FR2850299B1 - Catalyseurs partiellement cokes utilisables dans l'hydrotraitement des coupes contenant des composes soufres et des olefines - Google Patents

Catalyseurs partiellement cokes utilisables dans l'hydrotraitement des coupes contenant des composes soufres et des olefines

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Publication number
FR2850299B1
FR2850299B1 FR0301026A FR0301026A FR2850299B1 FR 2850299 B1 FR2850299 B1 FR 2850299B1 FR 0301026 A FR0301026 A FR 0301026A FR 0301026 A FR0301026 A FR 0301026A FR 2850299 B1 FR2850299 B1 FR 2850299B1
Authority
FR
France
Prior art keywords
cokes
hydroprocessing
olefins
catalysts
partially
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
FR0301026A
Other languages
English (en)
French (fr)
Other versions
FR2850299A1 (fr
Inventor
Denis Uzio
George Nathalie Marchal
Christophe Bouchy
Florent Picard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR0301026A priority Critical patent/FR2850299B1/fr
Priority to DK18185334.2T priority patent/DK3428248T3/da
Priority to EP18185334.2A priority patent/EP3428248B1/fr
Priority to EP03293276A priority patent/EP1447436A1/fr
Priority to US10/765,840 priority patent/US7347931B2/en
Priority to JP2004020802A priority patent/JP4547922B2/ja
Publication of FR2850299A1 publication Critical patent/FR2850299A1/fr
Application granted granted Critical
Publication of FR2850299B1 publication Critical patent/FR2850299B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/755Nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/882Molybdenum and cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0203Impregnation the impregnation liquid containing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/084Decomposition of carbon-containing compounds into carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20Sulfiding
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/638Pore volume more than 1.0 ml/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
FR0301026A 2003-01-29 2003-01-29 Catalyseurs partiellement cokes utilisables dans l'hydrotraitement des coupes contenant des composes soufres et des olefines Expired - Lifetime FR2850299B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR0301026A FR2850299B1 (fr) 2003-01-29 2003-01-29 Catalyseurs partiellement cokes utilisables dans l'hydrotraitement des coupes contenant des composes soufres et des olefines
DK18185334.2T DK3428248T3 (da) 2003-01-29 2003-12-19 Delvist forkoksede katalysatorer, der kan anvendes i hydrogenbehandling af oliefraktioner indeholdende svovlforbindelser og olefiner
EP18185334.2A EP3428248B1 (fr) 2003-01-29 2003-12-19 Catalyseurs partiellement cokes utilisables dans l'hydrotraitement des coupes contenant des composes soufres et des olefines
EP03293276A EP1447436A1 (fr) 2003-01-29 2003-12-19 Catalyseurs partiellement cokes utilisables dans l'hydrotraitement des coupes contenant des composes soufres et des olefines
US10/765,840 US7347931B2 (en) 2003-01-29 2004-01-29 Partially coked catalysts that can be used in the hydrotreatment of fractions that contain sulfur-containing compounds and olefins
JP2004020802A JP4547922B2 (ja) 2003-01-29 2004-01-29 硫黄化合物及びオレフィンを含む留分の水素処理に使用可能な部分的にコーキングされた触媒

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0301026A FR2850299B1 (fr) 2003-01-29 2003-01-29 Catalyseurs partiellement cokes utilisables dans l'hydrotraitement des coupes contenant des composes soufres et des olefines

Publications (2)

Publication Number Publication Date
FR2850299A1 FR2850299A1 (fr) 2004-07-30
FR2850299B1 true FR2850299B1 (fr) 2006-12-01

Family

ID=32669330

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0301026A Expired - Lifetime FR2850299B1 (fr) 2003-01-29 2003-01-29 Catalyseurs partiellement cokes utilisables dans l'hydrotraitement des coupes contenant des composes soufres et des olefines

Country Status (5)

Country Link
US (1) US7347931B2 (enExample)
EP (2) EP3428248B1 (enExample)
JP (1) JP4547922B2 (enExample)
DK (1) DK3428248T3 (enExample)
FR (1) FR2850299B1 (enExample)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2874838B1 (fr) * 2004-09-08 2006-11-24 Inst Francais Du Petrole Procede de sulfuration de catalyseurs d'hydrotraitement
US20060234860A1 (en) * 2005-04-15 2006-10-19 Brignac Garland B Activating hydroprocessing catalysts using carbon monoxide
FR2885137B1 (fr) * 2005-04-28 2007-07-13 Inst Francais Du Petrole Procede de desulfuration d'essences olefiniques
WO2006119311A2 (en) * 2005-05-02 2006-11-09 Symyx Technologies, Inc. High surface area metal and metal oxide materials and methods of making same
FR2888583B1 (fr) * 2005-07-18 2007-09-28 Inst Francais Du Petrole Nouveau procede de desulfuration d'essences olefiniques permettant de limiter la teneur en mercaptans
FR2895415B1 (fr) * 2005-12-22 2011-07-15 Inst Francais Du Petrole Procede d'hydrogenation selective mettant en oeuvre un catalyseur presentant un support specifique
FR2895416B1 (fr) 2005-12-22 2011-08-26 Inst Francais Du Petrole Procede d'hydrogenation selective mettant en oeuvre un catalyseur sulfure
FR2895414B1 (fr) * 2005-12-22 2011-07-29 Inst Francais Du Petrole Procede d'hydrogenation selective mettant en oeuvre un catalyseur presentant une porosite controlee
US7632962B2 (en) * 2006-04-26 2009-12-15 Eastman Chemical Company Hydrogenation process and catalysts
US7842639B2 (en) * 2006-05-19 2010-11-30 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Mechanical alloying of a hydrogenation catalyst used for the remediation of contaminated compounds
CA2673289C (en) * 2006-12-19 2015-07-28 Exxonmobil Research And Engineering Company High activity supported distillate hydroprocessing catalysts
CN101903499A (zh) * 2007-10-31 2010-12-01 雪佛龙美国公司 采用多金属催化剂的加氢转化方法和该多金属催化剂的制备方法
JP5566896B2 (ja) * 2007-10-31 2014-08-06 シェブロン ユー.エス.エー. インコーポレイテッド 水素化処理のバルク触媒及びその使用
FR2949981B1 (fr) 2009-09-11 2012-10-12 Eurecat Sa Procede de sulfuration de catalyseurs de traitement d'hydrocarbures
JP5690634B2 (ja) * 2011-03-31 2015-03-25 独立行政法人石油天然ガス・金属鉱物資源機構 水素化精製触媒及び炭化水素油の製造方法
JP5660956B2 (ja) * 2011-03-31 2015-01-28 独立行政法人石油天然ガス・金属鉱物資源機構 水素化分解触媒及び炭化水素油の製造方法
FR2984761B1 (fr) * 2011-12-21 2014-12-26 IFP Energies Nouvelles Procede de preparation d'un catalyseur a base d'un metal du groupe viii prepare au moyen d'au moins un additif organique et procede d'hydrogenation selective mettant en oeuvre ledit catalyseur
CN108620120B (zh) * 2017-03-24 2020-11-06 中国石油化工股份有限公司 一种催化柴油加氢转化催化剂的制备方法
FR3074496B1 (fr) * 2017-12-05 2019-12-13 IFP Energies Nouvelles Hydrotraitement de charges hydrocarbonees avec un catalyseur comprenant un materiau aluminique comprenant du carbone
FR3090005B1 (fr) * 2018-12-18 2021-07-30 Ifp Energies Now Procédé d’hydrodésulfuration de coupes essence oléfinique contenant du soufre mettant en œuvre un catalyseur régénéré.
FR3089825B1 (fr) 2018-12-18 2021-05-07 Ifp Energies Now Procédé de réjuvénation d’un catalyseur usé non régénéré d’un procédé d'hydrodésulfuration d'essences.
US12473499B2 (en) 2020-04-21 2025-11-18 Sabic Global Technologies B.V. Light olefins yield improvement over light olefin selective catalyst
FR3116740A1 (fr) 2020-11-27 2022-06-03 IFP Energies Nouvelles Procédé de préparation d’un catalyseur d’hydrodésulfuration d’une coupe essence comprenant un métal du groupe VIB, un métal du groupe VIII et du carbone graphitique
FR3116830B1 (fr) * 2020-11-27 2023-11-03 Ifp Energies Now Procédé d’hydrodésulfuration d’une coupe essence mettant en œuvre un catalyseur contenant un matériau graphitique caractérisé par son rapport H/C
FR3116827A1 (fr) 2020-11-27 2022-06-03 IFP Energies Nouvelles Procédé d’hydrodésulfuration d’une coupe essence mettant en œuvre un catalyseur contenant un matériau graphitique caractérisé par spectroscopie RMN13C MAS
CN120001079B (zh) * 2025-01-03 2025-10-10 东北大学 杂[3]芳烃晶体材料在吸附分离3-甲基噻吩和正庚烷混合物中的应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3110525B2 (ja) * 1991-11-05 2000-11-20 出光興産株式会社 炭化水素油水素化処理触媒の再生方法
EP0569084B1 (en) * 1992-05-04 1996-01-03 Akzo Nobel N.V. Metal carbides, process for making the same, and catalytic end-use
JP3291164B2 (ja) * 1995-06-02 2002-06-10 日石三菱株式会社 接触分解ガソリンの脱硫方法
US5922638A (en) * 1996-06-12 1999-07-13 Europeene De Retraitement De Catalyseurs Eurecat Process for presulfurizing hydrotreatment catalysts
FR2790000B1 (fr) * 1999-02-24 2001-04-13 Inst Francais Du Petrole Procede de production d'essences a faible teneur en soufre
US6372125B1 (en) * 1999-08-23 2002-04-16 Institut Francais Du Petrole Catalyst comprising a group VIB metal carbide, phosphorous and its use for hydrodesulphurisation and hydrogenation of gas oils

Also Published As

Publication number Publication date
EP3428248B1 (fr) 2022-02-23
EP1447436A1 (fr) 2004-08-18
EP3428248A1 (fr) 2019-01-16
US7347931B2 (en) 2008-03-25
JP4547922B2 (ja) 2010-09-22
FR2850299A1 (fr) 2004-07-30
US20040226863A1 (en) 2004-11-18
JP2004230383A (ja) 2004-08-19
DK3428248T3 (da) 2022-05-09

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