FR2521448A1 - Procede pour l'hydrodesulfuration de gaz naturel contenant des composes organiques du soufre et de l'oxygene - Google Patents
Procede pour l'hydrodesulfuration de gaz naturel contenant des composes organiques du soufre et de l'oxygene Download PDFInfo
- Publication number
- FR2521448A1 FR2521448A1 FR8202550A FR8202550A FR2521448A1 FR 2521448 A1 FR2521448 A1 FR 2521448A1 FR 8202550 A FR8202550 A FR 8202550A FR 8202550 A FR8202550 A FR 8202550A FR 2521448 A1 FR2521448 A1 FR 2521448A1
- Authority
- FR
- France
- Prior art keywords
- sulfur
- natural gas
- hydrogen
- gas
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000003345 natural gas Substances 0.000 title claims abstract description 14
- 150000002898 organic sulfur compounds Chemical class 0.000 title claims description 5
- 150000002927 oxygen compounds Chemical class 0.000 title 1
- 239000003054 catalyst Substances 0.000 claims abstract description 27
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 15
- 239000001257 hydrogen Substances 0.000 claims abstract description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 13
- 239000001301 oxygen Substances 0.000 claims abstract description 13
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 12
- 239000011593 sulfur Substances 0.000 claims abstract description 12
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 9
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims abstract description 6
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 125000001741 organic sulfur group Chemical group 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 230000009466 transformation Effects 0.000 abstract description 4
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 8
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000002941 palladium compounds Chemical class 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- JKDRQYIYVJVOPF-FDGPNNRMSA-L palladium(ii) acetylacetonate Chemical compound [Pd+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O JKDRQYIYVJVOPF-FDGPNNRMSA-L 0.000 description 1
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- VRRFSFYSLSPWQY-UHFFFAOYSA-N sulfanylidenecobalt Chemical class [Co]=S VRRFSFYSLSPWQY-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8202550A FR2521448A1 (fr) | 1982-02-15 | 1982-02-15 | Procede pour l'hydrodesulfuration de gaz naturel contenant des composes organiques du soufre et de l'oxygene |
| US06/466,690 US4460553A (en) | 1982-02-15 | 1983-02-15 | Process for the hydrodesulfurization of natural gas containing organic sulfur compounds and oxygen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8202550A FR2521448A1 (fr) | 1982-02-15 | 1982-02-15 | Procede pour l'hydrodesulfuration de gaz naturel contenant des composes organiques du soufre et de l'oxygene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2521448A1 true FR2521448A1 (fr) | 1983-08-19 |
| FR2521448B1 FR2521448B1 (https=) | 1984-04-20 |
Family
ID=9271046
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8202550A Granted FR2521448A1 (fr) | 1982-02-15 | 1982-02-15 | Procede pour l'hydrodesulfuration de gaz naturel contenant des composes organiques du soufre et de l'oxygene |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4460553A (https=) |
| FR (1) | FR2521448A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4505880A (en) * | 1982-05-25 | 1985-03-19 | Institut Francais Du Petrole | Process for the hydrodesulfurization and deoxygenation of a gas containing oxygen and organic sulfur compounds |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5010049A (en) * | 1989-03-24 | 1991-04-23 | The Regents Of The University Of Michigan | Modified molybdenum sulfide hydrodesulfurization/hydrodenitrogenation catalysts |
| US5849256A (en) * | 1996-04-26 | 1998-12-15 | Engelhard Corporation | Method for oxidizing carbon monoxide in a gas stream containing oxidizable sulphur compounds |
| EP1063010B1 (en) * | 1998-03-09 | 2008-07-02 | Osaka Gas Company Limited | Method for removing methane from exhaust gas |
| US6812179B2 (en) * | 2001-04-25 | 2004-11-02 | Syntroleum Corporation | Process for regenerating a slurry fischer-tropsch catalyst |
| US20020159939A1 (en) * | 2001-04-27 | 2002-10-31 | Plug Power Inc. | Gas purification system |
| US20070154742A1 (en) * | 2005-12-29 | 2007-07-05 | Hao Tang | Starting up and shutting down a fuel cell |
| US20070154359A1 (en) * | 2005-12-29 | 2007-07-05 | Parshant Dhand | Conditioning a de-sulfurization system |
| EP2331898B1 (fr) * | 2008-08-04 | 2017-12-27 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Procédé de génération et de séparation d'un mélange d'hydrogène et de monoxyde de carbone par distillation cryogénique |
| CA2709722A1 (en) * | 2010-07-15 | 2012-01-15 | Alakh Prasad | Integrated biogas cleaning a system to remove water, siloxanes, sulfur, oxygen, chlorides, and volatile organic compounds |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2731611A1 (de) * | 1977-07-13 | 1979-01-18 | Ludwig Ofag Indugas Gmbh | Verfahren zum erzeugen weitgehend schwefelfreier brenngase bei der gewinnung von schutzgasen aus schwefelhaltigen rohgasen |
| US4260840A (en) * | 1980-01-11 | 1981-04-07 | Exxon Research & Engineering Co. | Butene-1 containing feed purification process(CS-165) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB340016A (en) * | 1929-09-16 | 1930-12-16 | Ig Farbenindustrie Ag | A process for the catalytic desulphurization of gases |
| US4181503A (en) * | 1978-10-30 | 1980-01-01 | United Technologies Corporation | Process for alternately steam reforming sulfur containing hydrocarbons that vary in oxygen content |
-
1982
- 1982-02-15 FR FR8202550A patent/FR2521448A1/fr active Granted
-
1983
- 1983-02-15 US US06/466,690 patent/US4460553A/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2731611A1 (de) * | 1977-07-13 | 1979-01-18 | Ludwig Ofag Indugas Gmbh | Verfahren zum erzeugen weitgehend schwefelfreier brenngase bei der gewinnung von schutzgasen aus schwefelhaltigen rohgasen |
| US4260840A (en) * | 1980-01-11 | 1981-04-07 | Exxon Research & Engineering Co. | Butene-1 containing feed purification process(CS-165) |
| US4260840B1 (https=) * | 1980-01-11 | 1984-06-12 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4505880A (en) * | 1982-05-25 | 1985-03-19 | Institut Francais Du Petrole | Process for the hydrodesulfurization and deoxygenation of a gas containing oxygen and organic sulfur compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2521448B1 (https=) | 1984-04-20 |
| US4460553A (en) | 1984-07-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| SU1314949A3 (ru) | Способ очистки газов от сернистых соединений | |
| EP0332526B1 (fr) | Procédé pour l'élimination du mercure et éventuellement d'arsenic dans les hydrocarbures | |
| EP0484234B1 (fr) | Procédé d'élimination de mercure et de l'arsenic éventuellement présent dans un fluide, en présence d'une masse de captation de mercure et/ou d'arsenic | |
| CA1220614A (fr) | Procede catalytique de production de soufre a partir d'un gaz renfermant h.sub.2s | |
| US4786402A (en) | Preparation of medicinal white oils and medicinal paraffins | |
| EP2161076B1 (fr) | Procédé d'hydrogénation sélective mettant en oeuvre un catalyseur sulfuré de composition spécifique | |
| CA2211800C (fr) | Procede et catalyseur pour oxyder en soufre par voie catalytique l'h2s contenu en faible concentration dans un gaz | |
| CA1192023A (fr) | Procede pour l'hydrodesulfuration d'un gaz contenant de l'oxygene et des composes organiques du soufre | |
| FR2521448A1 (fr) | Procede pour l'hydrodesulfuration de gaz naturel contenant des composes organiques du soufre et de l'oxygene | |
| FR2511663A1 (fr) | Procede catalytique de production de soufre a partir d'un gaz renfermant h2s | |
| CA2310120C (fr) | Procede pour oxyder directement en soufre, par voie catalytique et en phase vapeur, l'h2s contenu a faible teneur dans un gaz | |
| FR2659570A1 (fr) | Procede de presulfuration de catalyseur de traitement d'hydrocarbures. | |
| WO1994021358A1 (fr) | Procede pour oxyder directement en soufre par voie catalytique, avec une selectivite elevee, l'h2s contenu en faible concentration dans un gaz et catalyseur pour la mise en ×uvre de ce procede | |
| JPH09503695A (ja) | 硫黄化合物を単体硫黄に選択的に酸化するための触媒、その触媒の調製法および硫黄化合物を単体硫黄に選択的に酸化するための方法 | |
| SK282140B6 (sk) | Spôsob katalytickej oxidácie amoniaku na dusík v odpadovom plyne | |
| CA2472916C (fr) | Oxidation directe de composes soufres a moins de 200.degree.c et par catalyseur avec 2% a 5% de fer | |
| EP0207957B1 (fr) | Procede d'elimination des composes cos et cs 2 contenus dans un gaz industriel | |
| NL7905421A (nl) | Werkwijze voor oxydatie van zwavel en zwavel- verbindingen. | |
| DE3049639C2 (de) | Verfahren zur Regenerierung eines rhodium- und aluminiumoxidhaltigen Tr{gerkatalysators | |
| CA1094294A (fr) | Production de soufre | |
| EP0628347A1 (fr) | Nouveau mode de présulfuration de catalyseur | |
| JPS6012905B2 (ja) | メタン化法 | |
| KR102242266B1 (ko) | 수소-풍부 가스로부터 유기 황 화합물을 제거하기 위한 방법 및 장치 | |
| JPS62115089A (ja) | 還元性ガスの製造方法 | |
| JPH0345505A (ja) | 液体硫黄の精製方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |