FR2521448A1 - Procede pour l'hydrodesulfuration de gaz naturel contenant des composes organiques du soufre et de l'oxygene - Google Patents
Procede pour l'hydrodesulfuration de gaz naturel contenant des composes organiques du soufre et de l'oxygene Download PDFInfo
- Publication number
- FR2521448A1 FR2521448A1 FR8202550A FR8202550A FR2521448A1 FR 2521448 A1 FR2521448 A1 FR 2521448A1 FR 8202550 A FR8202550 A FR 8202550A FR 8202550 A FR8202550 A FR 8202550A FR 2521448 A1 FR2521448 A1 FR 2521448A1
- Authority
- FR
- France
- Prior art keywords
- sulfur
- natural gas
- hydrogen
- gas
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000003345 natural gas Substances 0.000 title claims abstract description 14
- 150000002898 organic sulfur compounds Chemical class 0.000 title claims description 5
- 150000002927 oxygen compounds Chemical class 0.000 title 1
- 239000003054 catalyst Substances 0.000 claims abstract description 27
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 15
- 239000001257 hydrogen Substances 0.000 claims abstract description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 13
- 239000001301 oxygen Substances 0.000 claims abstract description 13
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 12
- 239000011593 sulfur Substances 0.000 claims abstract description 12
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 9
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims abstract description 6
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 125000001741 organic sulfur group Chemical group 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 230000009466 transformation Effects 0.000 abstract description 4
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 8
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000002941 palladium compounds Chemical class 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- JKDRQYIYVJVOPF-FDGPNNRMSA-L palladium(ii) acetylacetonate Chemical compound [Pd+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O JKDRQYIYVJVOPF-FDGPNNRMSA-L 0.000 description 1
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- VRRFSFYSLSPWQY-UHFFFAOYSA-N sulfanylidenecobalt Chemical class [Co]=S VRRFSFYSLSPWQY-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8202550A FR2521448A1 (fr) | 1982-02-15 | 1982-02-15 | Procede pour l'hydrodesulfuration de gaz naturel contenant des composes organiques du soufre et de l'oxygene |
| US06/466,690 US4460553A (en) | 1982-02-15 | 1983-02-15 | Process for the hydrodesulfurization of natural gas containing organic sulfur compounds and oxygen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8202550A FR2521448A1 (fr) | 1982-02-15 | 1982-02-15 | Procede pour l'hydrodesulfuration de gaz naturel contenant des composes organiques du soufre et de l'oxygene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2521448A1 true FR2521448A1 (fr) | 1983-08-19 |
| FR2521448B1 FR2521448B1 (OSRAM) | 1984-04-20 |
Family
ID=9271046
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8202550A Granted FR2521448A1 (fr) | 1982-02-15 | 1982-02-15 | Procede pour l'hydrodesulfuration de gaz naturel contenant des composes organiques du soufre et de l'oxygene |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4460553A (OSRAM) |
| FR (1) | FR2521448A1 (OSRAM) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4505880A (en) * | 1982-05-25 | 1985-03-19 | Institut Francais Du Petrole | Process for the hydrodesulfurization and deoxygenation of a gas containing oxygen and organic sulfur compounds |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5010049A (en) * | 1989-03-24 | 1991-04-23 | The Regents Of The University Of Michigan | Modified molybdenum sulfide hydrodesulfurization/hydrodenitrogenation catalysts |
| US5849256A (en) * | 1996-04-26 | 1998-12-15 | Engelhard Corporation | Method for oxidizing carbon monoxide in a gas stream containing oxidizable sulphur compounds |
| DK1063010T3 (da) * | 1998-03-09 | 2008-09-15 | Osaka Gas Co Ltd | Fremgangsmåde til fjernelse af methan fra udstödningsgasser |
| US6812179B2 (en) * | 2001-04-25 | 2004-11-02 | Syntroleum Corporation | Process for regenerating a slurry fischer-tropsch catalyst |
| US20020159939A1 (en) * | 2001-04-27 | 2002-10-31 | Plug Power Inc. | Gas purification system |
| US20070154359A1 (en) * | 2005-12-29 | 2007-07-05 | Parshant Dhand | Conditioning a de-sulfurization system |
| US20070154742A1 (en) * | 2005-12-29 | 2007-07-05 | Hao Tang | Starting up and shutting down a fuel cell |
| CN102132119B (zh) * | 2008-08-04 | 2014-06-04 | 乔治洛德方法研究和开发液化空气有限公司 | 通过低温蒸馏产生和分离氢--一氧化碳混合物的方法 |
| CA2709722A1 (en) * | 2010-07-15 | 2012-01-15 | Alakh Prasad | Integrated biogas cleaning a system to remove water, siloxanes, sulfur, oxygen, chlorides, and volatile organic compounds |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2731611A1 (de) * | 1977-07-13 | 1979-01-18 | Ludwig Ofag Indugas Gmbh | Verfahren zum erzeugen weitgehend schwefelfreier brenngase bei der gewinnung von schutzgasen aus schwefelhaltigen rohgasen |
| US4260840A (en) * | 1980-01-11 | 1981-04-07 | Exxon Research & Engineering Co. | Butene-1 containing feed purification process(CS-165) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB340016A (en) * | 1929-09-16 | 1930-12-16 | Ig Farbenindustrie Ag | A process for the catalytic desulphurization of gases |
| US4181503A (en) * | 1978-10-30 | 1980-01-01 | United Technologies Corporation | Process for alternately steam reforming sulfur containing hydrocarbons that vary in oxygen content |
-
1982
- 1982-02-15 FR FR8202550A patent/FR2521448A1/fr active Granted
-
1983
- 1983-02-15 US US06/466,690 patent/US4460553A/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2731611A1 (de) * | 1977-07-13 | 1979-01-18 | Ludwig Ofag Indugas Gmbh | Verfahren zum erzeugen weitgehend schwefelfreier brenngase bei der gewinnung von schutzgasen aus schwefelhaltigen rohgasen |
| US4260840A (en) * | 1980-01-11 | 1981-04-07 | Exxon Research & Engineering Co. | Butene-1 containing feed purification process(CS-165) |
| US4260840B1 (OSRAM) * | 1980-01-11 | 1984-06-12 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4505880A (en) * | 1982-05-25 | 1985-03-19 | Institut Francais Du Petrole | Process for the hydrodesulfurization and deoxygenation of a gas containing oxygen and organic sulfur compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| US4460553A (en) | 1984-07-17 |
| FR2521448B1 (OSRAM) | 1984-04-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |