FR2670212A1 - Nouveaux electrolytes a base de polyorganosiloxanes sulfones, leur preparation et leur application comme conducteurs ioniques solides. - Google Patents

Nouveaux electrolytes a base de polyorganosiloxanes sulfones, leur preparation et leur application comme conducteurs ioniques solides. Download PDF

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Publication number
FR2670212A1
FR2670212A1 FR9015219A FR9015219A FR2670212A1 FR 2670212 A1 FR2670212 A1 FR 2670212A1 FR 9015219 A FR9015219 A FR 9015219A FR 9015219 A FR9015219 A FR 9015219A FR 2670212 A1 FR2670212 A1 FR 2670212A1
Authority
FR
France
Prior art keywords
polyorganosiloxane
group
units
silicon
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR9015219A
Other languages
English (en)
French (fr)
Other versions
FR2670212B1 (enExample
Inventor
Poinsignon Christiane
Denoyelle Alain
Sanchez Jean-Yves
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique
Original Assignee
Centre National de la Recherche Scientifique
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique filed Critical Centre National de la Recherche Scientifique
Priority to FR9015219A priority Critical patent/FR2670212A1/fr
Priority to PCT/FR1991/000974 priority patent/WO1992010528A1/fr
Priority to EP92901756A priority patent/EP0560899B1/fr
Priority to DE69110057T priority patent/DE69110057D1/de
Publication of FR2670212A1 publication Critical patent/FR2670212A1/fr
Application granted granted Critical
Publication of FR2670212B1 publication Critical patent/FR2670212B1/fr
Granted legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/70—Polymers having silicon in the main chain, with or without sulfur, nitrogen, oxygen or carbon only
    • B01D71/702—Polysilsesquioxanes or combination of silica with bridging organosilane groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/28—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen sulfur-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/392—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing sulfur
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/122—Ionic conductors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/48—Conductive polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/54—Electrolytes
    • H01G11/56—Solid electrolytes, e.g. gels; Additives therein
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0289—Means for holding the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1523—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material
    • G02F1/1525—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material characterised by a particular ion transporting layer, e.g. electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Power Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Silicon Polymers (AREA)
  • Conductive Materials (AREA)
FR9015219A 1990-12-05 1990-12-05 Nouveaux electrolytes a base de polyorganosiloxanes sulfones, leur preparation et leur application comme conducteurs ioniques solides. Granted FR2670212A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR9015219A FR2670212A1 (fr) 1990-12-05 1990-12-05 Nouveaux electrolytes a base de polyorganosiloxanes sulfones, leur preparation et leur application comme conducteurs ioniques solides.
PCT/FR1991/000974 WO1992010528A1 (fr) 1990-12-05 1991-12-05 Membranes a base de polyorganosiloxanes sulfones, leur preparation et leur application comme conducteurs ioniques solides
EP92901756A EP0560899B1 (fr) 1990-12-05 1991-12-05 Membranes a base de polyorganosiloxanes sulfones, leur preparation et leur application comme conducteurs ioniques solides
DE69110057T DE69110057D1 (de) 1990-12-05 1991-12-05 Membranen auf basis von sulfonierten polyorganosiloxanen, deren herstellung und deren anwendung als feste ionenleiter.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9015219A FR2670212A1 (fr) 1990-12-05 1990-12-05 Nouveaux electrolytes a base de polyorganosiloxanes sulfones, leur preparation et leur application comme conducteurs ioniques solides.

Publications (2)

Publication Number Publication Date
FR2670212A1 true FR2670212A1 (fr) 1992-06-12
FR2670212B1 FR2670212B1 (enExample) 1995-02-24

Family

ID=9402914

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9015219A Granted FR2670212A1 (fr) 1990-12-05 1990-12-05 Nouveaux electrolytes a base de polyorganosiloxanes sulfones, leur preparation et leur application comme conducteurs ioniques solides.

Country Status (4)

Country Link
EP (1) EP0560899B1 (enExample)
DE (1) DE69110057D1 (enExample)
FR (1) FR2670212A1 (enExample)
WO (1) WO1992010528A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1323767A3 (de) * 2001-12-21 2003-08-27 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Protonenleitfähige Membranen/Schichten und Verfahren zu deren Herstellung
DE102004023586A1 (de) * 2004-05-13 2005-12-08 Universität Bremen Protonenleitfähiges, vernetztes Heteropolysiloxan, protonenleitfähige Membran und Verfahren zu deren Herstellung

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4223539C1 (de) * 1992-07-17 1993-11-25 Degussa Geformte Sulfonatgruppen-haltige Organopolysiloxane, Verfahren zu ihrer Herstellung und Verwendung
FR2789230B3 (fr) * 1999-01-29 2001-03-02 Recupyl Sa BATTERIE Mn02/Zn EN FILM MINCE A ELECTROLYTE POLYMERE CONDUCTEUR PROTONIQUE DE HAUTE DENSITE D'ENERGIE ET SON MODE DE REALISATION
JP3922162B2 (ja) * 2002-11-08 2007-05-30 トヨタ自動車株式会社 プロトン伝導材料
TWI269478B (en) * 2003-02-06 2006-12-21 Sekisui Chemical Co Ltd Proton conducting membrane, method for producing the same and fuel cell using the same
US7799276B2 (en) 2003-10-27 2010-09-21 Michigan Molecular Institute Functionalized particles for composite sensors

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2955128A (en) * 1958-12-31 1960-10-04 Union Carbide Corp Chlorosulfonylalkyl silicon compounds
US2968643A (en) * 1958-12-31 1961-01-17 Union Carbide Corp Sulfo-aralkylsiloxanes and salts thereof
US3215643A (en) * 1961-11-24 1965-11-02 Dow Corning Use of sulfur-containing siloxanes as solvent foamers
GB1451726A (en) * 1973-11-16 1976-10-06 Merck Patent Gmbh Preparation of organic-modified silicon dioxides
FR2413416A1 (fr) * 1977-12-28 1979-07-27 Fraunhofer Ges Forschung Heteropolycondensats siliciques utilisables comme membranes et adsorbants
EP0098946A2 (de) * 1982-07-13 1984-01-25 Degussa Aktiengesellschaft Sulfonatgruppen-haltige Organopolysiloxane, Verfahren zu ihrer Herstellung und Verwendung

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2955128A (en) * 1958-12-31 1960-10-04 Union Carbide Corp Chlorosulfonylalkyl silicon compounds
US2968643A (en) * 1958-12-31 1961-01-17 Union Carbide Corp Sulfo-aralkylsiloxanes and salts thereof
US3215643A (en) * 1961-11-24 1965-11-02 Dow Corning Use of sulfur-containing siloxanes as solvent foamers
GB1451726A (en) * 1973-11-16 1976-10-06 Merck Patent Gmbh Preparation of organic-modified silicon dioxides
FR2413416A1 (fr) * 1977-12-28 1979-07-27 Fraunhofer Ges Forschung Heteropolycondensats siliciques utilisables comme membranes et adsorbants
EP0098946A2 (de) * 1982-07-13 1984-01-25 Degussa Aktiengesellschaft Sulfonatgruppen-haltige Organopolysiloxane, Verfahren zu ihrer Herstellung und Verwendung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
STUDIES IN SURFACE SCIENCE AND CATALYSIS, vol. 20, (Catalysis by acids and bases), 1985, pages 383-390, Amsterdam, NL; A. SAUS et al.: "Alkylation of benzene with propene on benzyl sulfonic acid siloxane catalysts" *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1323767A3 (de) * 2001-12-21 2003-08-27 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Protonenleitfähige Membranen/Schichten und Verfahren zu deren Herstellung
DE102004023586A1 (de) * 2004-05-13 2005-12-08 Universität Bremen Protonenleitfähiges, vernetztes Heteropolysiloxan, protonenleitfähige Membran und Verfahren zu deren Herstellung

Also Published As

Publication number Publication date
FR2670212B1 (enExample) 1995-02-24
EP0560899B1 (fr) 1995-05-24
WO1992010528A1 (fr) 1992-06-25
EP0560899A1 (fr) 1993-09-22
DE69110057D1 (de) 1995-06-29

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