FR2511396A1 - Procede de revetement de surfaces metalliques par diffusion d'aluminium pour la protection contre le soufre a haute temperature - Google Patents
Procede de revetement de surfaces metalliques par diffusion d'aluminium pour la protection contre le soufre a haute temperature Download PDFInfo
- Publication number
- FR2511396A1 FR2511396A1 FR8115751A FR8115751A FR2511396A1 FR 2511396 A1 FR2511396 A1 FR 2511396A1 FR 8115751 A FR8115751 A FR 8115751A FR 8115751 A FR8115751 A FR 8115751A FR 2511396 A1 FR2511396 A1 FR 2511396A1
- Authority
- FR
- France
- Prior art keywords
- stainless steel
- aluminum
- titanium
- diffusion
- alumina
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 238000009792 diffusion process Methods 0.000 title claims abstract description 14
- 229910000963 austenitic stainless steel Inorganic materials 0.000 title claims abstract description 6
- 239000005864 Sulphur Substances 0.000 title abstract 3
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 15
- 239000010936 titanium Substances 0.000 claims abstract description 15
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 14
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 12
- 239000000956 alloy Substances 0.000 claims abstract description 12
- 239000010935 stainless steel Substances 0.000 claims abstract description 12
- 238000009434 installation Methods 0.000 claims abstract description 8
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 6
- 239000012190 activator Substances 0.000 claims abstract description 4
- 150000003839 salts Chemical class 0.000 claims abstract description 4
- 239000003245 coal Substances 0.000 claims abstract description 3
- 238000002309 gasification Methods 0.000 claims abstract description 3
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 3
- 229910052735 hafnium Inorganic materials 0.000 claims abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 26
- 239000004568 cement Substances 0.000 claims description 14
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 13
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 239000011593 sulfur Substances 0.000 claims description 12
- 235000019270 ammonium chloride Nutrition 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 238000004174 sulfur cycle Methods 0.000 claims description 4
- 229910000838 Al alloy Inorganic materials 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 239000002344 surface layer Substances 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 abstract description 3
- 239000010959 steel Substances 0.000 abstract description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 238000005260 corrosion Methods 0.000 description 9
- 230000007797 corrosion Effects 0.000 description 9
- 229910017052 cobalt Inorganic materials 0.000 description 6
- 239000010941 cobalt Substances 0.000 description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 229910000601 superalloy Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910001069 Ti alloy Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000004584 weight gain Effects 0.000 description 2
- 235000019786 weight gain Nutrition 0.000 description 2
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 102100033697 DNA cross-link repair 1A protein Human genes 0.000 description 1
- 101000871548 Homo sapiens DNA cross-link repair 1A protein Proteins 0.000 description 1
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 description 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005258 corrosion kinetic Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- -1 hafium Chemical compound 0.000 description 1
- 239000013529 heat transfer fluid Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/28—Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
- C23C10/34—Embedding in a powder mixture, i.e. pack cementation
- C23C10/36—Embedding in a powder mixture, i.e. pack cementation only one element being diffused
- C23C10/48—Aluminising
- C23C10/50—Aluminising of ferrous surfaces
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/28—Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
- C23C10/34—Embedding in a powder mixture, i.e. pack cementation
- C23C10/52—Embedding in a powder mixture, i.e. pack cementation more than one element being diffused in one step
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
- Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8115751A FR2511396A1 (fr) | 1981-08-14 | 1981-08-14 | Procede de revetement de surfaces metalliques par diffusion d'aluminium pour la protection contre le soufre a haute temperature |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8115751A FR2511396A1 (fr) | 1981-08-14 | 1981-08-14 | Procede de revetement de surfaces metalliques par diffusion d'aluminium pour la protection contre le soufre a haute temperature |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2511396A1 true FR2511396A1 (fr) | 1983-02-18 |
