FR2484428A1 - Compositions d'absorption a base de silice et de glycols et leur application a la fabrication d'articles en caoutchouc - Google Patents
Compositions d'absorption a base de silice et de glycols et leur application a la fabrication d'articles en caoutchouc Download PDFInfo
- Publication number
- FR2484428A1 FR2484428A1 FR8013395A FR8013395A FR2484428A1 FR 2484428 A1 FR2484428 A1 FR 2484428A1 FR 8013395 A FR8013395 A FR 8013395A FR 8013395 A FR8013395 A FR 8013395A FR 2484428 A1 FR2484428 A1 FR 2484428A1
- Authority
- FR
- France
- Prior art keywords
- sep
- silica
- pulverulent
- compositions
- peg
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 66
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 229920001971 elastomer Polymers 0.000 title claims abstract description 33
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 33
- 239000005060 rubber Substances 0.000 title claims abstract description 25
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 34
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 20
- 239000000945 filler Substances 0.000 claims abstract description 9
- 239000007787 solid Substances 0.000 claims abstract description 7
- 229940093476 ethylene glycol Drugs 0.000 claims abstract 4
- 239000000203 mixture Substances 0.000 claims description 66
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 238000004073 vulcanization Methods 0.000 abstract description 8
- 239000012190 activator Substances 0.000 abstract description 7
- 239000000470 constituent Substances 0.000 description 11
- 229920003048 styrene butadiene rubber Polymers 0.000 description 9
- 239000000806 elastomer Substances 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 239000002174 Styrene-butadiene Substances 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 235000021355 Stearic acid Nutrition 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000518 rheometry Methods 0.000 description 3
- 239000011115 styrene butadiene Substances 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- FIMHASWLGDDANN-UHFFFAOYSA-M methyl sulfate;tributyl(methyl)azanium Chemical compound COS([O-])(=O)=O.CCCC[N+](C)(CCCC)CCCC FIMHASWLGDDANN-UHFFFAOYSA-M 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- UDHXJZHVNHGCEC-UHFFFAOYSA-N Chlorophacinone Chemical compound C1=CC(Cl)=CC=C1C(C=1C=CC=CC=1)C(=O)C1C(=O)C2=CC=CC=C2C1=O UDHXJZHVNHGCEC-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229920002582 Polyethylene Glycol 600 Polymers 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052914 metal silicate Inorganic materials 0.000 description 1
- -1 natural or synthetic Substances 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000003763 resistance to breakage Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
- C09C1/30—Silicic acid
- C09C1/3063—Treatment with low-molecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/08—Ingredients agglomerated by treatment with a binding agent
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8013395A FR2484428A1 (fr) | 1980-06-17 | 1980-06-17 | Compositions d'absorption a base de silice et de glycols et leur application a la fabrication d'articles en caoutchouc |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8013395A FR2484428A1 (fr) | 1980-06-17 | 1980-06-17 | Compositions d'absorption a base de silice et de glycols et leur application a la fabrication d'articles en caoutchouc |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2484428A1 true FR2484428A1 (fr) | 1981-12-18 |
| FR2484428B1 FR2484428B1 (enrdf_load_stackoverflow) | 1983-10-21 |
Family
ID=9243180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8013395A Granted FR2484428A1 (fr) | 1980-06-17 | 1980-06-17 | Compositions d'absorption a base de silice et de glycols et leur application a la fabrication d'articles en caoutchouc |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2484428A1 (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2588874A1 (fr) * | 1985-10-18 | 1987-04-24 | Rhone Poulenc Chim Base | Procede d'obtention d'un comelange, ou melange-maitre a base de silice avec un polymere, produit ainsi obtenu et application au renforcement notamment des elastomeres |
| DE4116396A1 (de) * | 1991-05-18 | 1992-11-19 | Grace Gmbh | Modifizierte amorphe kieselsaeure, verfahren zu deren herstellung und antiblockingmittel |
| US5609679A (en) * | 1995-01-19 | 1997-03-11 | W. R. Grace & Co.-Conn. | Polyol-treated antiblocking aid |
-
1980
- 1980-06-17 FR FR8013395A patent/FR2484428A1/fr active Granted
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2588874A1 (fr) * | 1985-10-18 | 1987-04-24 | Rhone Poulenc Chim Base | Procede d'obtention d'un comelange, ou melange-maitre a base de silice avec un polymere, produit ainsi obtenu et application au renforcement notamment des elastomeres |
| DE4116396A1 (de) * | 1991-05-18 | 1992-11-19 | Grace Gmbh | Modifizierte amorphe kieselsaeure, verfahren zu deren herstellung und antiblockingmittel |
| EP0524386A3 (en) * | 1991-05-18 | 1993-04-14 | Grace Gmbh | Modified amorphous silica, process for the preparation thereof and antiblocking agent |
| AU649815B2 (en) * | 1991-05-18 | 1994-06-02 | Grace Gmbh | Modified amorphous silicic acid, process for its preparation and anti-blocking agent |
| US5609679A (en) * | 1995-01-19 | 1997-03-11 | W. R. Grace & Co.-Conn. | Polyol-treated antiblocking aid |
| DE19502629C2 (de) * | 1995-01-19 | 1998-11-05 | Grace Gmbh | Verwendung einer Zusammensetzung auf Basis von polyolbehandeltem Siliciumdioxid als Antiblockingmittel |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2484428B1 (enrdf_load_stackoverflow) | 1983-10-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| TP | Transmission of property | ||
| ST | Notification of lapse |