FR2655350A1 - Procede de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules. - Google Patents
Procede de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules. Download PDFInfo
- Publication number
- FR2655350A1 FR2655350A1 FR8916021A FR8916021A FR2655350A1 FR 2655350 A1 FR2655350 A1 FR 2655350A1 FR 8916021 A FR8916021 A FR 8916021A FR 8916021 A FR8916021 A FR 8916021A FR 2655350 A1 FR2655350 A1 FR 2655350A1
- Authority
- FR
- France
- Prior art keywords
- bed
- particles
- reaction
- catalyst
- reaction zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 34
- 239000002245 particle Substances 0.000 title claims abstract description 34
- 150000004945 aromatic hydrocarbons Chemical class 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 title claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 71
- 239000003054 catalyst Substances 0.000 claims abstract description 48
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 6
- 239000000571 coke Substances 0.000 claims abstract description 6
- 238000007654 immersion Methods 0.000 claims abstract description 3
- 230000008929 regeneration Effects 0.000 claims description 49
- 238000011069 regeneration method Methods 0.000 claims description 49
- 239000007789 gas Substances 0.000 claims description 30
- 238000005243 fluidization Methods 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 9
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052733 gallium Inorganic materials 0.000 claims description 5
- 238000002347 injection Methods 0.000 claims description 4
- 239000007924 injection Substances 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 230000002093 peripheral effect Effects 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 230000001172 regenerating effect Effects 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 6
- 239000010457 zeolite Substances 0.000 abstract description 6
- 229910021536 Zeolite Inorganic materials 0.000 abstract description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract description 3
- 239000008096 xylene Substances 0.000 abstract description 2
- 150000003738 xylenes Chemical class 0.000 abstract description 2
- 239000004576 sand Substances 0.000 description 9
- 238000012546 transfer Methods 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000000446 fuel Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000005899 aromatization reaction Methods 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 235000011160 magnesium carbonates Nutrition 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00026—Controlling or regulating the heat exchange system
- B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
- B01J2208/00088—Flow rate measurement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00477—Controlling the temperature by thermal insulation means
- B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00504—Controlling the temperature by means of a burner
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8916021A FR2655350A1 (fr) | 1989-12-01 | 1989-12-01 | Procede de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules. |
| EP90403375A EP0430804B1 (fr) | 1989-12-01 | 1990-11-28 | Procédé et dispositif de production d'hydrocarbures à partir d'une charge d'hydrocarbures aliphatiques dans un réacteur chauffé par un lit fluidisé de particules |
| DE69016952T DE69016952T2 (de) | 1989-12-01 | 1990-11-28 | Verfahren und Apparat für die Umwandlung von aromatischen Kohlenwasserstoffen aus aliphatischen Kohlenwasserstoffeinsätzen in einem mit fluidisierten Teilchen geheizten Reaktor. |
| NO905165A NO180782C (no) | 1989-12-01 | 1990-11-29 | Fremgangsmåte og apparat med fluidisert sjikt for fremstilling av aromatiske hydrokarboner fra alifatiske hydrokarboner, samt anvendelse av apparatet |
| AU67639/90A AU650434B2 (en) | 1989-12-01 | 1990-11-29 | Process and apparatus for the production of aromatic hydrocarbons from an aliphatic hydrocarbon charge in a reactor heated by a fluidized particle bed |
| ZA909634A ZA909634B (en) | 1989-12-01 | 1990-11-30 | Process and apparatus for the production of aromatic hydrocarbons from an aliphatic hydrocarbon charge in a reactor heated by a fluidized particle bed |
| MYPI90002115A MY108677A (en) | 1989-12-01 | 1990-11-30 | Process and apparatus for the production of aromatic hydrocarbons from an aliphatic hydrocarbon charge in a reactor heated by a fluidized particle bed. |
| CA002031247A CA2031247A1 (fr) | 1989-12-01 | 1990-11-30 | Procede et dispositif de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules |
| JP2341223A JPH03182591A (ja) | 1989-12-01 | 1990-11-30 | 粒子の流動床によって加熱された反応器における脂肪族炭化水素仕込原料からの芳香族炭化水素の製造方法および装置 |
| CN90110346A CN1033023C (zh) | 1989-12-01 | 1990-12-01 | 在颗粒流化床加热的反应器中用脂族烃料生产芳族烃的方法与设备 |
| KR1019900019755A KR910012202A (ko) | 1989-12-01 | 1990-12-01 | 유동성 입자 베드로 가열되는 반응기에서 지방족 탄화수소 충진물로부터 방향족 탄화수소를 제조하는 방법 및 장치 |
| US07/620,412 US5254765A (en) | 1989-12-01 | 1990-12-03 | Process and apparatus for the production of aromatic hydrocarbons from an aliphatic hydrocarbon charge in a reactor heated by a fluidized particle bed |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8916021A FR2655350A1 (fr) | 1989-12-01 | 1989-12-01 | Procede de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2655350A1 true FR2655350A1 (fr) | 1991-06-07 |
| FR2655350B1 FR2655350B1 (enrdf_load_stackoverflow) | 1994-04-22 |
Family
ID=9388140
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8916021A Granted FR2655350A1 (fr) | 1989-12-01 | 1989-12-01 | Procede de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules. |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR2655350A1 (enrdf_load_stackoverflow) |
| ZA (1) | ZA909634B (enrdf_load_stackoverflow) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2886507A (en) * | 1954-07-07 | 1959-05-12 | Socony Mobil Oil Co Inc | Method of supplying endothermic heat of reaction |
| FR2374283A1 (fr) * | 1976-12-20 | 1978-07-13 | British Petroleum Co | Composition de zeolite modifiee et son application a la production d'hydrocarbures aromatiques a partir d'hydrocarbures aliphatiques |
| US4224298A (en) * | 1977-04-14 | 1980-09-23 | Robinson Lee F | Reforming of hydrocarbons |
| FR2531944A1 (fr) * | 1982-08-12 | 1984-02-24 | Mitsubishi Heavy Ind Ltd | Appareil de reforming de combustible a base d'hydrocarbure en un gaz riche en hydrogene |
| EP0309219A1 (en) * | 1987-09-25 | 1989-03-29 | Mobil Oil Corporation | Hydrogen reactivation of zeolite cracking and conversion catalysts |
-
1989
- 1989-12-01 FR FR8916021A patent/FR2655350A1/fr active Granted
-
1990
- 1990-11-30 ZA ZA909634A patent/ZA909634B/xx unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2886507A (en) * | 1954-07-07 | 1959-05-12 | Socony Mobil Oil Co Inc | Method of supplying endothermic heat of reaction |
| FR2374283A1 (fr) * | 1976-12-20 | 1978-07-13 | British Petroleum Co | Composition de zeolite modifiee et son application a la production d'hydrocarbures aromatiques a partir d'hydrocarbures aliphatiques |
| US4224298A (en) * | 1977-04-14 | 1980-09-23 | Robinson Lee F | Reforming of hydrocarbons |
| FR2531944A1 (fr) * | 1982-08-12 | 1984-02-24 | Mitsubishi Heavy Ind Ltd | Appareil de reforming de combustible a base d'hydrocarbure en un gaz riche en hydrogene |
| EP0309219A1 (en) * | 1987-09-25 | 1989-03-29 | Mobil Oil Corporation | Hydrogen reactivation of zeolite cracking and conversion catalysts |
Also Published As
| Publication number | Publication date |
|---|---|
| ZA909634B (en) | 1992-10-28 |
| FR2655350B1 (enrdf_load_stackoverflow) | 1994-04-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |
Effective date: 20060831 |