| FR2511396B1 FR2511396B1 (enrdf_load_stackoverflow) | 1983-10-28 |
Family
ID=9261481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8115751A Granted FR2511396A1 (fr) | 1981-08-14 | 1981-08-14 | Procede de revetement de surfaces metalliques par diffusion d'aluminium pour la protection contre le soufre a haute temperature |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2511396A1 (enrdf_load_stackoverflow) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0159468A3 (en) * | 1984-04-25 | 1986-05-07 | Interatom Gesellschaft Mit Beschrankter Haftung | Exhaust gas catalyst support made of heat-resistant steel sheets containing aluminium and process for its production |
| EP0222241A1 (en) * | 1985-10-31 | 1987-05-20 | Air Products And Chemicals, Inc. | Deposition of titanium aluminides |
| WO1997041275A1 (en) * | 1996-04-30 | 1997-11-06 | Westaim Technologies Inc. | Surface alloyed high temperature alloys |
| WO1998020182A1 (en) * | 1996-11-08 | 1998-05-14 | Alon, Inc. | Aluminum-silicon diffusion coating |
| US6503347B1 (en) | 1996-04-30 | 2003-01-07 | Surface Engineered Products Corporation | Surface alloyed high temperature alloys |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2097024A (en) * | 1935-11-05 | 1937-10-26 | Enders Walter | Production of a protective layer on iron |
| GB798853A (en) * | 1954-05-31 | 1958-07-30 | Siemens Planiawerke Ag | Improvements in or relating to processes for depositing coatings of aluminium or of aluminium-base alloys on a basis metal and for the production of pulverous aluminium-base alloys |
| FR1454200A (fr) * | 1965-11-12 | 1966-07-22 | Gen Electric | Perfectionnements aux procédés pour le traitement de surfaces d'articles métalliques, et aux articles ainsi obtenus |
| US3447912A (en) * | 1967-11-02 | 1969-06-03 | Vitro Corp Of America | Sulfidation corrosion-resistant coating containing rare earth metal aluminides |
| FR1582301A (enrdf_load_stackoverflow) * | 1967-12-14 | 1969-09-26 | ||
| US3794511A (en) * | 1971-10-22 | 1974-02-26 | Avco Corp | Coating process for a superalloy article |
| FR2244011A1 (enrdf_load_stackoverflow) * | 1973-09-19 | 1975-04-11 | Rolls Royce | |
| JPS55104472A (en) * | 1979-02-01 | 1980-08-09 | Hitachi Zosen Corp | Grate material for garbage incinerating furnace, etc. |
-
1981
- 1981-08-14 FR FR8115751A patent/FR2511396A1/fr active Granted
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2097024A (en) * | 1935-11-05 | 1937-10-26 | Enders Walter | Production of a protective layer on iron |
| GB798853A (en) * | 1954-05-31 | 1958-07-30 | Siemens Planiawerke Ag | Improvements in or relating to processes for depositing coatings of aluminium or of aluminium-base alloys on a basis metal and for the production of pulverous aluminium-base alloys |
| FR1454200A (fr) * | 1965-11-12 | 1966-07-22 | Gen Electric | Perfectionnements aux procédés pour le traitement de surfaces d'articles métalliques, et aux articles ainsi obtenus |
| US3447912A (en) * | 1967-11-02 | 1969-06-03 | Vitro Corp Of America | Sulfidation corrosion-resistant coating containing rare earth metal aluminides |
| FR1582301A (enrdf_load_stackoverflow) * | 1967-12-14 | 1969-09-26 | ||
| US3794511A (en) * | 1971-10-22 | 1974-02-26 | Avco Corp | Coating process for a superalloy article |
| FR2244011A1 (enrdf_load_stackoverflow) * | 1973-09-19 | 1975-04-11 | Rolls Royce | |
| JPS55104472A (en) * | 1979-02-01 | 1980-08-09 | Hitachi Zosen Corp | Grate material for garbage incinerating furnace, etc. |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0159468A3 (en) * | 1984-04-25 | 1986-05-07 | Interatom Gesellschaft Mit Beschrankter Haftung | Exhaust gas catalyst support made of heat-resistant steel sheets containing aluminium and process for its production |
| EP0222241A1 (en) * | 1985-10-31 | 1987-05-20 | Air Products And Chemicals, Inc. | Deposition of titanium aluminides |
| US4698244A (en) * | 1985-10-31 | 1987-10-06 | Air Products And Chemicals, Inc. | Deposition of titanium aluminides |
| WO1997041275A1 (en) * | 1996-04-30 | 1997-11-06 | Westaim Technologies Inc. | Surface alloyed high temperature alloys |
| US6093260A (en) * | 1996-04-30 | 2000-07-25 | Surface Engineered Products Corp. | Surface alloyed high temperature alloys |
| US6268067B1 (en) | 1996-04-30 | 2001-07-31 | Surface Engineered Products Corporation | Surfaced alloyed high temperature alloys |
| US6503347B1 (en) | 1996-04-30 | 2003-01-07 | Surface Engineered Products Corporation | Surface alloyed high temperature alloys |
| WO1998020182A1 (en) * | 1996-11-08 | 1998-05-14 | Alon, Inc. | Aluminum-silicon diffusion coating |
| US6592941B1 (en) | 1996-11-08 | 2003-07-15 | Alon, Inc. | Aluminum and silicon diffusion coating |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2511396B1 (enrdf_load_stackoverflow) | 1983-10-28 |
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