FR2687483A1 - Procede pour obtenir des films comprenant des molecules organiques orientees. - Google Patents
Procede pour obtenir des films comprenant des molecules organiques orientees. Download PDFInfo
- Publication number
- FR2687483A1 FR2687483A1 FR9201967A FR9201967A FR2687483A1 FR 2687483 A1 FR2687483 A1 FR 2687483A1 FR 9201967 A FR9201967 A FR 9201967A FR 9201967 A FR9201967 A FR 9201967A FR 2687483 A1 FR2687483 A1 FR 2687483A1
- Authority
- FR
- France
- Prior art keywords
- molecules
- organic
- electric field
- layer
- orientable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 41
- 230000005684 electric field Effects 0.000 claims description 54
- 239000002243 precursor Substances 0.000 claims description 35
- XTTIQGSLJBWVIV-UHFFFAOYSA-N 2-methyl-4-nitroaniline Chemical compound CC1=CC([N+]([O-])=O)=CC=C1N XTTIQGSLJBWVIV-UHFFFAOYSA-N 0.000 claims description 31
- 229920000642 polymer Polymers 0.000 claims description 24
- 230000003287 optical effect Effects 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 17
- 229920000620 organic polymer Polymers 0.000 claims description 13
- LXQOQPGNCGEELI-UHFFFAOYSA-N 2,4-dinitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O LXQOQPGNCGEELI-UHFFFAOYSA-N 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 8
- -1 silicon alkoxides Chemical class 0.000 claims description 6
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 6
- 150000004703 alkoxides Chemical class 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 230000010287 polarization Effects 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 3
- LOCWBQIWHWIRGN-UHFFFAOYSA-N 2-chloro-4-nitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1Cl LOCWBQIWHWIRGN-UHFFFAOYSA-N 0.000 claims description 2
- KWIXNFOTNVKIGM-UHFFFAOYSA-N 2-chloro-5-nitroaniline Chemical compound NC1=CC([N+]([O-])=O)=CC=C1Cl KWIXNFOTNVKIGM-UHFFFAOYSA-N 0.000 claims description 2
- DPJCXCZTLWNFOH-UHFFFAOYSA-N 2-nitroaniline Chemical compound NC1=CC=CC=C1[N+]([O-])=O DPJCXCZTLWNFOH-UHFFFAOYSA-N 0.000 claims description 2
- TYMLOMAKGOJONV-UHFFFAOYSA-N 4-nitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1 TYMLOMAKGOJONV-UHFFFAOYSA-N 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- BNUHAJGCKIQFGE-UHFFFAOYSA-N Nitroanisol Chemical compound COC1=CC=C([N+]([O-])=O)C=C1 BNUHAJGCKIQFGE-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229910003437 indium oxide Inorganic materials 0.000 claims description 2
- 239000006193 liquid solution Substances 0.000 claims description 2
- NVLSIZITFJRWPY-ONEGZZNKSA-N n,n-dimethyl-4-[(e)-2-(4-nitrophenyl)ethenyl]aniline Chemical compound C1=CC(N(C)C)=CC=C1\C=C\C1=CC=C([N+]([O-])=O)C=C1 NVLSIZITFJRWPY-ONEGZZNKSA-N 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 229910001887 tin oxide Inorganic materials 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 229930195734 saturated hydrocarbon Natural products 0.000 claims 1
- 239000011159 matrix material Substances 0.000 abstract description 16
- 239000000463 material Substances 0.000 abstract description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 19
- 238000001228 spectrum Methods 0.000 description 12
- 238000002441 X-ray diffraction Methods 0.000 description 10
- 230000009477 glass transition Effects 0.000 description 10
- 229920000592 inorganic polymer Polymers 0.000 description 6
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 239000012456 homogeneous solution Substances 0.000 description 5
- 239000013078 crystal Substances 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- XJCVRTZCHMZPBD-UHFFFAOYSA-N 3-nitroaniline Chemical compound NC1=CC=CC([N+]([O-])=O)=C1 XJCVRTZCHMZPBD-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 150000002484 inorganic compounds Chemical class 0.000 description 3
- 229910010272 inorganic material Inorganic materials 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001341 grazing-angle X-ray diffraction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/35—Non-linear optics
- G02F1/355—Non-linear optics characterised by the materials used
- G02F1/361—Organic materials
- G02F1/3615—Organic materials containing polymers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/08—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of polarising materials
Landscapes
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Liquid Crystal (AREA)
- Laminated Bodies (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9201967A FR2687483A1 (fr) | 1992-02-17 | 1992-02-17 | Procede pour obtenir des films comprenant des molecules organiques orientees. |
| PCT/EP1993/000290 WO1993016401A1 (en) | 1992-02-17 | 1993-02-08 | Process for obtaining films comprising oriented organic molecules |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9201967A FR2687483A1 (fr) | 1992-02-17 | 1992-02-17 | Procede pour obtenir des films comprenant des molecules organiques orientees. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2687483A1 true FR2687483A1 (fr) | 1993-08-20 |
| FR2687483B1 FR2687483B1 (https=) | 1995-01-06 |
Family
ID=9426862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR9201967A Granted FR2687483A1 (fr) | 1992-02-17 | 1992-02-17 | Procede pour obtenir des films comprenant des molecules organiques orientees. |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR2687483A1 (https=) |
| WO (1) | WO1993016401A1 (https=) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0254949A2 (de) * | 1986-07-23 | 1988-02-03 | MERCK PATENT GmbH | Orientierte Polymermaterialien |
| WO1988002131A1 (en) * | 1986-09-19 | 1988-03-24 | Aktieselskabet Nordiske Kabel- Og Traadfabriker | A process for producing an electrooptical material having controllable-properties, and use of the material in electrooptical components |
| EP0293870A1 (en) * | 1987-06-03 | 1988-12-07 | Kuraray Co., Ltd. | Method for electric field orientation of liquid crystal polymers and oriented materials of liquid crystal polymers obtained by the method |
| US4877298A (en) * | 1987-02-26 | 1989-10-31 | Hoechst Celanese Corporation | Thin film waveguide electrooptic modulator |
| EP0406888A2 (en) * | 1989-07-07 | 1991-01-09 | Sumitomo Electric Industries, Ltd. | Nonlinear optical polymer composition and method for producing the same |
-
1992
- 1992-02-17 FR FR9201967A patent/FR2687483A1/fr active Granted
-
1993
- 1993-02-08 WO PCT/EP1993/000290 patent/WO1993016401A1/en not_active Ceased
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0254949A2 (de) * | 1986-07-23 | 1988-02-03 | MERCK PATENT GmbH | Orientierte Polymermaterialien |
| WO1988002131A1 (en) * | 1986-09-19 | 1988-03-24 | Aktieselskabet Nordiske Kabel- Og Traadfabriker | A process for producing an electrooptical material having controllable-properties, and use of the material in electrooptical components |
| US4877298A (en) * | 1987-02-26 | 1989-10-31 | Hoechst Celanese Corporation | Thin film waveguide electrooptic modulator |
| EP0293870A1 (en) * | 1987-06-03 | 1988-12-07 | Kuraray Co., Ltd. | Method for electric field orientation of liquid crystal polymers and oriented materials of liquid crystal polymers obtained by the method |
| EP0406888A2 (en) * | 1989-07-07 | 1991-01-09 | Sumitomo Electric Industries, Ltd. | Nonlinear optical polymer composition and method for producing the same |
Non-Patent Citations (1)
| Title |
|---|
| APPLIED PHYSICS LETTERS vol. 56, no. 26, 25 Juin 1990, pages 2610 - 2612 D. JUNGBAUER 'highly efficient and stable nonlinear optical polymers via chemical crosslinking under electric field' * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1993016401A1 (en) | 1993-08-19 |
| FR2687483B1 (https=) | 1995-01-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |