FR2918272A1 - Cosmetic care/make-up composition, useful for make-up of skin, lips and/or integument, comprises a first resin comprising rosin/its derivatives and/or hydrocarbon resin, a silicone polyamide, and a second resin - Google Patents

Abstract

Cosmetic care or make-up composition comprises: at least a first resin having a number average molecular weight of = 10000 g/mol comprising rosin or its derivatives and/or hydrocarbon resin; and at least a silicone polyamide; and at least a second resin, which is a silicone. Independent claims are included for: (1) make-up product comprising a first composition and a second composition comprising at least a liquid fatty phase; and (2) a make-up kit comprising at least a product.

Description

The present invention relates to a cosmetic composition, in particular

  makeup and / or care intended to be applied to the skin, the lips or the integuments of human beings such as hair, eyelashes, eyebrows or nails, comprising at least one liquid fatty phase comprising at least one silicone polyamide, at least one tackifying resin and at least one silicone resin.

  An object of the present invention is to provide a makeup that is both good and bright. Another object of the present invention is to provide a makeup or a care whose application is pleasant, especially in terms of sliding on application, and having gloss properties. In particular, the compositions according to the invention have a very good behavior and are non-transferable, once applied to keratin materials. It also has a satisfactory level of gloss.

  Poor behavior over time can result in particular in poor color retention and / or poor gloss performance over time. This poor performance may be characterized by a change in color (turning, paling) generally as a result of an interaction with sebum and / or sweat secreted by the skin in the case of foundation and make-up, or of an interaction with saliva in the case of lipsticks, or a decrease in gloss, in the case of a nail polish. This forces the user to remix himself very often, which can be a waste of time.

  The makeup compositions for the lips and the so-called non-transfer skin are compositions which have the advantage of forming a deposit which does not transfer, at least in part, onto the supports with which they are brought into contact (glass, clothing, cigarette, tissues)

  Unexpectedly, the inventors have found that the use of a tackifying resin and a silicone resin in combination with a silicone polyamide made it possible to obtain satisfactory compositions in these terms.

  Accordingly, according to a first aspect, the present invention relates to a cosmetic make-up or care composition comprising, in a physiologically acceptable medium, at least one fatty phase comprising: at least one first resin with a number average molecular weight of less than or equal to g / mol chosen from rosin, rosin derivatives, hydrocarbon resins and mixtures thereof, at least one silicone polyamide, and at least one second resin, said second resin being silicone-coated.

  Preferably, the first resin and the silicone polyamide are present in a ratio such that the proportion by mass of silicone polyamide / first resin is greater than or equal to 2. The fact that the composition has, in mass proportion, at least twice as much silicone polyamide that first resin (also called tackifying resin) allows in particular a better performance of the composition after application thereof, particularly with respect to compositions comprising less or as much by weight of silicone polyamide as tackifying resin.

  Preferably, said mass proportion between said at least one silicone polyamide and said first resin ranging from 2 to 40, that is to say that there is between 2 and 40 times more in mass proportion of silicone polyamide than first resin.

  The invention makes it possible to obtain compositions having improved slipperiness and their application is pleasant. The deposit obtained is homogeneous and has improved hold.

  The present invention also relates to a process for the makeup or care of keratin materials and in particular the lips in which a composition as defined above is applied to the lips. Likewise according to another of its aspects, the use of a silicone polyamide in combination with said first resin (also called tackifying resin) and said second silicone resin to prepare a cosmetic composition, stable and able to provide a film of improved fit.

  In addition, the compositions according to the invention have a slipperiness and an improved disintegration during the application, which is therefore more pleasant. According to the invention, the composition can be solid or liquid. Preferably, the composition according to the invention is solid.

  The terms solid and liquid characterize the state of the composition at ambient temperature (25 ° C.) and at atmospheric pressure (760 mmHg). Preferably, the composition according to the invention has, when it is solid, a hardness of between 30 and 300 g, or even 50 to 200 g.

  Shear measurement protocol: The measurement is carried out according to the following protocol: A sample of the composition in question is hot-cast in a stick mold 8 mm in diameter. The mold is then cooled in the freezer for about an hour. The lipstick stick is then stored at 20 C.

  The hardness of the samples is measured after 24 hours of waiting. The hardness of the samples of compositions of the invention, expressed in gram, is measured by means of a DFGS2 dynamometer marketed by INDELCO-CHATILLON. The hardness corresponds to the maximum shear force exerted by a rigid wire 250 m diameter in tungsten advancing at a speed of 100 mm / min. The technique described above is usually referred to as the so-called butter cutting method.

  Silicone Polyamide As indicated above, the compositions according to the invention comprise at least one silicone polyamide. The silicone polyamides of the composition are preferably solid at ambient temperature (25 ° C.) and atmospheric pressure (760 mmHg). For the purposes of the invention, the term "polymer" means a compound having at least 2 repeating units, preferably at least 3 repeating units and more preferably 10 repeating units.

  The silicone polyamides of the composition of the invention may be polymers of the polyorganosiloxane type, for instance those described in documents US Pat. No. 5,874,069, US Pat. No. 5,919,441, US Pat. No. 6,051,216 and US Pat. No. 5,981,680. . According to the invention, the silicone polymers may belong to the following two families: (1) polyorganosiloxanes comprising at least two amide groups, these two groups being located in the polymer chain, and / or (2) polyorganosiloxanes comprising at least two amide groups, these two groups being located on grafts or branches.

  A) According to a first variant, the silicone polymers are polyorganosiloxanes as defined above and whose amide units are arranged in the polymer chain.

  The silicone polyamides may more particularly be polymers comprising at least one unit corresponding to the general formula I: ## STR1 ## in which: G 'represents C (O) when G represents -C (0) -NH-Y-NH-, and G 'is -NH- when G is -NH-C (O) -YC (O) -2) R4, R5, R6 and R7, the same or different, represent a group chosen from: - saturated or unsaturated hydrocarbon groups, linear, branched or cyclic, in C 1 -C 40, which may contain in their chain one or more oxygen, sulfur and / or nitrogen atoms, and which may be substituted by partly or totally by fluorine atoms, - C 6 to C 10 aryl groups, optionally substituted by one or more C 1 to C 4 alkyl groups, polyorganosiloxane chains containing or not containing one or more oxygen, sulfur and / or nitrogen, 3) the X, identical or different, represent a linear alkylene di-yl group or branched C1 to Cao, which may contain in its chain one or more oxygen and / or nitrogen atoms, 4) Y is a divalent linear or branched alkylene, arylene, cycloalkylene, alkylarylene or arylalkylene group, saturated or unsaturated, C1 to Cso, which may comprise one or more oxygen, sulfur and / or nitrogen atoms, and / or may carry as substituent one of the following atoms or groups of atoms: fluorine, hydroxy, C3 cycloalkyl, C8, C1 to C40 alkyl, C5 to C10 aryl, phenyl optionally substituted with 1 to 3 C1 to C3 alkyl, C1 to C3 hydroxyalkyl and C1 to C6 alkyl, or 5) Y is a group corresponding to the formula: in which - T represents a trivalent or tetravalent hydrocarbon group, linear or branched, saturated or unsaturated, C3 to C24 optionally substituted with a polyorganosiloxane chain, and may contain one or more atoms selected from O, N and S, or T represents a trivalent atom chosen from N, P and Al, and - R8 represents a linear or branched C1-C50 alkyl group, or a polyorganosiloxane chain, which may comprise one or more ester, amide, urethane, thiocarbamate, urea, thiourea and / or sulphonamide groups which may be bonded or not to another chain of the polymer, 6) n is an integer ranging from 2 to 500, preferably from 2 to 200, and m 25 is an integer ranging from 1 to 1000, preferably from 1 to 700 and better still from 6 to 200.

  According to one embodiment of the invention, 80% of the R 4, R 5, R 6 and R 7, of the polymer are preferably selected from methyl, ethyl, phenyl and 3,3,3-trifluoropropyl groups. In another embodiment, 80% of the R4, R5, R6 and R7 of the polymer are methyl groups.

  According to the invention, Y may represent various divalent groups, optionally additionally having one or two free valences to establish bonds with other units of the polymer or copolymer. Preferably, Y represents a group chosen from: a) linear C 1 to C 20, preferably C 1 to C 10, alkylene groups, b) branched alkylene groups which may comprise rings and unsaturated C 3 to C 56 unsaturations; ) C5-C6 cycloalkylene groups, d) phenylene groups optionally substituted with one or more C1-C4 alkyl groups, e) C1-C20 alkylene groups having 1 to 5 amide groups, f) alkylene groups C1 to C20, having one or more substituents selected from hydroxyl, C3 to C8 cycloalkane, C1 to C3 hydroxyalkyl and C1 to C6 alkylamines, and g) polyorganosiloxane chains of the formula: R5 to R4 R4 SiO Si Wherein R4, R5, R6, R7, T and m are as defined above. B) According to the second variant, the silicone polyamides may be polymers comprising at least one unit corresponding to formula (II): ## STR1 ## in which - R 4 and R 6, which may be identical or different, are as defined above for the formula (I), - R10 represents a group as defined above for R4 and R6, or represents the group of formula -XG "-R12 in which X are as defined above for the formula (I) and R12 represents a hydrogen atom or a linear, branched or cyclic hydrocarbon group, saturated or unsaturated, with C 1 to C 50 optionally comprising in its chain one or more atoms chosen from O, S and N optionally substituted with one or more fluorine atoms and / or one or more hydroxyl groups, or phenyl optionally substituted with one or more C1-C4 alkyl groups, and G "represents C (O) NH- and NH-C (0) -. R "represents the group of formula -XG" -R12 in which X, G "and R12 are as defined above, - ml is an integer ranging from 1 to 998, and - m2 is an integer ranging from 2 at 500.

  According to the invention, the silicone polymer may be a homopolymer, that is to say a polymer comprising several identical units, in particular units of formula (I) or of formula (II).

  According to the invention, it is also possible to use a polymer consisting of a copolymer comprising several different units of formula (I), that is to say a polymer in which at least one of R4, R5, R6, R7, X, G, Y, m and n are different in one of the patterns. The copolymer may also be formed of several units of formula (II), in which at least one of R4, R6, Rio R ", mi and m2 is different in at least one of the units. polymer comprising at least one unit of formula (I) and at least one unit of formula (II), the units of formula (I) and the units of formula (II) being identical or different from one another. of the invention, it is also possible to use a silicone polyamide comprising in addition at least one hydrocarbon unit comprising two groups capable of establishing hydrogen interactions chosen from ester, amide, sulfonamide, carbamate, thiocarbamate, urea, urethane and thiourea groups, These copolymers may be block polymers, block polymers or graft polymers.

