FR2880024B1 - Utilisation de copolymeres a gradient de composition comme stabilisants dans la polymerisation radiculaire en emulsion - Google Patents

Utilisation de copolymeres a gradient de composition comme stabilisants dans la polymerisation radiculaire en emulsion

Info

Publication number
FR2880024B1
FR2880024B1 FR0413813A FR0413813A FR2880024B1 FR 2880024 B1 FR2880024 B1 FR 2880024B1 FR 0413813 A FR0413813 A FR 0413813A FR 0413813 A FR0413813 A FR 0413813A FR 2880024 B1 FR2880024 B1 FR 2880024B1
Authority
FR
France
Prior art keywords
emulsion
polymerization
radicular
stabilizers
gradient copolymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0413813A
Other languages
English (en)
French (fr)
Other versions
FR2880024A1 (fr
Inventor
Stephanie Magnet
Olivier Guerret
Catherine Lefay
Bernadette Charleux
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema SA
Original Assignee
Arkema SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0413813A priority Critical patent/FR2880024B1/fr
Application filed by Arkema SA filed Critical Arkema SA
Priority to PCT/EP2005/014169 priority patent/WO2006066971A1/en
Priority to US11/722,199 priority patent/US8389637B2/en
Priority to EP05825367A priority patent/EP2054447B1/en
Priority to CNA2005800444139A priority patent/CN101094871A/zh
Priority to MX2007007755A priority patent/MX2007007755A/es
Priority to JP2007547396A priority patent/JP2008525547A/ja
Priority to KR1020077014212A priority patent/KR20070093069A/ko
Priority to AT05825367T priority patent/ATE530583T1/de
Priority to TW094146233A priority patent/TW200640952A/zh
Publication of FR2880024A1 publication Critical patent/FR2880024A1/fr
Application granted granted Critical
Publication of FR2880024B1 publication Critical patent/FR2880024B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Cosmetics (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
FR0413813A 2004-12-23 2004-12-23 Utilisation de copolymeres a gradient de composition comme stabilisants dans la polymerisation radiculaire en emulsion Expired - Fee Related FR2880024B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR0413813A FR2880024B1 (fr) 2004-12-23 2004-12-23 Utilisation de copolymeres a gradient de composition comme stabilisants dans la polymerisation radiculaire en emulsion
AT05825367T ATE530583T1 (de) 2004-12-23 2005-12-22 Verwendung von copolymeren mit einem zusammensetzungsgradienten als stabilisatoren bei der radikalischen emulsionspolymerisation
EP05825367A EP2054447B1 (en) 2004-12-23 2005-12-22 Use of copolymers with a composition gradient as stabilizers in emulsion free-radical polymerization
CNA2005800444139A CN101094871A (zh) 2004-12-23 2005-12-22 有组成梯度的共聚物作为乳液自由基聚合中的稳定剂的用途
MX2007007755A MX2007007755A (es) 2004-12-23 2005-12-22 Uso de copolimeros con un gradiente de composicion como estabilizadores en polimierizacion de emulsion de radical libre.
JP2007547396A JP2008525547A (ja) 2004-12-23 2005-12-22 組成勾配を有するコポリマーの、乳化フリーラジカル重合での安定化剤としての使用
PCT/EP2005/014169 WO2006066971A1 (en) 2004-12-23 2005-12-22 Use of copolymers with a composition gradient as stabilizers in emulsion free-radical polymerization
US11/722,199 US8389637B2 (en) 2004-12-23 2005-12-22 Use of copolymers with a composition gradient as stabilizers in emulsion free-radical polymerization
KR1020077014212A KR20070093069A (ko) 2004-12-23 2005-12-22 유화 유리-라디칼 중합에서 안정제로서의 조성 구배를 갖는공중합체의 용도
TW094146233A TW200640952A (en) 2004-12-23 2005-12-23 Use of copolymers with a composition gradient as stabilizers in emulsion free-radical polymerization

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0413813A FR2880024B1 (fr) 2004-12-23 2004-12-23 Utilisation de copolymeres a gradient de composition comme stabilisants dans la polymerisation radiculaire en emulsion

Publications (2)

Publication Number Publication Date
FR2880024A1 FR2880024A1 (fr) 2006-06-30
FR2880024B1 true FR2880024B1 (fr) 2007-02-02

Family

ID=34951826

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0413813A Expired - Fee Related FR2880024B1 (fr) 2004-12-23 2004-12-23 Utilisation de copolymeres a gradient de composition comme stabilisants dans la polymerisation radiculaire en emulsion

