FR2531944A1 - Appareil de reforming de combustible a base d'hydrocarbure en un gaz riche en hydrogene - Google Patents
Appareil de reforming de combustible a base d'hydrocarbure en un gaz riche en hydrogene Download PDFInfo
- Publication number
- FR2531944A1 FR2531944A1 FR8313260A FR8313260A FR2531944A1 FR 2531944 A1 FR2531944 A1 FR 2531944A1 FR 8313260 A FR8313260 A FR 8313260A FR 8313260 A FR8313260 A FR 8313260A FR 2531944 A1 FR2531944 A1 FR 2531944A1
- Authority
- FR
- France
- Prior art keywords
- catalyst
- fuel
- tubes
- gas
- reforming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 111
- 238000002407 reforming Methods 0.000 title claims abstract description 110
- 229930195733 hydrocarbon Natural products 0.000 title description 6
- 150000002430 hydrocarbons Chemical class 0.000 title description 6
- 239000004215 Carbon black (E152) Substances 0.000 title description 5
- 239000003054 catalyst Substances 0.000 claims abstract description 94
- 239000007789 gas Substances 0.000 claims abstract description 94
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 21
- 239000001257 hydrogen Substances 0.000 claims abstract description 21
- 238000002485 combustion reaction Methods 0.000 claims description 34
- 238000010438 heat treatment Methods 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 20
- 239000000567 combustion gas Substances 0.000 claims description 19
- 238000004064 recycling Methods 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 2
- 230000001737 promoting effect Effects 0.000 claims description 2
- 239000000470 constituent Substances 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000001131 transforming effect Effects 0.000 abstract description 2
- 238000010276 construction Methods 0.000 abstract 1
- 238000012423 maintenance Methods 0.000 abstract 1
- 238000000629 steam reforming Methods 0.000 description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
- 239000000203 mixture Substances 0.000 description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 15
- 229910052799 carbon Inorganic materials 0.000 description 14
- 239000012530 fluid Substances 0.000 description 13
- 238000009826 distribution Methods 0.000 description 12
- 239000003546 flue gas Substances 0.000 description 9
- 238000011084 recovery Methods 0.000 description 9
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000011819 refractory material Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000005243 fluidization Methods 0.000 description 4
- 238000009434 installation Methods 0.000 description 4
- 238000005070 sampling Methods 0.000 description 4
- 238000007664 blowing Methods 0.000 description 3
- 229960004424 carbon dioxide Drugs 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
- 238000006057 reforming reaction Methods 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 230000008646 thermal stress Effects 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 206010022000 influenza Diseases 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- HBVFXTAPOLSOPB-UHFFFAOYSA-N nickel vanadium Chemical compound [V].[Ni] HBVFXTAPOLSOPB-UHFFFAOYSA-N 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- -1 oxy- Chemical class 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57140137A JPS5930705A (ja) | 1982-08-12 | 1982-08-12 | 燃料改質装置 |
| JP20858082A JPS59102803A (ja) | 1982-11-30 | 1982-11-30 | 燃料改質装置 |
| JP20857982A JPS59102802A (ja) | 1982-11-30 | 1982-11-30 | 燃料組成変換装置 |
| JP20931082A JPS59102804A (ja) | 1982-12-01 | 1982-12-01 | 燃料改質装置 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2531944A1 true FR2531944A1 (fr) | 1984-02-24 |
| FR2531944B1 FR2531944B1 (enrdf_load_stackoverflow) | 1985-04-19 |
Family
ID=27472285
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8313260A Granted FR2531944A1 (fr) | 1982-08-12 | 1983-08-12 | Appareil de reforming de combustible a base d'hydrocarbure en un gaz riche en hydrogene |
Country Status (6)
| Country | Link |
|---|---|
| CH (1) | CH655495B (enrdf_load_stackoverflow) |
| DE (1) | DE3329435A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2531944A1 (enrdf_load_stackoverflow) |
| GB (1) | GB2126118B (enrdf_load_stackoverflow) |
| MX (1) | MX168335B (enrdf_load_stackoverflow) |
| NL (1) | NL189123C (enrdf_load_stackoverflow) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0430804A1 (fr) * | 1989-12-01 | 1991-06-05 | Institut Français du Pétrole | Procédé et dispositif de production d'hydrocarbures à partir d'une charge d'hydrocarbures aliphatiques dans un réacteur chauffé par un lit fluidisé de particules |
| FR2655351A1 (fr) * | 1989-12-01 | 1991-06-07 | Inst Francais Du Petrole | Dispositif de conversion d'hydrocarbures dans un reacteur chauffe par un lit fluidise de particules et son utilisation. |
| FR2655350A1 (fr) * | 1989-12-01 | 1991-06-07 | Inst Francais Du Petrole | Procede de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules. |
| EP0342918A3 (en) * | 1988-05-17 | 1991-10-30 | Ube Industries, Ltd. | Fluidized bed apparatus |
| WO1996015850A1 (en) * | 1994-11-17 | 1996-05-30 | International Fuel Cells Corporation | Catalytic reactor designed to reduce catalyst slumping and crushing |
| US11351517B2 (en) * | 2016-09-14 | 2022-06-07 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Reformer tube having a structured catalyst and improved heat balance |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4557904A (en) * | 1984-03-26 | 1985-12-10 | Union Carbide Corporation | Integral reactor apparatus |
| US4861348A (en) * | 1986-10-08 | 1989-08-29 | Hitachi, Ltd. | Fuel reforming apparatus |
| GB2201903B (en) * | 1987-03-03 | 1990-11-28 | Shell Int Research | Apparatus and process suitable for producing hydrogen |
| US4792436A (en) * | 1987-05-08 | 1988-12-20 | Kinetics Technology International | Hydrocarbon converter furnace |
| DE4327176C1 (de) * | 1993-08-13 | 1995-01-26 | Metallgesellschaft Ag | Röhrenofen für die Erzeugung kohlenmonoxidhaltiger Gasgemische |
| DE19955676B4 (de) * | 1999-11-19 | 2004-06-03 | Uhde Gmbh | Verfahren zur Herstellung von Synthesegas in Verbindung mit einer Druckwechsel-Adsorptionsanlage |
| US20030061764A1 (en) * | 2001-10-01 | 2003-04-03 | Belhocine Benallal | Method and apparatus for steam reforming of hydrocarbons |
| DE102006046052B3 (de) * | 2006-09-28 | 2008-03-27 | Green Vision Holding B.V. | Herausschiebbarer Dampfreformer |
| EP2314543A1 (en) * | 2009-10-22 | 2011-04-27 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method for reducing the capacity of a steam reformer and reduced-capacity reformer |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE674656A (enrdf_load_stackoverflow) * | 1964-12-31 | 1966-06-30 | ||
| FR1571968A (enrdf_load_stackoverflow) * | 1967-07-15 | 1969-06-20 | ||
| US3980452A (en) * | 1973-09-14 | 1976-09-14 | Metallgesellschaft Aktiengesellschaft | Process for supplying heat to chemical reactions |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1579577A (en) * | 1977-04-14 | 1980-11-19 | Robinson L F | Reforming of hydrocarbons |
| NZ194405A (en) * | 1979-08-02 | 1982-05-25 | Dut Pty Ltd | Producing liquid hydrocarbon streams by hydrogenation of fossil-based feedstock |
-
1983
- 1983-08-10 MX MX198347A patent/MX168335B/es unknown
- 1983-08-11 NL NLAANVRAGE8302824,A patent/NL189123C/xx not_active IP Right Cessation
- 1983-08-12 CH CH442783A patent/CH655495B/de not_active IP Right Cessation
- 1983-08-12 DE DE19833329435 patent/DE3329435A1/de not_active Ceased
- 1983-08-12 GB GB08321739A patent/GB2126118B/en not_active Expired
- 1983-08-12 FR FR8313260A patent/FR2531944A1/fr active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE674656A (enrdf_load_stackoverflow) * | 1964-12-31 | 1966-06-30 | ||
| FR1571968A (enrdf_load_stackoverflow) * | 1967-07-15 | 1969-06-20 | ||
| US3980452A (en) * | 1973-09-14 | 1976-09-14 | Metallgesellschaft Aktiengesellschaft | Process for supplying heat to chemical reactions |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0342918A3 (en) * | 1988-05-17 | 1991-10-30 | Ube Industries, Ltd. | Fluidized bed apparatus |
| EP0430804A1 (fr) * | 1989-12-01 | 1991-06-05 | Institut Français du Pétrole | Procédé et dispositif de production d'hydrocarbures à partir d'une charge d'hydrocarbures aliphatiques dans un réacteur chauffé par un lit fluidisé de particules |
| FR2655351A1 (fr) * | 1989-12-01 | 1991-06-07 | Inst Francais Du Petrole | Dispositif de conversion d'hydrocarbures dans un reacteur chauffe par un lit fluidise de particules et son utilisation. |
| FR2655350A1 (fr) * | 1989-12-01 | 1991-06-07 | Inst Francais Du Petrole | Procede de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules. |
| US5254765A (en) * | 1989-12-01 | 1993-10-19 | Institut Francais Du Petrole | Process and apparatus for the production of aromatic hydrocarbons from an aliphatic hydrocarbon charge in a reactor heated by a fluidized particle bed |
| WO1996015850A1 (en) * | 1994-11-17 | 1996-05-30 | International Fuel Cells Corporation | Catalytic reactor designed to reduce catalyst slumping and crushing |
| US11351517B2 (en) * | 2016-09-14 | 2022-06-07 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Reformer tube having a structured catalyst and improved heat balance |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2531944B1 (enrdf_load_stackoverflow) | 1985-04-19 |
| GB8321739D0 (en) | 1983-09-14 |
| NL8302824A (nl) | 1984-03-01 |
| CH655495B (enrdf_load_stackoverflow) | 1986-04-30 |
| MX168335B (es) | 1993-05-17 |
| NL189123B (nl) | 1992-08-17 |
| NL189123C (nl) | 1993-01-18 |
| GB2126118A (en) | 1984-03-21 |
| GB2126118B (en) | 1986-09-10 |
| DE3329435A1 (de) | 1984-04-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| DL | Decision of the director general to leave to make available licences of right | ||
| ST | Notification of lapse |