorganic) or organic, insoluble in the liquid organic phase, are intended to color and / or opacify the composition and / or the deposition carried out with the composition. The pigments may be chosen from inorganic pigments, organic pigments, and composite pigments (that is to say pigments based on mineral and / or organic materials). The pigments may be chosen from monochromatic pigments, lacquers and optical effect pigments, such as nacres and goniochromatic pigments. If the composition comprises, their content usually varies from 0.1 to 10% by weight, relative to the weight of the composition, and preferably from 0.5 to 7% by weight relative to the weight of the composition.

The inorganic pigments may be chosen from metal oxide pigments, chromium oxides, iron oxides (black, yellow, red), titanium dioxide, zinc oxides, cerium oxides and zirconium oxides. , chromium hydrate, manganese violet, prussian blue, ultramarine blue, ferric blue, metal powders such as aluminum powders, copper powder, and mixtures thereof. Organic lakes are organic pigments formed of a dye attached to a substrate.

Lacquers which are also called organic pigments may be chosen from the following materials and their mixtures: - cochineal carmine; organic pigments of azo, anthraquinone, indigo, xanthene, pyrenic, quinoline, triphenylmethane and fluoran dyes. Among the organic pigments, mention may be made of those known under the following names: D & C Blue No. 4, D & C Brown No. 1, D & C Green No. 5, D & C Green No. 6, D & C Orange No. 4, D & C Orange No. 5, D & C Orange No. 10, D & C Orange No. 11, D & C Red No. 6, D & C Red No. 7, D & C Red No. 17, D & C Red No. 21, 25 D & C Red No. 22, D & C Red No. 27 , D & C Red No. 28, D & C Red No. 30, D & C Red No. 31, D & C Red No. 33, D & C Red No. 34, D & C Red No. 36, D & C Violet No. 2, D & C Yellow No. 7, D & C Yellow No. 8, D & C Yellow No. 10, D & C Yellow No. 11, FD & C Blue No. 1, FD & C Green No. 3, FD & C Red No. 40, FD & C Yellow No. 5, FD & C Yellow No. 6; the organic lakes may be insoluble salts of sodium, potassium, calcium, barium, aluminum, zirconium, strontium, titanium, acid dyes such as azo, anthraquinone, indigo, xanthene dyes, pyrenic, quinoline, triphenylmethane, fluoran, these dyes may comprise at least one carboxylic or sulfonic acid group. Organic lakes may also be supported by an organic carrier such as rosin or aluminum benzoate, for example. Among the organic lakes, mention may be made in particular of the following denominations: D & C Red No. 2 Aluminum Lake, D & C Red No. 3 Aluminum Lake, D & C Red No. 4 Aluminum Lake, D & C Red No. 6 Aluminum Lake, 23 D & C Red # 6 Barium Lake, D & C Red # 6 Barium / Strontium Lake, D & C Red # 6 Strontium Lake, D & C Red # 6 Potassium Lake, D & C Red # 7 Aluminum Lake, D & C Red # 7 Barium Lake, D & C Red # 7 Calcium Lake, D & C Red # 7 Calcium / Strontium Lake, D & C Red # 7 Zirconium Lake, D & C Red # 8 Sodium Lake, D & C Red # 9 Aluminum Lake, D & C Red # 9 Barium Lake, D & C Red # 9 Barium / Strontium Lake, D & C Red # 9 Zirconium Lake, D & C Red # 10 Sodium Lake, D & C Red # 19 Aluminum Lake, D & C Red # 19 Barium Lake, D & C Red # 19 Zirconium lake, D & C Red No. 21 Aluminum Lake, D & C Red No. 21 Zirconium Lake, D & C Red No. 22 Aluminum Lake, D & C Red No. 27 Aluminum Lake, D & C Red No. 27 Aluminum / Titanium / Zirconium Lake, D & C Red No. 27 Barium Lake, D & C Red # 27 Calci um lake, D & C Red # 27 Zirconium lake, D & C Red # 28 Aluminum lake, D & C Red # 30 lake, D & C Red # 31 Calcium lake, D & C Red # 33 Aluminum lake, D & C Red # 34 Calcium lake, D & C Red No. 36 Lake, D & C Red No. 40 Aluminum Lake, D & C Blue No. 1 Aluminum Lake, D & C Green No. 3 Aluminum Lake, D & C Orange No. 4 Aluminum Lake, D & C Orange No. 5 Aluminum Lake, D & C Orange No. ° 5 Zirconium lake, D & C Orange # 10 Aluminum lake, D & C Orange # 17 Barium lake, D & C Yellow # 5 Aluminum lake, D & C Yellow # 5 Zirconium lake, D & C Yellow # 6 Aluminum lake, D & C Yellow # 7 Zirconium lake, D & C Yellow # 10 Aluminum Lake, FD & C Blue # 1 Aluminum Lake, FD & C Red # 4 Aluminum Lake, FD & C Red # 40 Aluminum Lake, FD & C Yellow # 5 Aluminum Lake, FD & C Yellow # 6 Aluminum Lake . Mention may also be made of liposoluble dyes such as, for example, Sudan Red, DC Red 17, DC Green 6, [3-carotene, soya oil, Sudan Brown, DC Yellow 11, DC Violet 2 , orange DC 5, yellow quinoline.

The chemical materials corresponding to each of the organic dyestuffs mentioned above are mentioned in the "International Cosmetic Integrative Dictionary and Handbook", Edition 1997, pages 371 to 386 and 524 to 528, published by "The Cosmetic, Toiletry, and Fragrance Association". The contents of which are incorporated herein by reference.

The pigments may also have undergone hydrophobic treatment. The hydrophobic treatment agent may be chosen from silicones such as meticones, dimethicones, alkoxysilanes, perfluoroalkylsilanes; fatty acids such as stearic acid; metallic soaps such as aluminum dimyristate, hydrogenated tallow glutamate aluminum salt, perfluoroalkyl phosphates, perfluoroalkyl silanes, perfluoroalkyl silazanes, hexafluoropropylene polyoxides, polyorganosiloxanes comprising perfluoroalkyl perfluoropolyether groups, amino acids ; N-acyl amino acids or their salts; lecithin, isopropyl trisostearyl titanate, and mixtures thereof. The N-acyl amino acids may comprise an acyl group having from 8 to 22 carbon atoms, for example a 2-ethyl hexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl or cocoyl group. The salts of these compounds may be aluminum, magnesium, calcium, zirconium, zin, sodium or potassium salts. The amino acid may be, for example, lysine, glutamic acid or alanine. The alkyl term mentioned in the compounds mentioned above denotes in particular an alkyl group having from 1 to 30 carbon atoms, preferably having from 5 to 16 atoms. of carbon. Hydrophobic-treated pigments are described in particular in application EP-A-1086683.

Nacre For the purposes of the present application, "mother-of-pearl" is understood to mean colored particles of any shape, iridescent or otherwise, in particular produced by certain shellfish in their shell or else synthesized and which exhibit a color effect by optical interference.

Examples of pearlescent agents that may be mentioned are pearlescent pigments such as iron oxide-coated titanium mica, bismuth oxychloride-coated mica, titanium mica coated with chromium oxide, titanium mica coated with a organic dye including the aforementioned type as well as pearlescent pigments based on bismuth oxychloride.

It may also be mica particles on the surface of which are superimposed at least two successive layers of metal oxides and / or organic dyestuffs. The nacres may more particularly have a color or a yellow, pink, red, bronze, orange, brown, gold and / or coppery reflection.

As an illustration of the nacres that can be introduced as interference pigment in the first composition, mention may be made of gold-colored nacres sold especially by BASF under the name Brilliant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), and Monarch gold 233X (Cloisonne); bronze nacres sold especially by the company Merck under the names Bronze Fine (17384) (Colorona) and Bronze (17353) (Colorona) and by the company BASF under the name Super Bronze (Cloisonne); orange nacres sold especially by BASF under the name Orange 363C (Cloisonne) and by MERCK under the name Passion orange (Colorona) and Matte orange (17449) (Microna); the nacres of brown hue sold especially by ENGELHARD under the name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chroma-lite); nacres with a copper sheen sold especially by BASF under the name Copper 340A (Timica); the nacres with a red glint sold especially by MERCK under the name Sienna fine (17386) (Colorona); yellow-colored pearlescent agents marketed by BASF under the name Yellow (4502) (Chroma-lite); the gold-colored red-colored pearlescent agents marketed by BASF under the name Sunstone G012 (Gemtone); pink nacres sold especially by the company BASF under the name Tan opal G005 (Gemtone); the black nacres with gold reflection sold by the company BASF under the name Nu antique bronze 240 AB (Timica), the blue nacres sold especially by the company MERCK under the name Matte blue (17433) (Microna), white nacres with reflection silver sold in particular by the company Merck under the name Xirona Silver and the golden-green orange-colored mother-of-pearl sold by Merck under the name Indian Summer (Xirona) and mixtures thereof. Goniochromatic Pigments For the purpose of the present invention, the term "goniochromatic pigment" denotes a pigment which makes it possible to obtain, when the composition is spread on a support, a color path in the plane a * b * of the CIE 1976 color space. which corresponds to a variation Dh ° of the angle of h ° h of at least 20 ° when the angle of observation is varied with respect to the normal between 0 ° and 80 °, for an angle of incidence of light 45 °. The color path can be measured for example by means of an INSTRUMENT SYSTEMS brand spectrogoniorflectometer and GON 360 GON IOMETER reference, after the composition has been spread in the fluid state with a thickness of 300 μm by means of a automatic spreader on an ERICHSEN brand contrast card and Typ 24/5, the measurement being made on the black background of the card. The goniochromatic pigment may be chosen for example from interferential multilayer structures and liquid crystal coloring agents.

In the case of a multilayer structure, this may comprise for example at least two layers, each layer being made for example from at least one material selected from the group consisting of the following materials: MgF2, CeF3, ZnS , ZnSe, Si, 5iO2, Ge, Te, Fe2O3, Pt, Va, Al2O3, MgO, Y2O3, S2O3, SiO, HfO2, ZrO2, CeO2, Nb2O5, Ta2O5, TiO2, Ag, Al, Au, Cu, Rb, Ti, Ta, VV, Zn, MoS2, cryolite, alloys, polymers and their combinations. The multilayer structure may or may not have, with respect to a central layer, a symmetry at the chemical nature of the stacked layers.

Depending on the thickness and nature of the different layers, different effects are obtained. Examples of symmetrical multilayer interference structures are for example the following structures: Fe 2 O 3 / 5iO 2 / Fe 2 O 3 / 5iO 2 / Fe 2 O 3, a pigment having this structure being marketed under the name SICOPEARL by the company BASF; Mo52 / 5122 / mica-oxide / 5122 / Mo52; Fe 2 O 3 / 5I 2 O / micaoxide / 5I 2 O / Fe 2 O 3; TiO 2 / 5iO 2 / TiO 2 and TiO 2 / Al 2 O 3 / TiO 2, pigments having these structures being sold under the name Xirona by the company Merck. Liquid crystal coloring agents include, for example, silicones or cellulose ethers onto which mesomorphic groups are grafted. As liquid crystal goniochromatic particles, it is possible, for example, to use those sold by the company Chenix as well as those sold under the name Helicone® HO by the company VVacker. As goniochromatic pigment, it is also possible to use certain nacres, pigments having effects on a synthetic substrate, in particular an alumina-type substrate, silica, borosilicate, iron oxide, aluminum, or interfering flakes derived from a polyterephthalate film. By way of nonlimiting examples of goniochromatic pigments, mention may be made, alone or in mixtures, of SunShine® goniochromatic pigments sold by Sun, Toyo Aluminum Celestial Cosmol 0 by K.K., Merck's Xirona 0, Reflecks Multidimensions0 by BASF. These particles may optionally comprise or be covered with optical brightener (s) (or white organic fluorescent substances). Optical brighteners are compounds well known to those skilled in the art. Such compounds are described in "Fluorescent Vishing Agent, Encyclopedia of Chemical Technology, Kirk-Othmer," Vol. 11, p. 227-241, 4th edition, 1994, VViley. Their use in cosmetics derives particular benefit from the fact that they consist of chemical compounds with fluorescent properties that absorb in the ultraviolet (maximum absorption at a wavelength of less than 400 nm) and re-emit energy. by fluorescence for a wavelength between 380 and 830 nm. They can more particularly be defined as compounds which absorb essentially in the UVA between 300 and 390 nm and re-emit essentially between 400 and 525 nm. Their lightening effect is more particularly based on an energy emission of between 400 and 480 nm, which corresponds to an emission in the blue of the visible range, which contributes, when this emission takes place on the skin, to lighten it visually. . Stilbene derivatives, in particular polystyrylstilbenes and triazinstilbenes, coumarin derivatives, in particular hydroxycoumarines and aminocoumarines, oxazole derivatives, benzoxazole derivatives, imidazole derivatives, triazole derivatives, pyrazoline derivatives, pyrene derivatives, are especially known as optical brighteners. porphyrin derivatives and mixtures thereof. Optical brighteners that can be used can also be in the form of copolymers, for example of acrylates and / or methacrylates, grafted with optical brightening groups as described in application FR 99 10942. Additional charges By "charges", it is necessary to understand colorless or white, solid particles of all shapes, which are in an insoluble form and dispersed in the medium of the composition, and are of inorganic or organic nature. As used herein, the term "inorganic filler" means any inorganic solid which is insoluble in the medium at room temperature (25 ° C.). By "inorganic" is meant any compound or polymer whose chemical structure does not include a carbon atom.

The fillers may or may not be superficially coated, and in particular they may be surface-treated with silicones, amino acids, fluorinated derivatives or any other substance which promotes dispersion and compatibility of the filler in the composition.

Such fillers are distinct from the mineral thickeners as well as previously described coloring agents. The charges may be spherical, that is to say comprise at least one rounded general portion, preferably defining at least one portion of sphere, preferably defining internally a concavity or hollow (sphere, globules, bowls, horseshoe , etc.) or lamellar. Such fillers are advantageously chosen from: silica powders, such as the porous silica microspheres sold under the name SILICA BEADS SB-700 by the company MYOSHI; "SUNSPHERE® H51", "SUNSPHERE® H33" by the company ASAHI GLASS; polydimethylsiloxane-coated amorphous silica microspheres sold under the name "SA SUNSPHERE® H 33", "SA SUNSPHERE® H53" by the company ASAH I GLASS. acrylic (co) polymer powders, and their derivatives, in particular: the polymethyl methacrylate powder sold under the names COVABEAD® LH85 by the company VVACKHERR, or MICROSPHERE M-100® by the company Matsumoto; * the polymethyl methacrylate / ethylene glycol dimethacrylate powder sold under the name DOW CORNING 5640 MICROSPONGE® SKIN OIL ADSORBER by the company Dow Corning; GANZPEARL® GMP-0820 by the company GANZ CH EM ICAL, * the allyl polymethacrylate / ethylene glycol dimethacrylate powder sold under the name POLY-PORE® L200, POLY-PORE E200 by the company AMCOL Health and Beauty Solutions Inc., * the ethylene glycol dimethacrylate / lauryl methacrylate copolymer powder sold under the name POLYTRAP® 6603 by the company Dow Corning; the acrylate / alkyl acrylate copolymer powder, optionally crosslinked, crosslinked acrylate / ethylhexyl acrylate copolymer sold under the name TECHPOLYM ER ACP-8C by the company SEKISU I PLASTICS, and the ethylene-acrylate copolymer powder, as sold under the name FLOBEADS ® by Sumitomo Seika Chemicals, * hollow particles of expanded acrylonitrile (co-) polymer sold under the name EXPANCEL by Expancel, or microspheres marketed under the name MICROPEARL F 80 EDO by the company Matsumoto; polyurethane powders, for example sold under the names PLASTIC POVVDER D-400, PLASTIC POVVDER CS-400, PLASTIC POVVDER D25 800 and PLASTIC POVVDER T-75 by the company TOSHIKI; silicone powders advantageously chosen from: polymethylsilsesquioxane powders, especially those sold under the name Tospearl, in particular Tospearl 145 A, by the company Momentive Performance Materials, organopolysiloxane elastomer powders coated with silicone resin, in particular silsesquioxane resin, such as the products sold under the name KSP-100, KSP-101, KSP-102, KSP-103, KSP-104, KSP-105 by the company Shin Etsu, (INCI name: vinyl dimethicone / methicone silsesquioxane) crosspolymer); Silicone elastomer powders such as the products sold under the name Trefil® Powder E-505C and Trefil® Powder E-506C by the company Dow Corning; and the powders of organosilicone particles, for example in the form of bowls such as those described above. in JP-2003 128 788, JP-A-2000-191789, or in the application EP1579841 and sold in particular by TAKEMOTO OIL & FAT. polyamide powders, such as Nylon®, in particular nylon 12; as the nylon powders sold under the name ORGASOL 2002 5 EXS NAT COS by the company ARKEMA. powders of natural organic materials such as polysaccharide powders, and in particular starch powders, in particular corn, wheat or rice starch, crosslinked or otherwise, starch powders crosslinked with anhydride octenylsuccinate, sold under the name DRY-FLOC) 10 by the company National Starch, waxy corn starch powders such as those sold under the names C * GEL 04201 by the company CARGILL, AMIDON DE MAIS B by the company ROQUETTE, and ORGANIC CORN STARCH by DRACO NATURAL PRODUCTS; spherical cellulose microparticles, such as CELLULOBEADS D-10, CELLULOBEADS D-5 and CELLULOBEADS USF sold by the company DAITO KASEI KOGYO. the amino acid particles N-acylated at C8-C22 carbon atoms, the amino acid may be for example lysine, glutamic acid, alanine, preferably lysine. For example AMIHOPE LL by the company AJINOMOTO or 20 which is marketed under the name CORUM 5105 S by CORUM. Perlite powders, for instance those sold by the company Voral MineralS under the trade name Perlite P1430, Perlite P2550, Perlite P2040, or Optimatm 1430 OR or 2550 OR. EUROPERL EMP-2 and 25 EUROPERL 1 by the company IMERYS - zeolites such as products marketed by ZEOCHEM under the names ZEOFLAIR 300, ZEOFLAIR 200, ZEOFLAIR 100, X-MOL and X-MOL MT. calcium carbonate magnesium particles, such as those marketed by the company IMERYS under the name CALCIDOL, by the company LCVV (Sensient) under the name CARBOMAT, by the company OMYA under the name OMYACARE S 60-AV. It is also possible to use talc particles, for example sold under the names LUZENAC PHARMA M and UM by the company IMERYS, ROSE TALC and TALC SG-2000 by the company Nippon Talc; natural or synthetic mica particles, such as those sold under the names MICA M RP and SILK MICA by the company Merck, or the product sold under the name Sericite S-152-BC by the company Myoshi Kasei; calcium carbonate and magnesium hydrogen carbonate; hydroxyapatite; boron nitride; fluorphlogopite, and their mixtures. The spherical fillers may be coated with a hydrophobic treatment agent. The hydrophobic treatment agent may be selected from fatty acids such as stearic acid; metallic soaps such as aluminum dimyristate, aluminum salt of hydrogenated tallow glutamate; amino acids; N-acyl amino acids or their salts; lecithin, isopropyl trisostearyl titanate, and mixtures thereof. The N-acyl amino acids may comprise an acyl group having from 8 to 22 carbon atoms, for example a 2-ethyl hexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl or cocoyl group. The salts of these compounds may be the aluminum, magnesium, calcium, zirconium, zinc, sodium or potassium salts. The amino acid can be for example lysine, glutamic acid, alanine. The term alkyl mentioned in the compounds mentioned above denotes in particular an alkyl group having from 1 to 30 carbon atoms, preferably having from 5 to 16 carbon atoms. The composition advantageously has a content of additional filler (s) of between 0.1 and 10% by weight, relative to the weight of the composition, preferably between 0.1 and 5% by weight, more preferably from 0.1 to 2.5% by weight, relative to the weight of the composition. Optional additives The composition may comprise at least one optional ingredient chosen for example from non-volatile oils, hydrocarbon or silicone, polar or apolar; the film-forming agents different from the previously stabilized polymer particles; antioxidants; conservatives ; the perfumes ; the aromas ; neutralizers; emollients; organic thickeners; coalescing agents; moisturizers; vitamins, and mixtures thereof. Of course, those skilled in the art will take care to choose any additional additives and / or their amount so that the advantageous properties of the composition according to the invention are not, or not substantially impaired by the addition envisaged.

The compositions according to the invention are therefore intended for the care and / or makeup of keratinous substances, in particular the skin, the lips, as well as keratinous fibers such as eyelashes, eyebrows. They advantageously contain a physiologically acceptable medium, ie a medium compatible with the treated keratin materials. A composition according to the invention may be more particularly a composition for makeup and / or care of keratin materials, in particular the skin and / or lips, and better lips. According to a preferred embodiment, a composition of the invention is in liquid form. The invention is illustrated in more detail in the following examples.

All percentages of reagents described in the examples are percentages by weight. Synthesis Examples Example 1 In a first step, 1300 g of isododecane, 337 g of isobornyl acrylate, 28 g of methyl acrylate and 3.64 g of tert-butylperoxy-2-ethylhexanoate (1300 g) were introduced into a reactor ( Trigonox 21S from Akzo). The mass ratio Isobornyl Acrylate / Methyl Acrylate is 92/8. The mixture was heated to 90 ° C under argon with stirring. After 2 hours of reaction, 1430 g of isododecane were added to the reactor bottom, and the mixture was heated to 90 ° C.

In a second step, a mixture of 1376 g of methyl acrylate, 1376 g of isododecane and 13.75 g of Trigonox 21S was introduced over 2 hours 30 minutes and allowed to react for 7 hours. 3.3 liters of isododecane were then added and then a portion of the isododecane was evaporated to obtain a solids content of 50% by weight. A dispersion of methyl acrylate particles stabilized with a random copolymer stabilizer containing 92% isobornyl acrylate and 8% methyl acrylate was obtained in isododecane.

The oily dispersion contains in total (stabilizer + particles) 80% of methyl acrylate and 20% of isobornyl acrylate. The polymer particles of the dispersion have a number average size of about 160 nm. The dispersion is stable after storage for 7 days at room temperature (25 ° C).

EXAMPLE 2 A polymer dispersion was prepared in isododecane, according to the method of preparation of Example 1, using: Step 1: 275.5 g of isobornyl acrylate, 11.6 g of acrylate methyl, 11.6 g of ethyl acrylate, 2.99 g of Trigonox 21, 750 g of isododecane; then addition after reaction of 750 g of isododecane Step 2: 539.5 g of methyl acrylate, 539.5 g of ethyl acrylate, 10.8 g of Trigonox 21S, 1079 g of isododecane. After reaction, addition of 2 liters of isododecane and evaporation to obtain a solids content of 35% by weight.

An isododecane dispersion of methyl acrylate / ethyl acrylate (50/50) copolymer particles stabilized with a random copolymer stabilizer isobornyl acrylate / methyl acrylate / ethyl acrylate (92/4 / 4).

The oily dispersion contains in total (stabilizer + particles) 40% of methyl acrylate, 40% of ethyl acrylate and 20% of isobornyl acrylate. The dispersion is stable after storage for 7 days at room temperature (25 ° C). EXAMPLE 3 A polymer dispersion in isododecane was prepared according to the method of preparation of Example 1, using: Step 1: 315.2 g of isobornyl acrylate, 12.5 g of acrylate methyl, 12.5 g of ethyl acrylate, 3.4 g of Trigonox 21, 540 g of isododecane, 360 g of ethyl acetate; then addition after reaction of 540 g of isododecane and 360 g of ethyl acetate.

Step 2: 303 g of methyl acrylate, 776 g of ethyl acrylate, 157 g of acrylic acid, 11 g of Trigonox 21S, 741.6 g of isododecane and 494.4 g of ethyl acetate. ethyl. After reaction, addition of 3 liters of a mixture of isododecane / ethyl acetate (60/40 w / w) and total evaporation of the ethyl acetate and partial of the isododecane to obtain a solids content of 44% by weight. weight. An isododecane dispersion of methyl acrylate / ethyl acrylate / acrylic acid copolymer particles (24.5 / 62.8 / 12.7) stabilized with a random copolymer stabilizer isobornyl acrylate / acrylate was obtained of methyl / ethyl acrylate (92/4/4). The oily dispersion contains in total (stabilizer + particles) 10% of acrylic acid, 20% of methyl acrylate, 50% of ethyl acrylate and 20% of isobornyl acrylate.

The dispersion is stable after storage for 7 days at room temperature (25 ° C). EXAMPLE 4 A polymer dispersion in isododecane was prepared according to the method of preparation of Example 1 using: Step 1: 315.2 g isobornyl acrylate, 12.5 g acrylate methyl, 12.5 g of ethyl acrylate, 3.4 g of Trigonox 21, 540 g of isododecane, 360 g of ethyl acetate; then addition after reaction of 540 g of isododecane and 360 g of ethyl acetate. Step 2: 145 g of methyl acrylate, 934 g of ethyl acrylate, 157 g of acrylic acid, 12.36 g of Trigonox 21S, 741.6 g of isododecane and 494.4 g of acetate ethyl. After reaction, addition of 3 liters of a mixture of isododecane / ethyl acetate (60/40 w / w) and total evaporation of the ethyl acetate and partial of the isododecane to obtain a solids content of 44% by weight. weight. An isododecane dispersion of methyl acrylate / ethyl acrylate / acrylic acid (11.7 / 75.6 / 12.7) copolymer particles stabilized with a random copolymer stabilizer isobornyl acrylate / acrylate was obtained. of methyl / ethyl acrylate (92/4/4). The oily dispersion contains in total (stabilizer + particles) 10% of acrylic acid, 10% of methyl acrylate, 60% of ethyl acrylate and 20% of isobornyl acrylate. The dispersion is stable after storage for 7 days at room temperature (25 ° C). EXAMPLE 5 A polymer dispersion in isododecane was prepared according to the method of preparation of Example 1, using: Step 1: 48 g isobornyl acrylate, 2 g methyl acrylate, 2 g of ethyl acrylate, 0.52 g of Trigonox 21, 57.6 g of isododecane, 38.4 g of ethyl acetate; then addition after reaction of 540 g of isododecane and 360 g of ethyl acetate. Step 2: 98 g of methyl acrylate, 73 g of ethyl acrylate, 25 g of maleic anhydride, 1.96 g of Trigonox 21S, 50.4 g of isododecane and 33.60 g of acetate ethyl. After reaction, addition of 1 liter of a mixture of isododecane / ethyl acetate (60/40 w / w) and total evaporation of the ethyl acetate and partial isododecane to obtain a dry extract of 46.2 % in weight.

An isododecane dispersion of methyl acrylate / ethyl acrylate / maleic anhydride copolymer particles (50 / 37.2 / 12.8) stabilized with a stabilizing random copolymer of isobornyl acrylate / methyl acrylate / ethyl acrylate (92/4/4).

The oily dispersion contains in total (stabilizer + particles) 10% of maleic anhydride, 30% of methyl acrylate, 40% of ethyl acrylate and 20% of isobornyl acrylate.

The dispersion is stable after storage for 7 days at room temperature (25 ° C). Example 6 A polymer dispersion in isododecane was prepared according to the method of preparation of Example 1, using: Step 1: 48.5 g of isobornyl methacrylate, 4 g of methyl acrylate, 52 g of Trigonox 21, 115 g of isododecane; then addition after reaction of 80 g of isododecane.

Step 2: 190 g of methyl acrylate, 1.9 g of Trigonox 21S, 190 g of isododecane. After reaction, addition of 1 liter of isododecane and partial evaporation of the isododecane to obtain a solids content of 48% by weight. An isododecane dispersion of methyl acrylate polymer particles stabilized with a statistical copolymer stabilizer of isobornyl methacrylate / methyl acrylate (92/8) was obtained.

The oily dispersion contains in total (stabilizer + particles) 80% of methyl acrylate and 20% of isobornyl methacrylate. The dispersion is stable after storage for 7 days at room temperature (25 ° C).

Examples 7: Liquid Lipsticks The following compositions are prepared, the ingredients of which are summarized in the table below. The percentages are given by weight relative to raw materials, unless otherwise indicated. Ingredients Composition 1 Composition Comparative Invention Tributyl citrate 3.73 3.73 Disteardominium hectorite (BENTONE gel 10 ISDV; Elementis) (hectorite, isododecane, propylene glycol) Ethylcellulose (Aquacoat® ECD 30 from FMC 26.3 - Biopolymer; in ethylcellulose water, sodium lauryl sulphate, cetyl alcohol, 30% solids) Water - 26.3 Copolymer (Methyl Acrylate) -co- 52.35 52.35 (Ethyl Acrylate) -co- (Acid Acrylic) -co- (Isobornyl Acrylate) in isododecane (according to Example 4 CETYL PEG / PPG-10/1 DIMETHICONE (Abil EM 90 from Evonik Industries) 1.5 1.5 030-45 Alkyldimethylsilyl Polypropyl-O, 0.53 silsesquioxane (Dow Corning SVV-8005030 Dow Corning Resin Wax) triglycerol-4-isostearate (ISOLAN GI 34 0.5 0.5 Evonik Industries) Pigments 3.33 3.33 Preservative 0.7 0, 7 lsododecane qs qs Preparation protocol In a magnetic stirring beaker, the dispersion of ethylcellulose or water is mixed if it is not t not present and the preservative at room temperature. Furthermore, the dispersion of polymer particles according to Example 4 is mixed with the bentone gel, the silicone wax presolubilized hot in a part of the isododecane, the isododecane remaining in a container adapted to the speed mixer up to obtaining a smooth and homogeneous mixture. Then, in a skillet, the surfactants (lsolan GI 34 and Abil EM 90) are introduced into the preceding mixture and are homogenized with a mixer for 2 minutes until a homogeneous phase is obtained. soft white and opaque. The pre-milled pigments are then added to a portion of the isododecane and tributyl citrate and the mixture is homogenized. The aqueous phase, which may or may not comprise ethyl cellulose, is then introduced to obtain the emulsion and the mixture is mixed (for about 3 minutes) until a thick, smooth, glossy and homogeneous mixture is obtained. . Evaluation of the compositions Oil resistance test: On a BIOSKIN skin sample, the composition is applied (thickness of the wet film 25 μm). The sample is allowed to dry for 24 hours at 35 ° C. After the drying step a drop of olive oil is placed on the composition film and left for ten minutes.

The oil is then wiped off five times using a cotton pad. The integrity of the film after cotton passage is evaluated to evaluate the oil resistance of the composition, on a scale of 1 to 3, (1: excellent strength, 2: intermediate strength, and 3: poor strength) Protocol for Evaluating the Sticky: The composition is applied to the lips so as to form a deposit of uniform thickness. The stickiness of the finger was evaluated during the drying of the formula after 5 minutes at room temperature (25 ° C).

To do this, a finger was applied, at the end of the specified drying time, to the applied formula and the panty was appreciated by the subject when his finger was removed from the applied formula. Both compositions are easily applied in a deposit which after drying is not drying.

It is found that the composition according to the invention significantly improves the oil resistance and tackiness of the deposit, compared to the properties of the deposition of the comparative composition. EXAMPLES 8 Lipstick Liquid Lipsticks The following compositions are prepared, the ingredients of which are collated in the table below. The percentages are given by weight relative to raw materials, unless otherwise indicated. Ingredients Composition 2 Composition 3 Invention Tributyl citrate - 2.5 Disteardominium hectorite (BENTONE gel 13.27 8 ISDV; Elementis) (hectorite, isododecane, propylene glycol) Ethylcellulose (Aquacoat® ECD 30 from FMC 17.17 18 Biopolymer; in ethylcellulose water, sodium lauryl sulphate, cetyl alcohol, 30% solids) Water - 6.94 Copolymer (Methyl Acrylate) -co- 61.94 - (Ethyl Acrylate) -co- (Acrylic Acid) -co- (Isobornyl acrylate) in isododecane (according to Example 3 Copolymer (methyl acrylate) -co- (ethyl acrylate) -co- (acrylic acid) -co- (isobornyl acrylate) in isododecane (according to Example 4) 030-45 Alkyldimethylsilyl 0.53 0.48 Polypropylsilsesquioxane (Dow Corning SVV-8005 030 Resin Wax from Dow Corning) triglycerol-4-isostearate (ISOLAN GI 34 from 0.5 0.67 Evonik Industries ) Cetyl PEG / PPG-10/1 Dimethicone (Abil EM 1.5 2 90 from Evonik Industries) Pigments 3.33 2.36 Preservative 0.7 0.7 Perfume - 0.2 sweetener 0.03 lsododecane qs qs Preparation protocol In a magnetic stirring beaker, mix the ethylcellulose dispersion, the preservative and the sweetener if it is present at room temperature. Furthermore, the dispersion of polymer particles according to Example 3 is mixed with the bentone gel, the hot-presolubilized silicone wax in a part of the isododecane, the remaining isododecane and the perfume if it is present in a container adapted to the speed mixer until a smooth and homogeneous mixture is obtained. Then, in a skillet, the surfactants (lsolan GI 34 and Abil EM 90) are introduced into the preceding mixture and are homogenized with a mixer for 2 minutes until a homogeneous phase is obtained. soft white and opaque. The precured pigments are then added to a portion of the isododecane and tributyl citrate and the mixture is homogenized. The aqueous phase comprising ethylcellulose is then introduced to obtain the emulsion and the mixture (mixer, for about 3 minutes) is mixed until a thick, smooth, glossy and homogeneous mixture is obtained. Results The compositions are easily applied, give a homogeneous deposition, non-drying, non-tacky and resistant to oil (tests carried out according to the protocols detailed in the previous example). Composition 2 Composition 3 Invention Oil Resistance Good Good Sticky after 5 minutes Good Good Examples 9: Liquid lipstick lip gloss type The following compositions are prepared whose ingredients are summarized in the table below. The percentages are given by weight relative to raw materials, unless otherwise indicated. Ingredients Composition 4 invention Disteardominium hectorite (BENTONE gel ISDV; Elementis) 13,27 (hectorite, isododecane, propylene glycol) Ethylcellulose (Aquacoat® ECD 30 from FMC Biopolymer, dispersion in ethylcellulose water, sodium lauryl sulphate, cetyl alcohol dry matter 30%) Water 2 Copolymer (methyl acrylate) -co- (ethyl acrylate) -co- (57,22 acrylic acid) -co- (isobornyl acrylate) in isododecane (according to Example 4 40 0-45 Alkyldimethylsilyl Polypropylsilsesquioxane (Dow Corning SVV-8005030 Dow Corning Resin Wax) 0.53 triglycerol-4-isostearate (ISOLAN GI 34 from Evonik Industries) 0.66 Cetyl PEG / PPG-10/1 Dimethicone (Abil EM 90 of Evonik 2 Industries) Trimethyl pentaphenyl trisiloxane (Dow Corning PH-1555 HRI 2.49 Cosmetic Fluid from Dow Corning) Pigments 2.33 Preservative 0.7 lsododecane qs Protocol of preparation In a beaker with stirring at the magnetic bar, the dispersion is mixed of ethylcellulose, the preservative ambient temperature.

Furthermore, the dispersion of polymer particles according to Example 3 is mixed with the bentone gel, the silicone wax presolubilized hot in a portion of the isododecane, the isododecane remaining in a container adapted to the speed mixer up to obtaining a smooth and homogeneous mixture. Then, in a skillet, the surfactants (lsolan GI 34 and Abil EM 90) are introduced into the preceding mixture and are homogenized with a mixer for 2 minutes until a homogeneous phase is obtained. soft white and opaque. The precured pigments are then added to a portion of the isododecane and tributyl citrate and the mixture is homogenized. The aqueous phase comprising ethylcellulose is then introduced to obtain the emulsion and the mixture (mixer, for about 3 minutes) is mixed until a thick, smooth, glossy and homogeneous mixture is obtained. The composition is easily applied in a homogeneous, non-drying, non-tacky and oil-resistant deposit. 41

Claims (5)

REVENDICATIONS1. Composition in the form of a water-in-oil emulsion comprising particles of at least one polymer stabilized on the surface with a stabilizing agent, the polymer of the particles being a polymer of C 1 -C 4 alkyl (meth) acrylate, the stabilizing agent being a polymer of isobornyl (meth) acrylate selected from homopolymer of isobornyl (meth) acrylate and random copolymers of isobornyl (meth) acrylate and C1-C4 alkyl (meth) acrylate present in a ratio by weight of isobornyl (meth) acrylate / C1-C4 alkyl (meth) acrylate greater than 4; at least one hydrocarbon oil; at least one surfactant; and water. 2. Composition according to claim 1, characterized in that the polymer of the particles is a polymer of methyl acrylate and / or ethyl acrylate. 3. Composition according to any one of the preceding claims, characterized in that the polymer of the particles comprises an ethylenically unsaturated acidic monomer or their anhydride, preferably chosen from (meth) acrylic acid, maleic acid and maleic anhydride. 4. Composition according to any one of the preceding claims, characterized in that the polymer of the particles comprises from 80 to 100% by weight of C1-C4 alkyl (meth) acrylate and from 0 to 20% by weight of ethylenically unsaturated acid monomer, based on the total weight of the polymer. 5. Composition according to any one of the preceding claims, characterized in that the polymer of the particles is chosen from: homopolymers of methyl acrylate homopolymers of ethyl acrylate copolymers of methyl acrylate / ethyl acrylate copolymers methyl acrylate / ethyl acrylate / acrylic acid copolymers methyl acrylate / ethyl acrylate / maleic anhydride copolymers methyl acrylate / acrylic acid copolymers ethyl acrylate / acrylic acid methyl acrylate copolymers / maleic anhydride ethyl acrylate / maleic anhydride copolymers. 42. Composition according to any one of the preceding claims, characterized in that the stabilizing agent is a random copolymer of isobornyl (meth) acrylate and (C 1 -C 4) alkyl (meth) acrylate present in a ratio isobornyl (meth) acrylate / C1-C4 alkyl (meth) acrylate greater than or equal to 5. 7. Composition according to any one of the preceding claims, characterized in that the stabilizing agent is chosen from: homopolymers of isobornyl acrylate random copolymers of isobornyl acrylate / methyl acrylate random copolymers of isobornyl acrylate / methyl acrylate / ethyl acrylate random copolymers of isobornyl methacrylate / methyl acrylate. 8. Composition according to any one of the preceding claims, characterized in that the stabilizer + polymer group of the particles comprises from 10 to 50% by weight of polymerized isobornyl (meth) acrylate and from 50 to 90% by weight of (C 1 -C 4) alkyl (meth) acrylate polymerized, based on the total weight of the stabilizer + polymer group of the particles. 9. Composition according to any one of the preceding claims, characterized in that the hydrocarbon oil is chosen from apolar hydrocarbon oils having 8 to 16 carbon atoms, and preferably isododecane. 10. Composition according to any one of the preceding claims, characterized in that the content of hydrocarbon oil varies from 20 to 75% by weight, preferably from 20 to 60% by weight, relative to the weight of the composition. 11. Composition according to any one of the preceding claims, characterized in that it comprises a plasticizer selected from n-butyl tri-citrate, tripropylene glycol monomethyl ether, trimethyl pentaphenyl trisiloxane. 12. Composition according to any one of the preceding claims, characterized in that the polymer particles stabilized at the surface by a stabilizing agent are incorporated into the composition in the form of a dispersion in at least one hydrocarbon oil. 13. Composition according to any one of the preceding claims, characterized in that the content of polymer particles represents from 5 to 55% by weight relative to the weight of the composition. 14. Composition according to any one of the preceding claims, characterized in that the composition comprises at least alkylcellulose whose alkyl residue comprises between 2 and 6 carbon atoms, preferably between 2 and 3 carbon atoms, of preferably the alkylcellulose is chosen from ethylcellulose and propylcellulose, preferably ethylcellulose. 15. Composition according to the preceding claim, characterized in that the content of alkylcellulose represents from 1 to 8% by weight, relative to the weight of the composition, preferably from 2.5 to 6% by weight, relative to the weight of the composition. 16. Composition according to one of the preceding claims, characterized in that the water content varies between 10 and 50% by weight relative to the weight of the composition, and preferably between 10 and 40% by weight relative to the weight. of the composition. 17. Composition according to any one of the preceding claims, characterized in that the surfactant or surfactants are chosen from polyol fatty acid esters; alkyl or alkoxy dimethicone copolyols having a pendant alkyl or alkoxy chain or a silicone backbone having, for example, from 6 to 22 carbon atoms; polymers of the polyoxyalkylene glycol fatty acid ester type, and mixtures thereof. 18. Composition according to the preceding claim, characterized in that the content of surfactant (s) in the composition varies from 0; 2% to 10% by weight relative to the weight of the composition, or even from 0.5% to 7%. % by weight, based on the weight of the composition. 19. Composition according to any one of the preceding claims, characterized in that the composition comprises at least one mineral thickener chosen from clays, optionally hydrophobic modified, silicas, optionally hydrophobic modified, or mixtures thereof, preferably modified 44hectorites; fumed silicas optionally hydrophobic treated; hydrophobic silica aerogels, their mixtures. 20. Composition according to the preceding claim, characterized in that the mineral thickener content is 0.2 to 15% by weight, preferably 0.5 to 7% by weight, relative to the weight of the composition. 21. A process for making up and / or caring for human keratin materials, wherein the composition according to any one of the preceding claims is applied. 45