Country Status (10)

Country Link
US (1) US8389637B2 (OSRAM)
EP (1) EP2054447B1 (OSRAM)
JP (1) JP2008525547A (OSRAM)
KR (1) KR20070093069A (OSRAM)
CN (1) CN101094871A (OSRAM)
AT (1) ATE530583T1 (OSRAM)
FR (1) FR2880024B1 (OSRAM)
MX (1) MX2007007755A (OSRAM)
TW (1) TW200640952A (OSRAM)
WO (1) WO2006066971A1 (OSRAM)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009154205A1 (ja) * 2008-06-20 2009-12-23 東亞合成株式会社 接着剤組成物
FR2935000B1 (fr) * 2008-08-12 2011-07-01 Arkema France Procede de synthese de copolymeres amphiphiles a gradient de compositon et solubles en milieu alcalin
FR2974094A1 (fr) * 2011-04-15 2012-10-19 Arkema France Procede de preparation de surfaces
CN102391523B (zh) * 2011-08-29 2012-12-26 华南理工大学 具有双亲结构的苯乙烯-丙烯酸酯水分散体及其制备方法
CN103205202A (zh) * 2013-04-03 2013-07-17 中山职业技术学院 一种表面张力梯度性变化的梯度功能涂料及其制备方法
US20230383043A1 (en) 2020-11-30 2023-11-30 Basf Se Process of producing polymer dispersions
JP7770175B2 (ja) * 2021-12-14 2025-11-14 東ソー・ファインケム株式会社 上限臨界溶液温度型の温度応答性を有するカルボン酸系ポリマー及びその用途

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4414370A (en) * 1981-01-09 1983-11-08 S. C. Johnson & Son, Inc. Process for continuous bulk copolymerization of vinyl monomers
US4529787A (en) * 1982-06-15 1985-07-16 S. C. Johnson & Son, Inc. Bulk polymerization process for preparing high solids and uniform copolymers
JPS617368A (ja) * 1984-06-20 1986-01-14 Sumitomo Naugatuck Co Ltd 粘着剤組成物
US5807937A (en) * 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
DE19602538A1 (de) * 1996-01-25 1997-07-31 Basf Ag Verfahren zur Herstellung einer wäßrigen Polymerisatdispersion nach der Methode der radikalischen wäßrigen Emulsionspolymerisation
DE19704714A1 (de) 1996-01-25 1997-07-31 Basf Ag Amphiphile Blockcopolymere
US6160059A (en) * 1996-07-26 2000-12-12 Cook Composites And Polymers Co. Bulk polymerization process for preparing solid acrylic resin
DE19654168A1 (de) 1996-12-23 1998-06-25 Basf Ag Verfahren zur Herstellung wäßriger Polymerisatdispersionen durch radikalische, wäßrige Emulsionspolymerisation
US6437040B2 (en) * 1999-09-01 2002-08-20 Rhodia Chimie Water-soluble block copolymers comprising a hydrophilic block and a hydrophobic block
EP1199326A3 (en) * 2000-10-17 2004-01-07 National Starch and Chemical Investment Holding Corporation Aqueous polymer solution
FR2838653B1 (fr) 2002-04-18 2005-02-18 Rhodia Chimie Sa Procede de preparation d'une emulsion par dilution d'un concentre emulsionnable comprenant un copolymere amphiphile
DE10236133A1 (de) * 2002-08-07 2004-02-26 Byk-Chemie Gmbh Verwendung von Gradientencopolymeren als Dispergiermittel zur Behandlung von Pigmenten und Feststoffen
FR2848557B1 (fr) * 2002-12-13 2006-07-07 Atofina Copolymeres a gradient solubles ou du moins dispersibles dans l'eau comme dans les solvants organiques

Also Published As

Publication number Publication date
EP2054447B1 (en) 2011-10-26
TW200640952A (en) 2006-12-01
KR20070093069A (ko) 2007-09-17
WO2006066971A1 (en) 2006-06-29
FR2880024A1 (fr) 2006-06-30
CN101094871A (zh) 2007-12-26
ATE530583T1 (de) 2011-11-15
MX2007007755A (es) 2007-08-17
US20100036059A1 (en) 2010-02-11
JP2008525547A (ja) 2008-07-17
US8389637B2 (en) 2013-03-05
EP2054447A1 (en) 2009-05-06

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Effective date: 20130830