FR2541309A1 - Procede pour le traitement d'une scorie siderurgique contenant des composes oxydes du sodium et du phosphore - Google Patents
Procede pour le traitement d'une scorie siderurgique contenant des composes oxydes du sodium et du phosphore Download PDFInfo
- Publication number
- FR2541309A1 FR2541309A1 FR8303061A FR8303061A FR2541309A1 FR 2541309 A1 FR2541309 A1 FR 2541309A1 FR 8303061 A FR8303061 A FR 8303061A FR 8303061 A FR8303061 A FR 8303061A FR 2541309 A1 FR2541309 A1 FR 2541309A1
- Authority
- FR
- France
- Prior art keywords
- sodium
- slag
- aqueous solution
- process according
- sodium phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 49
- 239000002893 slag Substances 0.000 title claims abstract description 43
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims description 13
- 150000001875 compounds Chemical class 0.000 title claims description 13
- 229910052708 sodium Inorganic materials 0.000 title claims description 13
- 239000011734 sodium Substances 0.000 title claims description 13
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims description 10
- 229910052698 phosphorus Inorganic materials 0.000 title claims description 10
- 239000011574 phosphorus Substances 0.000 title claims description 10
- 238000009628 steelmaking Methods 0.000 title description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 70
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 33
- 229910000162 sodium phosphate Inorganic materials 0.000 claims abstract description 33
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims abstract description 33
- 239000007864 aqueous solution Substances 0.000 claims abstract description 30
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 26
- 239000000243 solution Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 9
- 239000001569 carbon dioxide Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 239000012452 mother liquor Substances 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 4
- -1 hydroxyl ions Chemical class 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 2
- 238000003723 Smelting Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 239000010959 steel Substances 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 8
- 239000007900 aqueous suspension Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000013078 crystal Substances 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 229910001018 Cast iron Inorganic materials 0.000 description 4
- 239000002198 insoluble material Substances 0.000 description 4
- 150000003388 sodium compounds Chemical class 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 229910001208 Crucible steel Inorganic materials 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 238000010908 decantation Methods 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- ASTWEMOBIXQPPV-UHFFFAOYSA-K trisodium;phosphate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O ASTWEMOBIXQPPV-UHFFFAOYSA-K 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- XYQRXRFVKUPBQN-UHFFFAOYSA-L Sodium carbonate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]C([O-])=O XYQRXRFVKUPBQN-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 150000004691 decahydrates Chemical class 0.000 description 1
- 238000005261 decarburization Methods 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- HDFXRQJQZBPDLF-UHFFFAOYSA-L disodium hydrogen carbonate Chemical compound [Na+].[Na+].OC([O-])=O.OC([O-])=O HDFXRQJQZBPDLF-UHFFFAOYSA-L 0.000 description 1
- GLYUSNXFOHTZTE-UHFFFAOYSA-L disodium;carbonate;heptahydrate Chemical compound O.O.O.O.O.O.O.[Na+].[Na+].[O-]C([O-])=O GLYUSNXFOHTZTE-UHFFFAOYSA-L 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 150000004688 heptahydrates Chemical class 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 238000010591 solubility diagram Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- BDSZAZGGHNKJCT-UHFFFAOYSA-J tetrasodium dihydrogen phosphate carbonate hydroxide Chemical compound [OH-].[Na+].P(=O)(O)([O-])[O-].[Na+].[Na+].C([O-])(O)=O.[Na+] BDSZAZGGHNKJCT-UHFFFAOYSA-J 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B3/00—General features in the manufacture of pig-iron
- C21B3/04—Recovery of by-products, e.g. slag
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/30—Alkali metal phosphates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Processing Of Solid Wastes (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8303061A FR2541309A1 (fr) | 1983-02-22 | 1983-02-22 | Procede pour le traitement d'une scorie siderurgique contenant des composes oxydes du sodium et du phosphore |
| LU85194A LU85194A1 (fr) | 1983-02-22 | 1984-02-03 | Procede pour le traitement d'une scorie siderurgique contenant des composes oxydes du sodium et du phosphore |
| BE1/10962A BE898920A (fr) | 1983-02-22 | 1984-02-16 | Procede pour le traitement d'une scorie siderurgique contenant des composes oxydes du sodium et du phosphore |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8303061A FR2541309A1 (fr) | 1983-02-22 | 1983-02-22 | Procede pour le traitement d'une scorie siderurgique contenant des composes oxydes du sodium et du phosphore |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2541309A1 true FR2541309A1 (fr) | 1984-08-24 |
| FR2541309B1 FR2541309B1 (cs) | 1985-04-26 |
Family
ID=9286240
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8303061A Granted FR2541309A1 (fr) | 1983-02-22 | 1983-02-22 | Procede pour le traitement d'une scorie siderurgique contenant des composes oxydes du sodium et du phosphore |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE898920A (cs) |
| FR (1) | FR2541309A1 (cs) |
| LU (1) | LU85194A1 (cs) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0263559A1 (de) * | 1986-10-08 | 1988-04-13 | Metallgesellschaft Ag | Verfahren zur Aufarbeitung von Sodaschlacken aus der Entschwefelung von Roheisen |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3220795A (en) * | 1962-07-18 | 1965-11-30 | Hooker Chemical Corp | Treatment of ferrophosphorus |
| DE1934308A1 (de) * | 1969-07-07 | 1971-02-11 | Kloeckner Humboldt Deutz Ag | Verfahren zur Verwertung von Sodaschlacke |
| BE868298A (fr) * | 1978-06-20 | 1978-10-16 | Centre Rech Metallurgique | Procede de traitement de scories d'acierie |
| FR2415612A1 (fr) * | 1978-01-26 | 1979-08-24 | Tokuyama Soda Kk | Procede de traitement de scories residuaires |
| BE889362A (fr) * | 1981-06-24 | 1981-12-28 | Potasco Sa | Procede et installation de fabrication de scories phosphatees |
-
1983
- 1983-02-22 FR FR8303061A patent/FR2541309A1/fr active Granted
-
1984
- 1984-02-03 LU LU85194A patent/LU85194A1/fr unknown
- 1984-02-16 BE BE1/10962A patent/BE898920A/fr not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3220795A (en) * | 1962-07-18 | 1965-11-30 | Hooker Chemical Corp | Treatment of ferrophosphorus |
| DE1934308A1 (de) * | 1969-07-07 | 1971-02-11 | Kloeckner Humboldt Deutz Ag | Verfahren zur Verwertung von Sodaschlacke |
| FR2415612A1 (fr) * | 1978-01-26 | 1979-08-24 | Tokuyama Soda Kk | Procede de traitement de scories residuaires |
| BE868298A (fr) * | 1978-06-20 | 1978-10-16 | Centre Rech Metallurgique | Procede de traitement de scories d'acierie |
| BE889362A (fr) * | 1981-06-24 | 1981-12-28 | Potasco Sa | Procede et installation de fabrication de scories phosphatees |
Non-Patent Citations (1)
| Title |
|---|
| REVUE DE METALLURGIE-CIT, juillet 1981, Paris (FR) * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0263559A1 (de) * | 1986-10-08 | 1988-04-13 | Metallgesellschaft Ag | Verfahren zur Aufarbeitung von Sodaschlacken aus der Entschwefelung von Roheisen |
Also Published As
| Publication number | Publication date |
|---|---|
| LU85194A1 (fr) | 1984-11-08 |
| FR2541309B1 (cs) | 1985-04-26 |
| BE898920A (fr) | 1984-08-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |