FR2888583B1 - Nouveau procede de desulfuration d'essences olefiniques permettant de limiter la teneur en mercaptans - Google Patents
Nouveau procede de desulfuration d'essences olefiniques permettant de limiter la teneur en mercaptansInfo
- Publication number
- FR2888583B1 FR2888583B1 FR0507685A FR0507685A FR2888583B1 FR 2888583 B1 FR2888583 B1 FR 2888583B1 FR 0507685 A FR0507685 A FR 0507685A FR 0507685 A FR0507685 A FR 0507685A FR 2888583 B1 FR2888583 B1 FR 2888583B1
- Authority
- FR
- France
- Prior art keywords
- essences
- limiting
- gasoline
- novel method
- mercaptan content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 title 1
- 230000003009 desulfurizing effect Effects 0.000 title 1
- 239000000686 essence Substances 0.000 title 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4006—Temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4012—Pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/04—Organic compounds
- C10L2200/0407—Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
- C10L2200/0415—Light distillates, e.g. LPG, naphtha
- C10L2200/0423—Gasoline
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0507685A FR2888583B1 (fr) | 2005-07-18 | 2005-07-18 | Nouveau procede de desulfuration d'essences olefiniques permettant de limiter la teneur en mercaptans |
DE602006003482T DE602006003482D1 (de) | 2005-07-18 | 2006-06-22 | Neues Verfahren zur Entschwefelung eines olefinischen Benzins zur Begrenzung von Mercaptan. |
EP06291025A EP1746144B1 (fr) | 2005-07-18 | 2006-06-22 | Nouveau procédé de désulfuration d'essences oléfiniques permettant de limiter la teneur en mercaptans |
CN200610105721.4A CN1900230B (zh) | 2005-07-18 | 2006-07-17 | 使烯烃汽油脱硫以限制硫醇含量的新方法 |
US11/487,605 US8034233B2 (en) | 2005-07-18 | 2006-07-17 | Process for desulphurizing olefinic gasolines to limit the mercaptans content |
JP2006195032A JP5138907B2 (ja) | 2005-07-18 | 2006-07-18 | チオール含有量を制限するためにオレフィンガソリンを脱硫するための新規な方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0507685A FR2888583B1 (fr) | 2005-07-18 | 2005-07-18 | Nouveau procede de desulfuration d'essences olefiniques permettant de limiter la teneur en mercaptans |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2888583A1 FR2888583A1 (fr) | 2007-01-19 |
FR2888583B1 true FR2888583B1 (fr) | 2007-09-28 |
Family
ID=36177723
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR0507685A Expired - Fee Related FR2888583B1 (fr) | 2005-07-18 | 2005-07-18 | Nouveau procede de desulfuration d'essences olefiniques permettant de limiter la teneur en mercaptans |
Country Status (6)
Country | Link |
---|---|
US (1) | US8034233B2 (fr) |
EP (1) | EP1746144B1 (fr) |
JP (1) | JP5138907B2 (fr) |
CN (1) | CN1900230B (fr) |
DE (1) | DE602006003482D1 (fr) |
FR (1) | FR2888583B1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107429172B (zh) * | 2015-04-15 | 2020-07-03 | Ifp 新能源公司 | 将烯烃型汽油中的硫醚类型的化合物脱硫的方法 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101343562B (zh) * | 2007-07-09 | 2011-09-21 | 中国石油化工股份有限公司 | 一种汽油加氢脱硫、降烯烃方法 |
WO2011114352A2 (fr) * | 2010-03-17 | 2011-09-22 | Indian Oil Corporation Limited | Procédé pour extraction sélective de mercaptan d'un carburéacteur |
CN102465025B (zh) * | 2010-11-05 | 2014-05-21 | 中国石油化工股份有限公司 | 一种劣质汽油加工方法 |
CN102839021A (zh) * | 2011-06-22 | 2012-12-26 | 北京金伟晖工程技术有限公司 | 一种低成本制造低硫高辛烷值汽油的装置及其方法 |
US9017545B2 (en) * | 2011-11-10 | 2015-04-28 | China Petroleum & Chemical Corporation | Process for hydrotreating inferior naphtha fraction |
US9806164B1 (en) * | 2013-03-26 | 2017-10-31 | The Penn State Research Foundation | Controlled synthesis and transfer of large area heterostructures made of bilayer and multilayer transition metal dichalocogenides |
US10144883B2 (en) | 2013-11-14 | 2018-12-04 | Uop Llc | Apparatuses and methods for desulfurization of naphtha |
US10597593B2 (en) | 2016-10-07 | 2020-03-24 | Haldor Topsoe A/S | Process for hydrotreatment of a fuel gas stream containing more than 4% olefins |
FR3116740A1 (fr) * | 2020-11-27 | 2022-06-03 | IFP Energies Nouvelles | Procédé de préparation d’un catalyseur d’hydrodésulfuration d’une coupe essence comprenant un métal du groupe VIB, un métal du groupe VIII et du carbone graphitique |
FR3130834A1 (fr) * | 2021-12-20 | 2023-06-23 | IFP Energies Nouvelles | Procédé de traitement d'une essence contenant des composés soufrés |
FR3142487A1 (fr) * | 2022-11-30 | 2024-05-31 | IFP Energies Nouvelles | Procédé d’hydrodésulfuration de finition des essences mettant en œuvre un catalyseur à base de métaux du groupe VIB et VIII et du phosphore sur support alumine à faible surface spécifique |
FR3142486A1 (fr) * | 2022-11-30 | 2024-05-31 | IFP Energies Nouvelles | Procédé d’hydrodésulfuration de finition des essences mettant en œuvre un enchaînement de catalyseurs |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2431920A (en) | 1944-12-21 | 1947-12-02 | Shell Dev | Catalytic treatment of sulfurbearing hydrocarbon distillates |
US2746907A (en) * | 1952-01-11 | 1956-05-22 | Union Oil Co | Process for hydro-desulfurization of light hydrocarbons using a nickel oxide catalyst |
US4113603A (en) * | 1977-10-19 | 1978-09-12 | The Lummus Company | Two-stage hydrotreating of pyrolysis gasoline to remove mercaptan sulfur and dienes |
JPH07102266A (ja) * | 1993-11-17 | 1995-04-18 | Tonen Corp | 石油蒸留物の低イオウ化方法 |
JP3269900B2 (ja) * | 1993-12-06 | 2002-04-02 | 日石三菱株式会社 | 分解ガソリン留分の脱硫処理方法 |
JP3291164B2 (ja) * | 1995-06-02 | 2002-06-10 | 日石三菱株式会社 | 接触分解ガソリンの脱硫方法 |
US5968466A (en) | 1995-06-07 | 1999-10-19 | Asec Manufacturing | Copper-silver zeolite catalysts in exhaust gas treatment |
JP3387700B2 (ja) * | 1995-07-26 | 2003-03-17 | 新日本石油株式会社 | 接触分解ガソリンの脱硫方法 |
US6126814A (en) * | 1996-02-02 | 2000-10-03 | Exxon Research And Engineering Co | Selective hydrodesulfurization process (HEN-9601) |
US6409913B1 (en) | 1996-02-02 | 2002-06-25 | Exxonmobil Research And Engineering Company | Naphtha desulfurization with reduced mercaptan formation |
US6231754B1 (en) | 1996-02-02 | 2001-05-15 | Exxon Research And Engineering Company | High temperature naphtha desulfurization using a low metal and partially deactivated catalyst |
US6231753B1 (en) * | 1996-02-02 | 2001-05-15 | Exxon Research And Engineering Company | Two stage deep naphtha desulfurization with reduced mercaptan formation |
US5968346A (en) * | 1998-09-16 | 1999-10-19 | Exxon Research And Engineering Co. | Two stage hydroprocessing with vapor-liquid interstage contacting for vapor heteroatom removal |
US6824673B1 (en) * | 1998-12-08 | 2004-11-30 | Exxonmobil Research And Engineering Company | Production of low sulfur/low aromatics distillates |
EP1268711A4 (fr) * | 1999-12-22 | 2004-06-09 | Exxonmobil Res & Eng Co | Depressurisation a haute temperature pour l'elimination de mercaptans de naphta |
CA2407066A1 (fr) | 2000-04-18 | 2001-10-25 | Exxonmobil Research And Engineering Company | Hydrocraquage et elimination selectifs de mercaptans |
FR2811328B1 (fr) * | 2000-07-06 | 2002-08-23 | Inst Francais Du Petrole | Procede comprenant deux etapes d'hydrodesulfuration d'essence et une elimination intermediaire de l'h2s forme au cours de la premiere etape |
US6736962B1 (en) | 2000-09-29 | 2004-05-18 | Exxonmobil Research And Engineering Company | Catalytic stripping for mercaptan removal (ECB-0004) |
US7153415B2 (en) * | 2002-02-13 | 2006-12-26 | Catalytic Distillation Technologies | Process for the treatment of light naphtha hydrocarbon streams |
FR2840315B1 (fr) * | 2002-06-03 | 2004-08-20 | Inst Francais Du Petrole | Procede d'hydrodesulfuration de coupes contenant des composes soufres et des olefines en presence d'un catalyseur supporte comprenant des metaux des groupes viii et vib |
FR2850299B1 (fr) * | 2003-01-29 | 2006-12-01 | Inst Francais Du Petrole | Catalyseurs partiellement cokes utilisables dans l'hydrotraitement des coupes contenant des composes soufres et des olefines |
-
2005
- 2005-07-18 FR FR0507685A patent/FR2888583B1/fr not_active Expired - Fee Related
-
2006
- 2006-06-22 EP EP06291025A patent/EP1746144B1/fr not_active Revoked
- 2006-06-22 DE DE602006003482T patent/DE602006003482D1/de active Active
- 2006-07-17 US US11/487,605 patent/US8034233B2/en not_active Expired - Fee Related
- 2006-07-17 CN CN200610105721.4A patent/CN1900230B/zh not_active Expired - Fee Related
- 2006-07-18 JP JP2006195032A patent/JP5138907B2/ja not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107429172B (zh) * | 2015-04-15 | 2020-07-03 | Ifp 新能源公司 | 将烯烃型汽油中的硫醚类型的化合物脱硫的方法 |
Also Published As
Publication number | Publication date |
---|---|
JP2007023285A (ja) | 2007-02-01 |
US8034233B2 (en) | 2011-10-11 |
CN1900230B (zh) | 2012-10-31 |
CN1900230A (zh) | 2007-01-24 |
EP1746144B1 (fr) | 2008-11-05 |
JP5138907B2 (ja) | 2013-02-06 |
US20070012596A1 (en) | 2007-01-18 |
FR2888583A1 (fr) | 2007-01-19 |
DE602006003482D1 (de) | 2008-12-18 |
EP1746144A1 (fr) | 2007-01-24 |
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