  In the formulas (I) and (II), the alkylene group representing X or Y may optionally contain in its alkylene part at least one of the following elements: 1) 1 to 5 amide groups, urea, urethane, or carbamate, 2 ) a C 5 or C 6 cycloalkyl group, and 3) a phenylene group optionally substituted with 1 to 3 identical or different C 1 to C 3 alkyl groups. In the formulas (I) and (II), the alkylene groups may also be substituted by at least one member selected from the group consisting of: - a hydroxy group - a C3 to C8 cycloalkyl group - one to three alkyl groups C1 to C40 - phenyl optionally substituted with one to three C1 to C3 alkyl groups, - C1 to C3 hydroxyalkyl, and - C1 to C6 aminoalkyl.

  In these formulas (I) and (II), Y may also represent: R8 T where R8 represents a polyorganosiloxane chain, and T represents a group of formula: or R13 (CH2) a C (CH2) b (CH2) a N ( Wherein a, b and c are independently integers from 1 to 10, and R13 is a hydrogen atom or a group such as those defined for R4, R5, R6 and R7. In the formulas (I) and (II), R4, R5, R6 and R7 preferably independently represent a linear or branched C1-C4 alkyl group, preferably a CH3, C2H5, n-C3H7 or isopropyl group. , a polyorganosiloxane chain or a phenyl group optionally substituted with one to three methyl or ethyl groups. As seen above, the polymer may comprise identical or different units of formula (I) or (II). Thus, the polymer may be a polyamide containing several units of formula (I) or (II) of different lengths, ie a polyamide having the formula (III): (CH 2), (CH 2) 4 R ', where NH 4 NH] R6 m ~ R7 n C (O) -X ~ SiO where X (Y), where X, Y, n, R4 to R7 have the meanings given above, mi and m2 which are different, are chosen in the range from 1 to 1000, and p is an integer from 2 to 300.

  In this formula, the units may be structured to form either a block copolymer, a random copolymer, or an alternating copolymer. In this copolymer, the units may be not only of different lengths but also of different chemical structures, for example having different Ys. In this case, the polymer can meet the formula IV:

  R '4 ~~ ~ [C (0) ùXù [ù Si0 SiùXùC (0) ù NH ùYù NHJ ~ C (0) ùX- - Si0 SiùXùC (0) ù NH ùY'ù NH R6 m'R7 n R6 m2R7 JP in which R4 to R7, X, Y, mi, m2, n and p have the meanings given above and YI is different from Y but selected from the groups defined for Y. As previously, the different units can be structured to form either a block copolymer, a random copolymer or an alternating copolymer. In this first embodiment of the invention, the silicone polymer may also consist of a graft copolymer. Thus, the polyamide with silicone units can be grafted and optionally crosslinked with silicone chains containing amide groups. Such polymers can be synthesized with trifunctional amines.

  According to the invention, as seen above, the siloxane units may be in the main chain or backbone of the polymer, but they may also be present in grafted or pendant chains. In the main chain, the siloxane units may be in the form of segments as described above. In the pendant or grafted chains, the siloxane units may appear individually or in segments. According to an alternative embodiment of the invention, it is possible to use a copolymer of silicone polyamide and hydrocarbon-based polyamide, ie a copolymer comprising units of formula (I) or (II) and hydrocarbon-based polyamide units. In this case, the polyamide-silicone units may be disposed at the ends of the hydrocarbon polyamide.

  Advantageously, the composition comprises at least one polyamide / polydimethylsiloxane polymer, in particular a polymer of general formula (I) having an index m of value greater than 50, in particular greater than 75, in particular of approximately 100.

  Advantageously, the silicone polyamide of formula (I) has a weight average molecular weight ranging from 10,000 to 500,000 g / mol.

  More preferably, X and Y independently represent a group selected from linear C 1 to C 20, preferably C 1 to C 10, alkylene groups.

  As examples of usable polymers, mention may be made of one of the silicone polyamides obtained according to Examples 1 to 3 of US Pat. No. 5,981,680, such as the product sold under the reference DC 2-8179 by Dow Corning) . According to an alternative embodiment of the invention, the polymer is constituted by a homopolymer or copolymer comprising urethane or urea groups. These polymers are described in detail in application WO 2003/106614.

  The first composition may contain, in place of the silicone polyamide, a polyorganosiloxane polymer containing two or more urethane and / or urea groups, either in the backbone of the polymer, or on side chains or as groups.

20 pendants.

  Polymers comprising at least two urethane and / or urea groups in the backbone may be polymers comprising at least one unit having the following formula: ## STR1 ## wherein R 4, R 5, R 6, R7, X, Y, m and n have the meanings given above for the formula (I), and U represents -O- or ùNH-, so that: ùR 4 1 Si-O R6 NH corresponds to a urethane group or urea. In this formula, Y may be a linear or branched C1-C40 alkylene group, optionally substituted with C1-C15 alkyl or C5-C10 aryl. Preferably, a - (CH 2) 6 - group is used. The polymer constituting the silicone polymer may be formed of silicone urethane and / or silicone-urea units of different lengths and / or constitution, and may be in the form of block, sequential or random (random) block copolymers. As in the case of silicone polyamides of formula (I), (II) or (III), polyurethanes or silicone polyureas having patterns of different length and structure, in particular length patterns, may be used in the invention. different by the number of silicone units.

  The polymers and copolymers used in the composition of the invention advantageously have a transition temperature of the solid state in the liquid state ranging from 45 ° C. to 190 ° C. Preferably, they have a solid state transition temperature. in the liquid state ranging from 70 to 130 C and better still from 80 C to 105 C.

  The silicone polyamide may be present in the first composition in a total content ranging from 0.5% to 70% by weight relative to the total weight of the composition, preferably ranging from 5% to 50% by weight, and better ranging from From 8% to 45% by weight, preferably from 10 to 40% by weight of the total weight of said composition.

  According to an advantageous embodiment, the composition comprises at least two silicone polyamides, in particular two silicone polyamides each independently comprising at least one unit of formula (I). The silicone polyamides may, for example, have a silicone portion having a different degree of polymerization.

  Preferably, according to this embodiment, m varies from 50 to 600, in particular from 60 to 400, in particular from 75 to 200 and more particularly is of the order of 120 for the first polymer and m is 5 to at 100, in particular from 10 to 75 and more particularly is of the order of 15 for the second polymer.

  Advantageously, the first polymer has a weight average molecular weight of between 10,000 and 500,000 g / mol. Advantageously, the second polymer preferably has a weight average molecular weight ranging from 1,000 to 500,000 g / mol, especially between 10,000 and 300,000 g / mol.

First Resin

  The first resin (also called tackifying resin) used in the composition according to the invention preferably has a number average molecular weight of less than or equal to 10,000 g / mol, in particular ranging from 250 to 10,000 g / mol, preferably lower or equal to 5,000 g / mol, in particular ranging from 250 to 5,000 g / mol, better still, less than or equal to 2,000 g / mol, especially ranging from 250 to 2,000 g / mol and even more preferably less than or equal to 1,000 g in particular mol ranging from 250 to 1000 g / mol. The number average molecular weights (Mn) are determined by liquid gel permeation chromatography (THF solvent, calibration curve established with linear polystyrene standards, refractometric detector). The resin of the composition according to the invention is advantageously a so-called tackifying resin. Such resins are especially described in the Handbook of Pressure Sensitive Adhesive, edited by Donatas Satas, 3rd ed., 1989, p. 609-619. The tackifying resin of the composition according to the invention is chosen from rosin, rosin derivatives, hydrocarbon resins and mixtures thereof. Rosin is a mixture comprising mainly organic acids called rosin acids (mainly abietic and pimaric type acids). There are three types of rosin: rosin ("gum rosin") obtained by incision on live trees, rosin of wood ("wood rosin") that is extracted from stumps or pine wood, and tall oil ("tall oil rosin") which is obtained from a by-product from the production of paper.

  The rosin derivatives may be derived in particular from the polymerization, hydrogenation and / or esterification (for example with polyhydric alcohols such as ethylene glycol, glycerol, pentaerythritol) of rosin acids. There may be mentioned, for example, the rosin esters marketed under the reference FORAL 85, PENTALYN H and STAYBELITE ESTER 10 by the company HERCULES; SYLVATAC 95 and ZONESTER 85 by ARIZONA CHEMICAL or UNIREZ 3013 by UNION CAMP.

  The hydrocarbon resins are chosen from low molecular weight polymers which can be classified, according to the type of monomer they comprise, into: indene hydrocarbon resins such as the resins resulting from the polymerization in majority proportion of monomer indene and in proportion minority of monomer selected from styrene, methylindene, methylstyrene and mixtures thereof. These resins may optionally be hydrogenated. These resins may have a molecular weight ranging from 290 to 1150 g / mol. As examples of indene resins, mention may be made of those sold under the reference ESCOREZ 7105 by the company Exxon Chem., NEVCHEM 100 and NEVEX 100 by the company Neville Chem., NORSOLENE 5105 by the company Sartomer, PICCO 6100 by the company Hercules and Resinall by the company Resinall Corp., or the hydrogenated indene / methylstyrene / styrene copolymers sold under the name REGALITE by the company Eastman Chemical, in particular REGALITE R 1100, REGALITE R 1090, REGALITE R7100, REGALITE R1010, HYDROCARBON RESIN, REGALITE R1125 HYDROCARBON RESIN . aliphatic pentanediene resins such as those resulting from the polymerization mainly of 1,3-pentanediene monomers (trans or cis piperylene) and of a minor monomer chosen from isoprene, butene, 2-methyl-2-butene, Pentene, 1,4-pentanediene and mixtures thereof. These resins may have a molecular weight ranging from 1000 to 2500 g / mol.

  Such resins of 1,3-pentanediene are sold, for example, under the references PICCOTAC 95 by the company Eastman Chemical, ESCOREZ 1304 by the company Exxon Chemicals, NEVTAC 100 by the company Neville Chem. or WINGTACK 95 by the company Goodyear; mixed pentanediene and indene resins, which result from the polymerization of a mixture of pentanediene and indene monomers such as those described above, for example the resins marketed under the reference ESCOREZ 2101 by the Exxon Chemicals., NEVPENE 9500 by Neville Chem., HERCOTAC 1148 by Hercules., Norsolene A 100 by Sartomer, WINGTACK 86, WINGTACK EXTRA and WINGTACK PLUS by Goodyear, - Diene dimer resins from cyclopentanediene such as those resulting from the polymerization of the first monomer chosen from indene and styrene, and the second monomer chosen from cyclopentanediene dimers such as dicyclopentanediene, methyldicyclopentanediene, the other dimers of pentanediene, and mixtures thereof. These resins generally have a molecular weight ranging from 500 to 800 g / mol, such as for example those sold under the reference BETAPRENE BR 100 by Arizona Chemical Co., NEVILLE LX-685-125 and NEVILLE LX-1000 by the company Neville Chem., PICCODIENE 2215 by Hercules, PETRO-REZ 200 by Lawter or RESINALL 760 by Resinall Corp. ; diene resins of dimers of isoprene, such as terpene resins resulting from the polymerization of at least one monomer chosen from α-pinene, 13-pinene and limonene, and mixtures thereof. These resins may have a molecular weight ranging from 300 to 2000 g / mol. Such resins are sold for example under the name PICCOLYTE A115 and S125 by the company Hercules, ZONAREZ 7100 or ZONATAC 105 LITE by the company ARIZONA Chem.

  Mention may also be made of certain modified resins such as hydrogenated resins, for example those sold under the name EASTOTAC C6-C20 POLYOLEFINE by the company Eastman Chemical Co., under the reference ESCOREZ 5300 by the company Exxon Chemicals, or the proposed NEVILLAC HARD or NEVROZ resins. by the company Neville Chem., the resins PICCOFYN A-100, PICCOTEX 100 or PICCOVAR AP25 proposed by the company Hercules or the resin SP-553 proposed by Schenectady Chemical Co.

  According to a preferred embodiment, the tackifying resin is chosen from indene hydrocarbon resins, in particular the hydrogenated indene / methylstyrene / styrene copolymers sold under the name REGALITE by Eastman Chemical, such as REGALITE R 1100, REGALITE R 1090, REGALITE R -7100, REGALITE R1010HYDROCARBON RESIN, REGALITE R1125 HYDROCARBON RESIN.

  The first resin may be present in the composition according to the invention in a content ranging from 0.1 to 30% by weight, relative to the total weight of the composition, preferably ranging from 0.3 to 20% by weight, more preferably ranging from 0.5 to 15% by weight.

  Liquid fatty phase The fatty phase of the composition according to the invention is in particular a liquid fatty phase based on at least one oil.

  In a preferred embodiment, the composition according to the invention comprises at least one volatile oil (also called solvent).

  The composition may also comprise at least one non-volatile oil. According to a preferred embodiment, the composition according to the invention is free of non-volatile oil.

  For the purposes of the invention, a volatile oil has a vapor pressure ranging from 0.02 mm to 300 mm of Hg Pa) and more preferably from 0.1 to 90 mm Hg (13 Pa to 12,000 Pa). The nonvolatile oils then correspond to a vapor pressure of less than 0.02 mmHg (2.66 Pa), and more preferably less than 10-3 mmHg (0.13 Pa).

  The oil may be a silicone oil, an ester oil or a non-silicone oil. at. Silicone oil According to a variant of the invention, the liquid fatty phase comprises at least one silicone oil. This can be a volatile oil or a non-volatile oil. The volatile silicone oil may be chosen from linear or cyclic silicone oils such as linear or cyclic polydimethylsiloxanes (PDMS) having from 3 to 7 silicon atoms. By way of example of such oils, mention may be made of octyltrimethicone, hexyltrimethicone, decamethylcyclopentasiloxane (cyclopentasiloxane or D5), octamethylcyclotetrasiloxane (cyclotetradimethylsiloxane or D4), dodecamethylcyclohexasiloxane (D6) and decamethyltetrasiloxane (L4). , KF 96 A from Shin Etsu, polydimethylsiloxanes such as those sold under the reference DC 200 (1.5 cSt), DC 200 (5 cSt), DC 200 (3 cSt) by Dow Corning.

  The non-volatile silicone oils may be polydimethylsiloxanes, polyalkylmethylsiloxanes, dimethicone copolyols, alkylmethicone copolyols, cetyldimethicone, silicones containing alkylglyceryl ether groups, silicones with side amines and dilauroyltrimethylolpropane siloxysilicate. The alkyl groups of these oils have in particular from 2 to 24 carbon atoms. The non-volatile silicone oils that may be used in the liquid fatty phase may in particular be non-volatile, linear polydimethylsiloxanes (PDMS) that are liquid at room temperature; polydimethylsiloxanes comprising alkyl, alkoxy or phenyl groups, pendant and / or at the end of the silicone chain, groups each having from 2 to 24 carbon atoms; fluoro silicones with group (s) during (s) or at the end of chain having 1 to 12 carbon atoms, all or part of the hydrogen atoms is substituted by fluorine atoms, dimethiconols and mixtures thereof.

  According to a preferred embodiment, the composition according to the invention comprises, as nonvolatile silicone oils, a phenyl silicone. By phenyl silicone is meant an organopolysiloxane substituted with at least one phenyl group.

  The phenyl silicone is preferably non-volatile. Preferably, the molecular weight of the phenyl silicone oil is between 500 and 10,000 g / mol.

  The silicone oil may be chosen from phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones and diphenyl methyldiphenyl trisiloxanes. The silicone oil may correspond to the formula: ## STR1 ## in which the groups R represent, independently of one another, a methyl or a phenyl. Preferably in this formula, the silicone oil comprises at least three phenyl groups, for example at least four, at least five or at least six.

  According to another embodiment, the silicone oil corresponds to the formula ## STR1 ## in which the groups R represent, independently of one another, a methyl or a phenyl. Preferably in this formula, said organopolysiloxane comprises at least three phenyl groups, for example at least four or at least five.

  Mixtures of the phenyl organopolysiloxanes described above can be used. Examples of these are, for example, mixtures of triphenylated, tetra- or pentaphenylated organopolysiloxane. According to another embodiment, the silicone oil corresponds to the formula Ph Ph Me Si Si Si Si Me Ph Me Ph in which Me represents methyl, Ph represents phenyl. Such phenyl silicone is especially manufactured by Dow Corning under the reference Dow Corning 555 Cosmetic Fluid (INCI name: trimethyl pentaphenyl trisiloxane). The reference Dow Corning 554 Cosmetic Fluid can also be used.

  The silicone oils have a viscosity preferably chosen in the range of from 5 to 800,000 cSt at 25 ° C, preferably from 10 to 500,000 cSt, and more preferably from 10 to 5,000 cSt. The liquid fatty phase preferably contains from 0.1 to 70%, for example from 5 to 60% by weight of silicone oil (s). b. Ester Oil According to one variant of the invention, at least one of the oils of the liquid fatty phase is an oil, called ester oil, which is chosen from esters of monocarboxylic acids with monoalcohols and polyalcohols.

  Advantageously, said ester has the following formula: RI-CO-O-R2 where RI represents a linear or branched alkyl radical of 1 to 40 carbon atoms, preferably 7 to 19 carbon atoms, optionally comprising one or more double ethylenic bonds, and optionally substituted.

  R2 represents a linear or branched alkyl radical of 1 to 40 carbon atoms, preferably of 3 to 30 carbon atoms and better still of 3 to 20 carbon atoms, optionally comprising one or more ethylenic double bonds, and optionally substituted. By optionally substituted is meant that R1 and R2 may carry one or more substituents selected, for example, from groups comprising one or more heteroatoms selected from O, N and S, such as amino, amine, alkoxy, hydroxyl. Preferably, the total number of carbon atoms of R1 + R2 is> 9. R1 may represent the remainder of a linear or preferably branched fatty acid comprising from 1 to 40 and better still from 7 to 19 carbon atoms and R2 may represent a linear or preferably branched hydrocarbon chain containing from 1 to 40, preferably from 3 to 30 and more preferably from 3 to 20 carbon atoms. Again, preferably, the number of carbon atoms of R1 + R2> 9. Examples of the R1 groups are those derived from fatty acids selected from the group consisting of acetic, propionic, butyric, caproic, caprylic, pelargonic, capric, undecanoic, lauric, myristic, palmitic, stearic, isostearic, arachidic, behenic, oleic, linolenic, linoleic, oleostearic, arachidonic, erucic, and mixtures thereof. Examples of esters which can be used in the fatty phases of the compositions of the invention are, for example, purcellin oil (cetostearyl octanoate), isononyl isononanoate, isopropyl myristate, ethyl palmitate. 2-hexyl, octyl 2-dodecyl stearate, octyl 2-dodecyl erucate, isostearyl isostearate, and heptanoates, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, for example fatty alcohols. Advantageously, the esters are chosen from the compounds of the above formula, in which R 1 represents an unsubstituted linear or branched alkyl group, optionally comprising one or more ethylenic double bonds, of 1 to 40 carbon atoms, preferably 7 to 19 carbon atoms, and R2 represents an unsubstituted linear or branched alkyl group, optionally comprising one or more ethylenic double bonds, of 1 to 40 carbon atoms, preferably of 3 to 30 carbon atoms, and more preferably of 3 to 20 carbon atoms. Preferably, R 1 is an unsubstituted branched alkyl group of 4 to 14 carbon atoms, preferably 8 to 10 carbon atoms, and R 2 is an unsubstituted branched alkyl group of 5 to 15 carbon atoms, preferably 9 to 15 carbon atoms. 11 carbon atoms. Preferably in the formula (I), R 1 -CO- and R 2 have the same number of carbon atoms and are derived from the same radical, preferably unsubstituted branched alkyl, for example isononyl, that is to say that advantageously the ester oil molecule is symmetrical. The ester oil will preferably be chosen from the following compounds: isononyl isononanoate, cetostearyl octanoate, isopropyl myristate, 2-ethylhexyl palmitate, stearate octyl 2-dodecyl, - octyl 2-dodecyl erucate, - isostearyl iso stearate. The most preferred ester is isononyl isononanoate. According to one embodiment, the composition comprises less than 10% volatile ester oil, preferably less than 5% volatile ester oil, better than less than 3% volatile ester oil, or even free of volatile ester oil. . Advantageously, the liquid fatty phase comprises from 0.1 to 60% by weight of the oil or ester oils, preferably from 5 to 50% by weight. vs. Non-silicone oil The liquid fatty phase of the compositions according to the invention may also contain one or more volatile or non-volatile non-silicone oils. The volatile non-silicone oils may be chosen from the group of hydrocarbon oils and esters and volatile ethers such as volatile hydrocarbons such as isododecane and isohexadecane, and C8-C16 isoparaffins. Preferably, the composition comprises at least one volatile oil, preferably a hydrocarbon oil, such as isododecane. By hydrocarbon oil is meant an oil containing mainly hydrogen and carbon atoms, and optionally oxygen, nitrogen, sulfur and / or phosphorus atoms. The volatile non-silicone oil may also be chosen from fluorinated oils such as perfluoropolyethers, perfluoroalkanes such as perfluorodecalin, perfluorodamantanes, monoesters, diesters and triesters of perfluoroalkylphosphates and fluorinated ester oils.

  By way of example of volatile non-silicone oils that can be used in the composition of the invention, mention may be made of isododecane, isohexadecane, propylene glycol n-butyl ether, ethyl 3-ethoxypropionate and acetate. propylene glycol methyl ether, C11-C13 isoparaffins such as Isopar L or C11-C12 isoparaffins such as Isopar H.

  The liquid fatty phase may also contain other non-silicone oils, for example polar oils such as: hydrocarbon vegetable oils with a high triglyceride content consisting of esters of fatty acids and of glycerol, the fatty acids of which may have various chain lengths, the latter being linear or branched, saturated or unsaturated; these oils include wheat germ, corn, sunflower, shea, castor oil, sweet almond, macadamia, apricot, soya, rapeseed, cotton, alfalfa, poppy, of pumpkin, sesame, squash, avocado, hazelnut, grape seed or black currant, evening primrose, millet, barley, quinoa, olive, rye, safflower, bancoulier passionflower, muscat rose; or the triglycerides of caprylic / capric acids, such as those sold by the company Stearines Dubois or those sold under the names Miglyol 810, 812 and 818 by the company Dynamit Nobel, synthetic ethers having from 10 to 40 carbon atoms, C 8 to C 26 fatty alcohols such as oleic alcohol or octyldodecanol, fatty acids such as oleic, linoleic or linolenic acid, and mixtures thereof.

  The liquid fatty phase may also contain apolar oils such as hydrocarbons or fluorocarbons, linear or branched, of synthetic or mineral origin, volatile or otherwise, such as paraffin oils (such as isoparaffins) and its derivatives, petroleum jelly, polydecenes, hydrogenated polyisobutene such as parleam, squalane, and mixtures thereof.

  The oil or oils (volatile or non-volatile) may be present in the composition according to the invention in a content ranging from 0.1% to 90% by weight, preferably from 5% to 80% by weight relative to the total weight. of the composition.

  When the fatty phase comprises a volatile oil, it advantageously represents from 0.1 to 60%, and more preferably from 0.5 to 40%, of the total weight of the composition.

  In general, the amount of volatile oil is used in sufficient quantity to improve the spreading and holding qualities of the composition. This quantity will be adapted by the skilled person depending on the intensity of the desired properties. Silicone resin

  The composition according to the invention contains at least one silicone resin (called second silicone resin). By way of example of these silicone resins, mention may be made of: siloxysilicates which may be trimethylsiloxysilicate of formula [(CH 3) 3 SiO] R (SiO 4 12) y (MQ units) in which x and y are integers ranging from 50 to 80, polysilesquioxanes of formula (CH3SiO312) .X (T units) in which x is greater than 100 and at least one of the methyl radicals may be substituted by a group R as defined above, polymethylsilsesquioxanes which are polysilsesquioxanes in which none of the methyl radicals is substituted by another group. Such polymethylsilsesquioxanes are described in US 5,246,694, the contents of which are incorporated by reference. By way of examples of commercially available polymethylsilsesquioxane resins, mention may be made of those sold: by the company Wacker under the reference Resin MK such as Belsil PMS MK: polymer comprising repeating units CH3SiO312 (T units), also Comprising up to 1% by weight of (CH 3) 2 SiO 2 12 units (D units) and having an average molecular weight of about 10,000, - by SHIN-ETSU under the references KR-220L which are composed of units T of formula CH 3 SiO 3 12 and have Si-OH end groups (silanol), under the reference KR-242A, which comprise 98% of T units and 2% of dimethyl D units and have terminal Si-OH groups or still under the reference KR-251 comprising 88% of T units and 12% of dimethyl D units and have Si-OH end groups. As siloxysilicate resins, there may be mentioned trimethylsiloxysilicate (TMS) resins optionally in the form of powders. Such resins are sold under the reference SR1000 by the company General Electric or under the reference TMS 803 by the company Wacker. Mention may also be made of timethylsiloxysilicate resins sold in a solvent such as cyclomethicone, sold under the name "KF-7312J" by the company Shin-Etsu, "DC 749", "DC 593" by the company Dow Corning.

  Advantageously, the silicone resin, such as trimethylsiloxysilicates resin for example, is present in a content ranging from 0.5 to 30% relative to the total weight of the composition, or better still from 1 to 25% or even better, from at 25%.

  Preferably, the silicone resin, and in particular the trimethylsiloxysilicate resin, is present in a ratio such that the proportion by weight of silicone polyamide / silicone resin is between 1/4 and 4, and preferably between 1/3 and 3.

  Non-transfer: The first composition and / or the second composition can also be chosen so that the product, once applied to the keratin materials, has satisfactory non-transfer properties.

  In particular, the first composition preferably has a transfer index of less than 35, preferably less than or equal to 30, preferably less than or equal to 20, preferably less than or equal to 15, preferably less than or equal to 10, preferably , less than or equal to 5, and more preferably less than or equal to 2 in 100.

  The second composition may be chosen such that the transfer index of the product of the invention is less than or equal to 35, preferably less than or equal to 30, preferably less than or equal to 20, preferably less than or equal to 15, preferably less than or equal to 10, preferably less than or equal to 5. The transfer index can be measured according to the following method. Preheating a support (rectangle 40 mm × 70 mm and 3 mm thick) of adhesive polyethylene foam on one of the faces having a density of 33 kg / m3 (sold under the name RE40X70EP3 of the company JOINT TECHNIQUE LYONNAIS IND) on a heating plate maintained at the temperature of 40 C so that the surface of the support is maintained at a temperature of 33 C 1 C.

  While leaving the support on the heating plate, the composition is applied to the entire non-adhesive surface of the support by spreading it with the aid of a brush to obtain a deposit of the composition of about 15 gm and then allowed to dry. during 30 minutes.

  After drying, the support is adhered by its adhesive side on an anvil with a diameter of 20 mm and provided with a screw thread. The support / deposit assembly is then cut using a punch with a diameter of 18 mm. The anvil is then screwed onto a press (MANUAL STATIF IMADA SV-2 from SOMECO) equipped with a dynamometer (IMADA DPS-20 from SOMECO).

  A white photocopy paper of 80 g / m2 is placed on the base of the press and the support / deposit assembly is pressed on the paper at a pressure of 2.5 kg for 30 seconds. After removal of the carrier / deposit assembly, a portion of the deposit was transferred to the paper. The color of the transferred deposit is then measured on the paper using a MINOLTA CR300 colorimeter, the color being characterized by the colorimetric parameters L *, a *, b *. The colorimetric parameters L * 0, a * 0, b * 0 of the color of the bare paper used are determined.

  The color difference AE1 is then determined between the color of the transferred deposit with respect to the color of the bare paper by the following relation. AE1 = (L * _Lo *) 2 + (a * - ao *) 2 + (b * - bo *) 2 Moreover, a total transfer reference is prepared by applying the composition directly to a paper identical to that used previously at room temperature (25 ° C.), spreading the composition with the aid of a brush and to obtain a deposit of the composition of approximately 15 μm and then allowed to dry for 30 minutes at room temperature (25 ° C.) . After drying, the colorimetric parameters L * ', a *', b * 'of the color of the deposit placed on the paper, corresponding to the total transfer reference color, are measured directly. The colorimetric parameters L * '0, a *' 0, b * '0 of the color of the bare paper used are determined. The color difference AE2 between the total transfer reference color and the color of the bare paper is then determined by the following relationship. AE2 = (L * 'L0 * 2 + (a *' - a0 * 2 + (b * '- b012 The transfer of the composition, expressed as a percentage, is equal to the ratio: 100 X AE1 / AE2

  The measurement is carried out on 4 supports in succession and the transfer value corresponds to the average of the 4 measurements obtained with the 4 supports.

  The first composition and / or the second composition may also be chosen so that the product, once applied to the keratin materials, has satisfactory holding properties.

  In particular, the first composition preferably has a resistance index greater than or equal to 80%, preferably greater than or equal to 85%, preferably less than or equal to 90%, preferably greater than or equal to 95%. The second composition may be chosen such that the strength of the product is greater than or equal to 80%, preferably greater than or equal to 85%, preferably less than or equal to 90%, preferably greater than or equal to 95%. %.

  The resistance index of the deposit obtained with the composition according to the invention is determined according to the measurement protocol described below.

  A support (rectangle 40 mm × 70 mm) made of an acrylic coating (hypoallergenic acrylic adhesive on a polyethylene film sold under the name BLENDERME ref FHSO00-55113 by the company 3M Santé) is prepared on a layer of adhesive polyethylene foam. on the opposite side to that on which is fixed the plaster (layer of foam sold under the name RE40X70EP3 of the company JOINT TECHNIQUE LYONNAIS IND).

  The color L * 0a * 0b * 0 of the support is measured using a MINOLTA CR 300 colorimeter, on the acrylic coating side.

  The support thus prepared is preheated on a heating plate maintained at a temperature of 40 ° C. so that the surface of the support is maintained at a temperature of 20 ° C.

  While leaving the support on the hot plate, the composition is applied to the entire non-adhesive surface of the support (i.e., on the surface of the acrylic coating) by spreading it with a brush to obtain a deposit of the composition of about 15 gm 25 and then allowed to dry for 10 minutes.

  After drying, the color L * a * b * of the film thus obtained is measured.

  The color difference AE1 is then determined between the color of the film with respect to the color of the bare substrate by the following relationship.

  AE1 = (L * _LO *) 2 + (a * - ao *) 2 + (b * - bo *) 2 The support is then glued by its adhesive side (adhesive side of the foam layer) on an anvil of a diameter of 20 mm and provided with a screw thread. A test piece of the support / deposit assembly is then cut using a punch with a diameter of 18 mm. The anvil is then screwed onto a press (MANUAL STATIF IMADA SV-2 from SOMECO) equipped with a dynamometer (IMADA DPS-20 from SOMECO).

  On a 80 g / m2 white photocopy paper, draw a strip 33 mm wide and 29.7 cm long, draw a first line 2 cm from the edge of the sheet, then a second line at 5 cm the edge of the sheet, the first and second lines thus delimiting a box on the strip; then we have a first mark and a second mark located in the band at 8 cm and 16 cm markings respectively. 20 pl of water are placed on the first mark and on the second mark 10 pl of refined sunflower oil (sold by the company LESIEUR).

  The white paper is placed on the base of the press and the specimen placed on the square of the paper strip is pressed at a pressure of approximately 300 g / cm 2 exerted for 30 seconds. Then the press is raised and the test piece is placed again just after the second line (hence beside the box), a pressure of approximately 300 g / cm 2 is again made and is moved rectilinearly on contact. The paper was made at a speed of 1 cm / sec. along the length of the web so that the specimen passed through the water and oil deposits.

  After removal of the specimen, a portion of the deposit was transferred to the paper. The color L * ', a *', b * 'of the deposit remained on the specimen.

  The color difference AE 2 is then determined between the color of the deposit remaining on the specimen relative to the color of the bare support by the following relation.

  AE2 = (L * '_ L0 * `2 + (a *' - a0 *) 2 + (b * '- b0 *` 2 The strength index of the composition, expressed as a percentage, is equal to the ratio: 5 100 X AE2 / AE1

  The measurement is carried out on 6 supports in succession and the transfer value corresponds to the average of the 6 measurements obtained with the 6 supports. The first composition may contain, in addition to the silicone polyamide and the tackifying resin, at least one oil, another silicone polymer, a surfactant, a coloring agent, a filler, an active agent and a mixture thereof.

  Active ingredients The composition according to the invention may further comprise at least one active ingredient. By active is meant a compound having a cosmetic and / or dermatological effect on the lips. This active agent may be hydrophilic or hydrophobic. The asset can be water soluble. Thus, the active agent present in the composition according to the invention may be independently chosen from: - skin-relaxing agents, - agents stimulating the synthesis of dermal or epidermal macromolecules and / or preventing their degradation, - anti-glycation agents, Anti-irritant agents, moisturizing agents, desquamating agents, pigmentation modifying agents, NO-synthase inhibitors, agents stimulating proliferation of fibroblasts or keratinocytes and / or differentiation of keratinocytes, anti-pollution or anti-radical agents, soothing agents, agents acting on microcirculation, agents acting on the energetic metabolism of cells, healing agents, and their mixtures.

  The amount of active agent (s) is, for example, from 0.0001% to 30% by weight and preferably from 0.01% to 20% by weight of active material relative to the total weight of the composition.

  Physiologically Acceptable Medium The composition of the invention must be cosmetically or dermatologically acceptable, namely to contain a physiologically acceptable medium which is non-toxic and may be applied to the lips of human beings. By cosmetically acceptable is meant in the sense of the invention a composition of appearance, smell and pleasant touch.

  Structuring agent The composition according to the invention may comprise, in addition to the silicone polyamide (s) described above, a structuring agent chosen from waxes, semi-crystalline polymers, lipophilic gelling agents and mixtures thereof.

  It is understood that the amount of these additional compounds can be adjusted by those skilled in the art so as not to damage the desired effect in the context of the present invention.

  Wax (es) The wax considered in the context of the present invention is generally a lipophilic compound, solid at room temperature (25 C), with a reversible solid / liquid state change, having a higher melting point or equal to 30 C up to 200 C and in particular up to 120 C. In particular, the waxes suitable for the invention may have a melting point greater than or equal to 45 C, and in particular greater than or equal to 55 vs.

  For the purposes of the invention, the melting temperature corresponds to the temperature of the most endothermic peak observed in thermal analysis (DSC) as described in ISO 11357-3; 1999. The melting point of the wax can be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name MDSC 2920 by the company TA Instruments.

  The measurement protocol is as follows: A sample of 5 mg of wax placed in a crucible is subjected to a first rise in temperature from -20 ° C to 100 ° C, at a heating rate of 10 ° C / minute, then is cooled by 100 C at -20 C at a cooling rate of 10 C / minute and finally subjected to a second temperature rise from -20 C to 100 C at a heating rate of 5 C / minute. During the second temperature rise, the variation of the power difference absorbed by the empty crucible and the crucible containing the wax sample as a function of temperature is measured. The melting point of the compound is the value of the temperature corresponding to the peak apex of the curve representing the variation of the difference in power absorbed as a function of the temperature. The waxes that may be used in the compositions according to the invention are chosen from waxes, solid, at room temperature of animal, vegetable, mineral or synthetic origin, and mixtures thereof. Illustrative waxes suitable for the invention include hydrocarbon waxes such as beeswax, lanolin wax, and Chinese insect wax, rice bran wax, Carnauba wax , Candelllila wax, Ouricury wax, Alfa wax, berry wax, shellac wax, Japanese wax and sumac wax; montan wax, orange and lemon waxes, microcrystalline waxes, paraffins and ozokerite; polyethylene waxes, waxes obtained by Fisher-Tropsch synthesis and waxy copolymers and their esters. There may also be mentioned waxes obtained by catalytic hydrogenation of animal or vegetable oils having linear or branched C8-C32 fatty chains. Among these, there may be mentioned isomerized jojoba oil such as trans isomerized partially hydrogenated jojoba oil manufactured or marketed by DESERT WHALE under the trade reference Iso-Jojoba-50, hydrogenated sunflower oil , hydrogenated castor oil, hydrogenated coconut oil, hydrogenated lanolin oil, and di- (1,1,1-trimethylolpropane) tetrastearate sold under the name Hest 2T-4S by the company HETERENE. Mention may also be made of silicone waxes (C30-45 ALKYL DIMETHICONE) and fluorinated waxes. It is also possible to use the waxes obtained by hydrogenation of castor oil esterified with cetyl alcohol sold under the names Phytowax Ricin 16L64 and 22L73 by the company SOPHIM. Such waxes are described in the application FR-A-2792190. As wax, a C20-C40 alkyl (hydroxystearyloxy) stearate (the alkyl group comprising from 20 to 40 carbon atoms) can be used, alone or as a mixture .

  Such a wax is in particular sold under the names Kester Wax K 82 P, Hydroxypolyester K 82 P and Kester Wax K 80 P by the company Koster Keunen. As micro-waxes that can be used in the compositions according to the invention, mention may be made in particular of carnauba micro-waxes, such as that marketed under the name MicroCare 350 by the company Micro Powders, and synthetic wax micro-waxes such as that marketed under the name MicroEase 114S by the company MICRO POWDERS, the micro waxes consisting of a mixture of carnauba wax and polyethylene wax such as those sold under the names Micro Care 300 and 310 by the company MICRO POWDERS, micro waxes consisting of a mixture of carnauba wax and synthetic wax such as that sold under the name Micro Care 325 by the company Micro Powders, the polyethylene micro-waxes such as those sold under the names Micropoly 200, 220, 220L and 250S by the company MICRO POWDERS and micro-waxes of polytetrafluoroethylene such those marketed under the names Microslip 519 and 519 L by the company MICRO POWDERS.

  The composition according to the invention may comprise a wax content ranging from 0.1 to 30% by weight relative to the total weight of the composition, in particular it may contain from 0.5 to 15%, more particularly from 1 to 10%. According to another embodiment, the composition according to the invention is free of wax.

  Paste Compounds The composition according to the invention may further comprise a pasty compound which may advantageously be chosen from: lanolin and its derivatives - polymeric or non-polymeric silicone compounds - fluorinated or non-polymeric fluorinated compounds - vinyl polymers, in particular: homopolymers of olefins • copolymers of olefins • homopolymers and copolymers of hydrogenated dienes • linear or branched oligomers, homo or copolymers of alkyl (meth) acrylates preferably having a C8-C30 alkyl group • oligomers homo and copolymers of vinyl esters having C 8 -C 30 alkyl groups; homo and copolymer oligomers of vinyl ethers having C 8 -C 30 alkyl groups; liposoluble polyethers resulting from polyetherification between one or more C2-C100 diols preferably C 2 -C 50, esters, and mixtures thereof. Among the esters, the following are particularly preferred: esters of an oligomeric glycerol, in particular the diglycerol esters, in particular the adipic acid and glycerol condensates, for which part of the hydroxyl groups of the glycerols have reacted with a mixture fatty acids such as stearic acid, capric acid, stearic acid and isostearic acid and 12-hydroxystearic acid, such as those marketed under the tradename Softisan 649 by Sasol, - arachidyl propionate sold under the trade name Waxenol 801 by Alzo, - phytosterol esters, - triglycerides of fatty acids and their derivatives, - pentaerythritol esters, - non-crosslinked polyesters resulting from the polycondensation between a linear or branched C 4 -C 50 dicarboxylic acid or polycarboxylic acid and a C2-050 diol or polyol; - the ester aliphatic esters resulting from the esterification of an acid ester aliphatic hydroxycarboxylic acid with an aliphatic carboxylic acid, - the polyesters resulting from the esterification, by a polycarboxylic acid, of an aliphatic hydroxy carboxylic acid ester, said ester comprising at least two hydroxyl groups such as the products Risocast DA-H, and Risocast DA-L, and mixtures thereof. Among the pasty compounds of plant origin, a mixture of soy sterols and oxyethylenated (5OE) oxypropylene pentaerythritol (5 PO), marketed under the reference Lanolide by the company VEVY, will preferably be chosen.

  According to one embodiment, the composition comprises less than 10% by weight, preferably less than 7%, better less than 5%, and even more preferably less than 3% by weight of pasty fatty substance relative to the total weight of the composition. . More preferably, the composition is completely free of pasty fatty substances.

  Lipophilic Gelling Agents The gelling agents that may be used in the compositions according to the invention may be organic or inorganic, polymeric or molecular lipophilic gelling agents. As inorganic lipophilic gelling agents, there may be mentioned optionally modified clays, such as hectorites modified with a C 10 -C 22 ammonium chloride, such as hectorite modified with di-stearyl dimethyl ammonium chloride such as, for example, sold under the name Bentone 38V by the company ELEMENTIS.

  It is also possible to mention fumed silica optionally treated hydrophobic surface whose particle size is less than 1 m. It is indeed possible to chemically modify the surface of the silica, by chemical reaction generating a decrease in the number of silanol groups present on the surface of the silica. In particular, it is possible to substitute silanol groups with hydrophobic groups: a hydrophobic silica is then obtained. The hydrophobic groups may be: trimethylsiloxyl groups, which are especially obtained by treatment of fumed silica in the presence of hexamethyldisilazane. Silicas thus treated are called silica silylate according to the CTFA (8th edition, 2000). They are for example sold under the references Aerosil R812 by the company Degussa, CAB-O-SIL TS-530 by the company CABOT, dimethylsilyloxyl or polydimethylsiloxane groups, which are obtained in particular by treatment of fumed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas thus treated are known as silica dimethyl silylate according to the CTFA (8th edition, 2000). They are for example marketed under the Aerosil R972 references, and Aerosil R974 by the DEGUSSA company, CAB-O-SIL TS-610 and CAB-O-SIL TS-720 by CABOT. The hydrophobic fumed silica has in particular a particle size that can be nanometric to micrometric, for example ranging from about 5 to 200 nm.

  Polymeric organic lipophilic gelling agents are, for example, partially or fully crosslinked elastomeric organopolysiloxanes of three-dimensional structure, such as those sold under the names KSG6, KSG16 and KSG18 by the company Shin-Etsu, Trefil E-505C and Trefil E-506C. by DOW-CORNING, Gransil SR-CYC, SR DMF10, SR-DC556, SR SCYC gel, SR DMF 10 gel and SR DC 556 gel by GRANT INDUSTRIES, SF 1204 and JK 113 by the company GENERAL ELECTRIC; ethylcellulose such as that sold under the name Ethocel by Dow Chemical; galactomannans having from one to six, and in particular from two to four, hydroxyl groups per sac, substituted by a saturated or unsaturated alkyl chain, such as guar gum alkylated by C1-C6 alkyl chains, and in particular C1 C3 and mixtures thereof. Block copolymers of the diblock, triblock or radial type of the polystyrene / polyisoprene, polystyrene / polybutadiene type, such as those sold under the name Luvitol HSB by the company BASF, of the polystyrene / copoly (ethylene-propylene) type, such as those sold under the name Kraton by the company Shell Chemical Co., or else of the polystyrene / copoly (ethylene-butylene) type, mixtures of triblock and radial (star) copolymers in isododecane, such as those sold by PENRECO under the name Versagel as per for example the mixture of butylene triblock copolymer / ethylene / styrene and star copolymer ethylene / propylene / styrene in isododecane (Versagel M 5960). Among the lipophilic gelling agents that can be used in the compositions according to the invention, mention may also be made of dextrin and fatty acid esters, such as dextrin palmitates, in particular such as those sold under the names Rheopearl TL or Rheopearl KL by the company CHIBA FLOUR.

  Aqueous Phase According to a first embodiment of the invention, the composition according to the invention may comprise an aqueous medium, constituting an aqueous phase, which can form the dispersed phase of the composition. The aqueous phase may consist essentially of water; it may also comprise a mixture of water and of a water-miscible solvent (miscibility in water greater than 50% by weight at 25 ° C.), such as lower monoalcohols having from 1 to 5 carbon atoms such as ethanol isopropanol, glycols having 2 to 8 carbon atoms such as propylene glycol, ethylene glycol, 1,3-butylene glycol, dipropylene glycol, C3-C4 ketones, C2-aldehydes; C4 and mixtures thereof. The aqueous phase (water and optionally the water-miscible solvent) may be present in a content ranging from 1% to 95% by weight relative to the total weight of the composition, preferably ranging from 2% to 80% by weight, and preferably ranging from 3% to 60% by weight. The composition according to the invention may also contain less than 10% by weight or even less than 4% by weight of aqueous phase or water.

  According to a second embodiment, the composition is anhydrous, that is to say that it comprises less than 10% water by weight or better still less than 4%, relative to the total weight of the composition, or it is totally anhydrous.

  Dyestuffs According to one embodiment, the composition according to the invention may further contain at least one coloring agent which may be chosen from water-soluble or liposoluble dyes, pigments, pearlescent agents and mixtures thereof. The composition according to the invention may further comprise one or more dyestuffs chosen from water-soluble dyes and pulverulent dyestuffs such as pigments, nacres and flakes well known to those skilled in the art.

  The dyestuffs may be present in the composition in a content ranging from 0.01% to 50% by weight, relative to the weight of the composition, preferably from 0.01% to 30% by weight.

  The term "pigments" is intended to mean white or colored particles, mineral or organic, insoluble in an aqueous solution, intended to color and / or opacify the resulting film. The pigments may be present in a proportion of from 0.01 to 20% by weight, especially from 0.01 to 15% by weight, and in particular from 0.02 to 10% by weight, relative to the total weight of the cosmetic composition. .

  As inorganic pigments that can be used in the invention, mention may be made of titanium oxide, zirconium oxide or cerium oxide, as well as zinc, iron or chromium oxides, ferric blue, manganese violet, ultramarine blue and the like. chromium hydrate. It may also be a pigment having a structure which may for example be sericite / brown iron oxide / titanium dioxide / silica. Such a pigment is marketed for example under the reference COVERLEAF NS or JS by CHEMICALS AND CATALYSTS and has a contrast ratio of about 30. The dyestuff may also comprise a pigment having a structure which may be for example microspheres type. silica containing iron oxide. An example of a pigment having this structure is that marketed by MIYOSHI under the reference PC BALL PC-LL-100P, this pigment consisting of silica microspheres containing yellow iron oxide.

  Among the organic pigments that can be used in the invention, mention may be made of carbon black, D & C type pigments, cochineal carmine, barium, strontium, calcium, aluminum or diketo pyrrolopyrrole (DPP) lacquers. ) described in EP-A-542669, EP-A-787730, EP-A-787731 and WO-A-96/08537.

  By nacres, it is necessary to understand colored particles of any shape, iridescent or not, in particular produced by certain shellfish in their shell or else synthesized and which exhibit a color effect by optical interference. The nacres can be chosen from pearlescent pigments such as titanium mica coated with an iron oxide, titanium mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with a dye. organic and pearlescent pigments based on bismuth oxychloride. It may also be mica particles on the surface of which are superimposed at least two successive layers of metal oxides and / or organic dyestuffs.

  Mention may also be made, by way of example of nacres, of natural mica coated with titanium oxide, with iron oxide, with natural pigment or with bismuth oxychloride. Among the nacres available on the market, mention may be made of mother-of-pearl TIMICA, FLAMENCO and DUOCHROME (based on mica) marketed by ENGELHARD, TIMIRON pearls marketed by MERCK, mother-of-pearl containing PRESTIGE mica marketed by the company. ECKART and nacres based on SUNSHINE synthetic mica sold by the company SUN CHEMICAL. The nacres may more particularly have a color or a yellow, pink, red, bronze, orange, brown, gold and / or coppery reflection. As an illustration of nacres that can be used in the context of the present invention, mention may be made especially of gold-colored nacres sold especially by ENGELHARD under the name Brillant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne); bronze nacres sold especially by the company Merck under the name Bronze Fine (17384) (Colorona) and Bronze (17353) (Colorona) and by Engelhard under the name Super Bronze (Cloisonne); orange nacres sold especially by the company Engelhard under the name Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and by the company Merck under the name Passion Orange (Colorona) and Matte Orange (17449) (Microna); brown-colored pearlescent agents marketed by Engelhard under the name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite); nacres with a copper sheen sold especially by Engelhard under the name Copper 340A (Timica); the nacres with a red glint sold especially by MERCK under the name Sienna fine (17386) (Colorona); yellow-colored pearlescent agents marketed by ENGELHARD under the name Yellow (4502) (Chromalite); the red-colored pearlescent agents with a gold glint sold especially by ENGELHARD under the name Sunstone G012 (Gemtone); pink nacres sold especially by Engelhard under the name Tan opal G005 (Gemtone); the black nacres with gold reflection sold by the company Engelhard under the name Nu antique bronze 240 AB (Timica), the blue nacres sold especially by the company Merck under the name Matte Blue (17433) (Microna), the white nacres with reflection silver sold in particular by the company Merck under the name Xirona Silver and the golden-green orange-colored mother-of-pearl marketed by Merck under the name Indian summer (Xirona) and their mixtures.

  By dyes, it is necessary to understand generally organic compounds soluble in fatty substances such as oils or in a hydroalcoholic phase. The cosmetic composition according to the invention may also comprise water-soluble or fat-soluble dyes. Liposoluble dyes are for example Sudan Red, DC Red 17, DC Green 6, 13-carotene, Sudan Brown, DC Yellow 11, DC Violet 2, DC Orange 5, yellow quinoline. The water-soluble dyes are, for example, beet juice, methylene blue.

  The cosmetic composition according to the invention may also contain at least one material with a specific optical effect.

  This effect is different from a simple effect of conventional hue, that is to say unified and stabilized as produced by conventional dyestuffs such as monochromatic pigments. In the sense of the invention, stabilized means devoid of color variability effect with the angle of observation or in response to a change in temperature. For example, this material may be chosen from particles with a metallic sheen, goniochromatic coloring agents, diffractive pigments, thermochromic agents, optical brighteners, as well as fibers, in particular interferential fibers. Of course, these different materials can be combined to provide the simultaneous manifestation of two effects, or even a new effect according to the invention. The particles with a metallic sheen that can be used in the invention are in particular chosen from: particles of at least one metal and / or at least one metal derivative; particles comprising a substrate, organic or inorganic, monomatiere or multimaterial at least partially covered by at least one metal-reflecting layer comprising at least one metal and / or at least one metal derivative, and the mixtures of said particles. Among the metals that may be present in said particles, mention may be made, for example, of Ag, Au, Cu, Al, Ni, Sn, Mg, Cr, Mo, Ti, Zr, Pt, Va, Rb, W, Zn, Ge, Te. Se and their mixtures or alloys. Ag, Au, Cu, Al, Zn, Ni, Mo, Cr, and mixtures or alloys thereof (eg, bronzes and brasses) are preferred metals.

  The term "metal derivatives" denotes compounds derived from metals, in particular oxides, fluorides, chlorides and sulphides. As an illustration of these particles, mention may be made of aluminum particles, such as those sold under the names STARBRITE 1200 EAC by the company SIBERLINE and METALURE by the company ECKART.

  Mention may also be made of copper metal powders or alloy mixtures such as the references 2844 sold by the company Radium Bronze, metallic pigments such as aluminum or bronze, such as those sold under the names ROTOSAFE 700 from the company ECKART the silica-coated aluminum particles marketed under the name VISIONAIRE BRIGHT SILVER by ECKART and the metal alloy particles such as bronze powders (copper and zinc alloy) coated with silica marketed under the name of Visionaire Bright Natural Gold from Eckart. It may also be particles comprising a glass substrate such as those marketed by the company NIPPON SHEET GLASS under the names MICROGLASS METASHINE. The goniochromatic coloring agent may be chosen for example from interferential multilayer structures and liquid crystal coloring agents. Examples of symmetrical interferential multilayer structures that can be used in compositions produced in accordance with the invention are, for example, the following structures: Al / SiO 2 / Al / SiO 2 / Al, pigments having this structure being marketed by the company DUPONT DE NEMOURS; Cr / MgF 2 / Al / MgF 2 / Cr, pigments having this structure being marketed under the name CHROMAFLAIR by the company FLEX; MoS2 / SiO2 / Al / SiO2 / MoS2; Fe2O3 / SiO2 / Al / SiO2 / Fe2O3, and Fe2O3 / SiO2 / Fe2O3 / SiO2 / Fe2O3, pigments having these structures being marketed under the name SICOPEARL by BASF; MoS2 / SiO2 / mica-oxide / SiO2 / MoS2, Fe2O3 / SiO2 / mica-oxide / SiO2 / Fe2O3; TiO2 / SiO2 / TiO2 and TiO2 / Al2O3 / TiO2; SnO / TiO2 / SiO2 / TiO2 / SnO; Fe2O3 / SiO2 / Fe2O3; SnO / mica / TiO 2 / SiO 2 / TiO 2 / mica / SnO, pigments having these structures being sold under the name XIRONA by the company Merck (Darmstadt). By way of example, these pigments may be the pigments of silica / titania / tin oxide structure marketed under the trademark Xirona Magic by the company Merck, the silica / brown iron oxide structural pigments marketed under the name XIRONA INDIAN SUMMER by the company MERCK and silica structural pigments / titanium oxide / mica / tin oxide marketed under the name XIRONA 25 CARRIBEAN BLUE by MERCK. Mention may also be made of the INFINITE COLORS pigments from SHISEIDO. Depending on the thickness and nature of the different layers, different effects are obtained. Thus, with the Fe 2 O 3 / SiO 2 / Al / SiO 2 / Fe 2 O 3 structure, grey-green to gray-red is passed for SiO 2 layers of 320 to 350 nm; from red to golden for layers of SiO2 from 380 to 400 nm; from purple to green for 410 SiO2 layers at 420 nm; from copper to red for SiO2 layers from 430 to 440 nm.

  Mention may be made, by way of example of pigments with a polymeric multilayer structure, those marketed by the company 3M under the name COLOR GLITTER. As liquid crystal goniochromatic particles, it is possible to use, for example, those sold by the company CHENIX as well as those marketed under the name HELICONE HC by the company WACKER.

  Filler The composition according to the invention may comprise at least one filler, in particular in a content ranging from 0.01% to 50% by weight, relative to the total weight of the composition, preferably ranging from 0.01% to 30% by weight. % in weight. By fillers, it is necessary to include particles of any form, colorless or white, mineral or synthetic, insoluble in the medium of the composition regardless of the temperature at which the composition is manufactured. These fillers serve in particular to modify the rheology or the texture of the composition. The fillers can be mineral or organic of any shape, platelet, spherical or oblong, irrespective of the crystallographic form (for example sheet, cubic, hexagonal, orthorhombic, etc.). Mention may be made of talc, mica, silica, kaolin, polyamide (nylon) powders (Orgasol from Atochem), poly-B-alanine and polyethylene, tetrafluoroethylene polymer powders (Teflon), lauroyllysine, starch, boron nitride, polymeric hollow microspheres such as polyvinylidene chloride / acrylonitrile such as Expancel (Nobel Industrie), copolymers of acrylic acid (Polytrap Dow Corning) and the silicone resin microbeads (Toshiba Tospearls, for example), elastomeric polyorganosiloxane particles, precipitated calcium carbonate, magnesium carbonate and hydrocarbonate, hydroxyapatite, hollow silica microspheres (Silica Beads) of Maprecos), glass or ceramic microcapsules, metal soaps derived from organic carboxylic acids containing from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, for example zinc stearate, magnesium or lithium, zinc laurate, magnesium myristate.

  Additional Usual Cosmetic Ingredients The composition according to the invention may furthermore comprise any usual cosmetic ingredient that may be chosen especially from antioxidants, perfumes, preservatives, neutralizers, surfactants, sunscreens, vitamins, moisturizers, compounds self-tanning agents, anti-wrinkle active agents, emollients, hydrophilic or lipophilic active agents, anti-free radical agents, deodorant agents, sequestering agents, film-forming agents, and mixtures thereof. Of course, those skilled in the art will take care to choose any additional ingredients and / or their quantity so that the advantageous properties of the composition according to the invention are not or substantially not impaired by the addition envisaged.

  The product according to the invention can be advantageously used for the makeup of the skin and / or lips and / or integuments according to the nature of the ingredients used. In particular, the product of the invention can be in the form of a solid foundation, stick or paste of lipstick, concealer, or eye contours, eye liner, mascara, eyeshadow, body make-up product or a skin coloring product. The compositions of the product of the invention can be obtained by heating the various constituents to a temperature corresponding to the melting temperature of the highest ingredient or ingredients, and then pouring the molten mixture into a mold (cup or thimble). They can also be obtained by extrusion as described in application EP-A-0 667 146. In particular, the composition of the invention can be in the form of a colored lipstick makeup product such as a lipstick, lips or pencil, possibly with care or treatment properties. It can be in the form of an anhydrous stick. The composition according to the invention can be manufactured by known methods, generally used in the cosmetic or dermatological field. For example, it can be manufactured by the following method.

  Firstly, the fillers and the pigments can be milled in part of the oily phase.

  The remaining liposoluble ingredients can then be mixed at a temperature of the order of 100 C. The ground material or the pre-dispersed active agents can then be added to the oily phase. Any hydrophilic active agents can then be dispersed using a mechanical stirrer. Finally, the composition may be cast in a mold capable of providing the final shape (for example stick) and the whole can be left to cool to room temperature.

  According to another aspect, the invention also relates to a cosmetic assembly comprising: i) a container delimiting a compartment, said container being closed by a closure element; and ii) a composition according to the invention disposed within said compartment. The container can be in any suitable form. It may especially be in the form of a bottle, a tube, a pot, a case, a box, a bag or a case. The closure element may be in the form of a removable cap, a lid, a lid, a tearable strip, or a capsule, in particular of the type comprising a body fixed to the container and a cap. articulated on the body. It may also be in the form of an element ensuring the selective closure of the container, in particular a pump, a valve, such as a valve for example.

  According to an advantageous embodiment it is possible to provide a second composition, which may especially be intended to be applied over the first composition. The invention thus also relates to a cosmetic makeup or care product comprising a first composition as defined above, and a second composition comprising at least one liquid fatty phase. Preferably, said fatty phase of said second composition comprises at least one phenyl silicone oil.

  The invention also relates to a makeup process and to a make-up kit containing said product, the first and second compositions being able to be packaged in separate containers or in separate compartments of the same container, and are advantageously accompanied appropriate means of application. These means may be brushes, brushes, pens, pencils, felts, feathers, sponges, tubes and / or foam tips ... The product according to the invention is in particular a lipstick, a mascara or nail polish. The following examples are given by way of non-limiting illustration of the present invention. Percentages are percentages by weight.

  Examples 1 and 2 of lipsticks

  Compositions 1 and 2 are obtained according to the following protocol.

  Firstly, the fillers and the pigments are ground in part of the oily phase. The remainder of the fat-soluble ingredients are then mixed at a temperature of the order of 100 ° C. The mash or pre-dispersed active ingredients are then added to the oily phase.

  Finally, the composition is poured into a mold for obtaining sticks 8 mm in diameter and the whole is allowed to cool in a freezer for about an hour. Compound (INCI name US) Example 1 Example 2 (Comparative) (Invention) A ISO-DODECANE QSP 100 QSP 100 RESIN TRIMETHYL SILOXYSILICATE 14.04 14.04 ----------------- -------------------------- NYLON- 611 / DIMETHICONE 19.49 19.49 COPOLYMER (= polyamide / polydimethyl siloxane DC 2-8179 from Dow Corning) AMORPHOUS SILICA MICRO-SPHERES 2.00 2.00 (GRANULOMETRY: 5 MICRONS) N-LAUROYL L-LYSINE 1.00 1.00 COPOLYMER STYRENE / METHYL-1.00 STYRENE / HYDROGEN INDENE (REGALITE R 1100) C HOMOPOLYMER OF ETHYLENE 11.40 11.40 --------------------------------------- ---- FATTY ALCOHOL MIX WITH LONG 1.71 1.71 LINEAR CHAIN (C30-050) AND HYDROCARBON WITH THE SAME NUMBER OF CARBON (80/20) TITANIUM OXIDE RUTILE TREATED 2.74 2.74 ALUMINA / SILICA / TRI-METHYOLPROPANE (CI: 77891) LITHOL RED CALCIUM SALT 0.54 0.54 B BLUE ALUMINUM LIGHT 0.16 0.16 BRILLIANT FCF ON ALUMINA (12/88) 2.57 2 , 57 (CI: 42090: 2 + 77002) 0.25 0.25 BRILLIANT YELLOW ALUMINUM GLASS FCF ON ALUMINA (42/58) (CI: 15985: 1 + 7700 2) BLACK IRON OXIDE (CI: 77499) ISO-DODECANE 5,12 5,12 SMECTITE: MAGNESIUM SILICATE 10,00 10,00 MODIFIED IN ISODODECANE RESIN TRIMETHYL SILOXYSILICATE 3.20 3.20 E MICA-DIOXIDE OF TITANIUM- OXIDE 2.00 2.00 OF BROWN IRON (77/21/4) (SIZE: 16-128 2.00 2.00 MICRONS) MICA (CI: 77019) The application of the stick of lipstick of the example 2 according to the invention is more pleasing, and in particular has a better sliding effect than that of Comparative Example 1.

  In addition, it is observed that the composition 2 according to the invention has an improved non-transfer behavior and level compared to Comparative Example 1.

Claims (56)

  Cosmetic make-up or skincare composition comprising, in a physiologically acceptable medium, at least one fatty phase comprising: at least one first resin having a number-average molecular weight of less than or equal to 10,000 g / mol chosen from rosin, rosin, hydrocarbon resins and mixtures thereof, at least one silicone polyamide, and at least one second resin, said second resin being silicone-coated.   2. Cosmetic composition according to the preceding claim, characterized in that said first resin and said silicone polyamide are present in a ratio such that the mass proportion of silicone polyamide / first resin is greater than or equal to 2.   3. Cosmetic composition according to any one of the preceding claims, characterized in that the proportion by mass silicone polyamide / first resin ranging from 2 to 40.   4. Composition according to any one of the preceding claims, comprising less than 10% or even less than 4% of water, in particular being anhydrous.   5. Composition according to any one of the preceding claims, having a total content of silicone polyamides representing from 0.5 to 70%, preferably from 5 to 50%, and more preferably from 8 to 45% of the total weight of the composition. .   6. Composition according to any one of the preceding claims, in which the silicone polyamide comprises at least one unit corresponding to the general formula I: ## STR2 ## in which: ## STR1 ## represents C (O) when G is -C (O) -NH-Y-NH-, and G 'is -NH- when G is -NH-C (O) -YC (O) -2) R4, R5, R6 and R7, which may be identical or different, represent a group chosen from: saturated or unsaturated, linear, branched or cyclic, C1 to C4o hydrocarbon groups, which may contain in their chain one or more oxygen, sulfur and / or nitrogen, and may be substituted in part or totally by fluorine atoms, - C6-C10 aryl groups, optionally substituted by one or more C1-C4 alkyl groups, -the polyorganosiloxane chains containing or not one or more oxygen atoms, sulfur and / or nitrogen, 3) the X, identical or different, represent a group al kylene di-yl, linear or branched C1 to Cao, which may contain in its chain one or more oxygen and / or nitrogen atoms, 4) Y is a divalent linear or branched alkylene, arylene, cycloalkylene, alkylarylene or arylalkylene, saturated or unsaturated, C1 to C50, which may contain one or more oxygen, sulfur and / or nitrogen atoms, and / or may substitute one of the following atoms or groups of atoms: fluorine, hydroxy, C 3 -C 8 cycloalkyl, C 1 -C 40 alkyl, C 5 -C 10 aryl, phenyl optionally substituted with 1 to 3 C 1 to C 3 alkyl, C 1 to C 3 hydroxyalkyl and C 1 to C 6 alkylaryl, or 5) Y represents a group corresponding to the formula: in which - T represents a trivalent or tetravalent hydrocarbon group, linear or branched, saturated or unsaturated, C3 to C24 optionally substituted with a polyorganosiloxane chain, and which may contain one or more atoms chosen from O , N and S, or T represents a trivalent atom chosen from N, P and Al, and - R8 represents a linear or branched C1-C50 alkyl group, or a polyorganosiloxane chain, which may comprise one or more ester, amide, urethane, thiocarbamate, urea, thiourea and and / or sulfonamide which may or may not be linked to another chain of the polymer, 6) n is an integer ranging from 2 to 500, preferably from 2 to 200, and m is an integer ranging from 1 to 1000, preferably from 1 to 700 and more preferably from 6 to 200.   7. Composition according to the preceding claim, wherein X and / or Y represent an alkylene group containing in its alkylene part at least one of the following elements: 1) 1 to 5 amide groups, urea, urethane, or carbamate, 2) a C5 or C6 cycloalkyl group, and 3) a phenylene group optionally substituted with 1 to 3 identical or different C1 to C3 alkyl groups, and / or substituted by at least one element selected from the group consisting of: - a hydroxyl group a C 3 to C 8 cycloalkyl group, one to three C 1 to C 4 alkyl groups, a phenyl group optionally substituted with one to three C 1 to C 3 alkyl groups, a C 1 to C 3 hydroxyalkyl group, and a amino-C1-C6 alkyl group.   8. Composition according to any one of claims 6 and 7, wherein R4, R5, R6 and R7 represent, independently, a linear or branched C1-C40 alkyl group, preferably a CH3, C2H5, n-C3H7 group. or isopropyl, a polyorganosiloxane chain or a phenyl group optionally substituted with one to three methyl or ethyl groups.   9. Composition according to any one of the preceding claims, comprising at least one polymer of general formula (I) as defined in claim 6 and having an index m with a value greater than 50, in particular greater than 75, better than 100 and in particular about 120. 30   10. Product according to the preceding claim, wherein the polymer of formula (I) preferably has a weight average molecular weight ranging from 10,000 to 500,000 g / mol. 10 15 20   11. Composition according to any one of the preceding claims, comprising at least one first silicone polyamide and at least one second silicone polyamide each independently comprising at least one unit of formula (I) as defined in claim 6 in which: m varies from 50 to 600, in particular from 60 to 400, in particular from 75 to 200 and more particularly is of the order of 120 for the first polymer and m is from 5 to 100, in particular from 10 to 75, and more particularly is of the order of 15 for the second polymer.   12. Composition according to the preceding claim, wherein the first polymer has a weight average molecular weight of between 10,000 and 500,000 g / mol.   13. Composition according to claim 11 or 12, wherein the second polymer preferably has a weight average molecular weight ranging from 1,000 to 500,000 g / mol, especially between 10,000 and 300,000 g / mol. 15   14. Composition according to any one of the preceding claims, characterized in that said first resin has a number average molecular weight ranging from 250 to 10000 g / mol.   15. Composition according to any one of the preceding claims, characterized in that said first resin is an indene hydrocarbon resin resulting from the polymerization of indene monomer and of monomer chosen from styrene, methylindene, methylstyrene and their mixtures.   16. Composition according to the preceding claim, characterized in that said first indene hydrocarbon resin is hydrogenated.   17. Composition according to any one of claims 1 to 16, characterized in that said first resin is an indene resin chosen from hydrogenated indene / methylstyrene / styrene copolymers.   18. Composition according to any one of claims 1 to 16, characterized in that said first resin is an aliphatic pentanediene resin resulting from the polymerization of the monomer 1,3-pentanediene (trans or cis piperylene) and monomer chosen from isoprene, butene, 2-methyl-2-butene, pentene, 1,4-pentanediene and mixtures thereof.   19. Composition according to any one of claims 1 to 16, characterized in that said first resin is a mixed resin of pentanediene and indene.   20. Composition according to any one of claims 1 to 16, characterized in that said first resin is a diene resin of cyclopentanediene dimers resulting from the polymerization of the first monomer chosen from indene and styrene, and second monomer chosen among the dimers of cyclopentanediene.   21. Composition according to any one of claims 1 to 16, characterized in that said first resin is a diene resin of isoprene dimer resulting from the polymerization of at least one monomer chosen from α-pinene, the 13-pinene, limonene, and mixtures thereof.   22. Composition according to any one of the preceding claims, characterized in that said first resin is present in a content ranging from 0.1 to 30% by weight, relative to the total weight of the composition, preferably ranging from 0, 3 to 20% by weight, more preferably from 0.5 to 15% by weight.   23. Composition according to any one of the preceding claims, characterized in that said second silicone resin is a siloxysilicate resin, such as trimethylsiloxysilicate resin.   24. Composition according to any one of the preceding claims, characterized in that said second silicone resin represents 0.5 to 30% relative to the total weight of the composition, preferably 1 to 25%, or more preferably 5 to 25%.   25. Composition according to any one of the preceding claims, characterized in that said second silicone resin is present in a ratio such that the mass proportion of silicone polyamide / silicone resin is between 1/4 and 4, and preferably between 1/4 and 3 and 3.   26. Composition according to any one of the preceding claims, characterized in that said first resin is a hydrogenated indene / methylstyrene / styrene copolymer, in that said silicone polyamide is the nylon-611 / dimethicone copolymer, and in that said second resin is the trimethylsiloxysilicate resin.   27. Composition according to any one of the preceding claims, characterized in that it is liquid.   28. Composition according to any one of the preceding claims, characterized in that it is solid.   29. Composition according to any one of the preceding claims, characterized in that it comprises at least one silicone oil.   30. Composition according to the preceding claim, characterized in that the or said silicone oils represent from 0.1 to 70% relative to the total weight of the composition, or better still from 5 to 60%.   31. Composition according to any one of claims 29 and 30, characterized in that the one or more silicone oils represent at least 20% relative to the total weight of the composition, or better still at least 30%.   32. Composition according to any one of claims 29 to 31, characterized in that said silicone oil is a phenyl silicone oil.   33. Composition according to any one of the preceding claims, characterized in that it comprises at least one pasty fatty substance.   34. Composition according to any one of the preceding claims, characterized in that it comprises less than 10% by weight of pasty fat, preferably less than 7%, better less than 5%, and even more preferably less than 3%. by weight of pasty fatty substance relative to the total weight of the composition, or even is completely free of pasty fat.   35. Composition according to any one of the preceding claims, characterized in that it comprises at least one wax.   36. Composition according to the preceding claim, characterized in that the wax content represents from 0.1 to 20% by weight relative to the total weight of the composition, or better still from 0.5 to 15%, or more particularly from 1 to at 15%.   37. Composition according to any one of claims 1 to 34, characterized in that it is free of wax.   38. Composition according to any one of the preceding claims, characterized in that it comprises at least one volatile oil.   39. Composition according to the preceding claim, characterized in that the said volatile oil (s) represent (s) from 0.1 to 60%, and better still from 0.5 to 40%, of the total weight of the composition.   40. Composition according to the preceding claim, characterized in that said volatile oil is chosen from volatile hydrocarbons such as isododecane and isohexadecane, isoparaffins C8-C16.   41. A composition according to any one of the preceding claims, comprising at least one non-volatile oil.   42. Composition according to any one of claims 1 to 40, characterized in that it is free of non-volatile oil.   43. Composition according to any one of the preceding claims, comprising at least one non-silicone oil. 10   44. Composition according to any one of the preceding claims, comprising at least one ester oil.   45. Composition according to any one of the preceding claims, further comprising at least one active agent chosen from: - skin-relaxing agents, - agents stimulating the synthesis of dermal or epidermal macromolecules and / or preventing their degradation, - anti-inflammatory agents; glycation, - anti-irritant agents, - moisturizing agents, - desquamating agents - depigmenting, anti-pigmenting or pro-pigmenting agents, - inhibitors of NO-synthase, - agents stimulating the proliferation of fibroblasts or keratinocytes and / or differentiation of keratinocytes, anti-pollution or anti-radical agents, soothing agents, agents acting on the microcirculation, agents acting on the energetic metabolism of cells, healing agents, and - their mixtures.   46. Composition according to any one of the preceding claims, comprising at least one film-forming polymer. 15 20 25 30   47. Composition according to any one of the preceding claims, comprising at least one surfactant.   48. Composition according to any one of the preceding claims, comprising at least one dyestuff.   49. A composition according to any one of the preceding claims comprising a filler.   50. Composition according to any one of the preceding claims, characterized in that it is in the form of a solid foundation, stick or paste of lipstick, concealer, or eye contours, d. eye liner, mascara, eye shadow, body make-up product or a skin coloring product.   51. A process for making up the skin and / or the lips and / or integuments, in which a composition as defined according to any one of the preceding claims is applied.   52. Use of a Silicone Polyamide in Combination with a First Resin of Average Molecular Weight of Less Than or Equal to 10000 g / mol Selected Among Rosin, Rosin Derivatives, Hydrocarbon Resins and Their Blends, and with a Second Resin silicone, as defined in claims 1 to 26, for preparing a solid cosmetic composition for the skin and / or the lips and / or integuments, capable of providing an improved holding film.   53. Makeup product characterized in that it comprises at least a first composition as defined in any one of claims 1 to 50 and in that it comprises at least a second composition comprising at least one liquid fatty phase.   54. Makeup product according to the preceding claim, characterized in that said fatty phase of said second composition comprises at least one phenyl silicone oil.   55. A process for making up the skin and / or the lips and / or the integuments comprising applying to the skin, the lips and / or the integuments a first layer of a first composition comprising at least one silicone polyamide, at least one first resin having a number average molecular weight of less than or equal to 10,000 g / mol chosen from rosin, rosin derivatives, hydrocarbon resins and their mixtures, and at least one second resin, said second resin being silicone-coated, and then to be applied to all or part of said first layer, a second layer of a second composition comprising at least one liquid fatty phase.   56. Makeup kit comprising at least one product according to the preceding claim.