FR2464656A1 - Sugar-coated prods. and coating syrups - contg. sorbitol and sugar ester - Google Patents

Sugar-coated prods. and coating syrups - contg. sorbitol and sugar ester Download PDF

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FR2464656A1
FR2464656A1 FR8014208A FR8014208A FR2464656A1 FR 2464656 A1 FR2464656 A1 FR 2464656A1 FR 8014208 A FR8014208 A FR 8014208A FR 8014208 A FR8014208 A FR 8014208A FR 2464656 A1 FR2464656 A1 FR 2464656A1
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sucrester
sorbitol
syrup
sugar
parts
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French (fr)
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Renzo Cillario
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Ferrero SpA
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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/50—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
    • A23G3/54—Composite products, e.g. layered, coated, filled
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/343—Products for covering, coating, finishing, decorating
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00—Medicinal preparations characterised by special physical form
    • A61K9/20—Pills, tablets, discs, rods
    • A61K9/28—Dragees; Coated pills or tablets, e.g. with film or compression coating
    • A61K9/2806—Coating materials
    • A61K9/282—Organic compounds, e.g. fats
    • A61K9/2826—Sugars or sugar alcohols, e.g. sucrose; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G2200/00—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
    • A23G2200/06—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing beet sugar or cane sugar if specifically mentioned or containing other carbohydrates, e.g. starches, gums, alcohol sugar, polysaccharides, dextrin or containing high or low amount of carbohydrate

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Medicinal Chemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Confectionery (AREA)
  • Medicinal Preparation (AREA)

Abstract

Sugar-coated prods. and aq. coating syrups are claimed. The sugar-coated prods. comprise a core with an adherent coating, at least one layer of which comprises a mixt. of sorbitol (I) and a sugar ester (II). The syrups contain (I) and (II). The prods. are suitable for use in the confectionery and pharmaceutical industries. Combinations of (I) and (II) produce smooth compact white coatings without a granular mouth-feel. The coated prods. have a practically unlimited shelf-life when stored in sealed containers.

Description

La présente invention concerne les produits dragéifiés comprenant un noyau et un enrobage adhérent au noyau, dans lesquels au moins une couche de l'enrobage est constituée essentiellement par un sucre. Des produits de ce genre sont typiques des industries de la confiserie et des industries pharmaceutiques. The present invention relates to coated products comprising a core and a coating adhering to the core, in which at least one layer of the coating consists essentially of a sugar. Products of this kind are typical of the confectionery and pharmaceutical industries.

Le sucre est généralement le saccharose, très souvent en mélange avec des aromatisants, des agents de blanchiment ou des colorants. Sugar is usually sucrose, very often mixed with flavorings, bleaches or colors.

Dans de nombreux cas, la présence du saccharose n'est pas désirable, par exemple pour des raisons diététiques. On sait en outre que le saccharose est une substance cariogène, et on a déjà essayé dans la technique de le substituer par du sorbitol dans différents produits de confiserie. Par exemple, on a déjà proposé du chewinggum, dans lequel le composant gommeux est édulcoré avec du sorbitol. In many cases, the presence of sucrose is undesirable, for example for dietary reasons. We also know that sucrose is a cariogenic substance, and we have already tried in the art to substitute it with sorbitol in various confectionery products. For example, chewing gum has already been proposed, in which the gummy component is sweetened with sorbitol.

Cependant, on n'a jusqu'à présent jamais proposé de fa çon sérieuse l'utilisation du sorbitol à la place du saccharose dans l'enrobage des noyaux de produits dragéifiés. En fait, comme cela a été également confirmé par les expériences effectuées par la demanderesse, il n'a pas été possible, jusqu'à présent, d'obtenir avec le sorbitol un enrobage lisse, de structure homogène, dépourvu de granulosité et présentant un degré suffisant de sécheresse. D'autre part, on sait que le sorbitol présente une tendance importante à retenir de façon tenace l'humidité, et cette caractéristique rend difficile, et dans certains cas impossible, l'opération de bassinage qui est l'opération de base pour l'obtention de produits drégéifiés. However, the use of sorbitol in place of sucrose in the coating of sugar-coated product nuclei has never hitherto been seriously proposed. In fact, as has also been confirmed by the experiments carried out by the applicant, it has not been possible, until now, to obtain with sorbitol a smooth coating, of homogeneous structure, devoid of graininess and having a sufficient degree of drought. On the other hand, it is known that sorbitol exhibits a significant tendency to retain moisture tenaciously, and this characteristic makes it difficult, and in some cases impossible, the operation of drenching which is the basic operation for the production of sugar-coated products.

La présente invention se base sur la découverte que les inconvénients mentionnés ci-dessus peuvent être évités en utilisant du sorbitol mélangé avec un sucrester. The present invention is based on the discovery that the above-mentioned drawbacks can be avoided by using sorbitol mixed with a sucrester.

Les sucresters sont des esters du saccharose avec des acides gras en C14 - C18, comme en particulier les acides myristique, oléique, palmitique et stéarique. Grace à la présence de groupes fortement hydrophiles (saccharose) et de groupes lipophiles (un ou plusieurs radicaux d'acides gras), les sucresters présentent d'excellentes propriétés émulsifiantes et sont utilisés dans ce but également dans l'industrie alimentaire. En ce qui concerne la présente invention, il faut noter, cependant, que le sorbitol est soluble dans l'eau avec une très grande facilité, ce qui fait que la découverte ci-dessus est extrèmement surprenante. Sucesters are sucrose esters with C14 - C18 fatty acids, such as myristic, oleic, palmitic and stearic acids in particular. Thanks to the presence of highly hydrophilic groups (sucrose) and lipophilic groups (one or more fatty acid radicals), the sucresters have excellent emulsifying properties and are used for this purpose also in the food industry. With regard to the present invention, it should be noted, however, that sorbitol is water soluble with very great ease, so that the above finding is extremely surprising.

En conséquence, un des objets de l'invention consiste en un produit dragéifié comme défini auparavant, caractérisé en ce que le sucre est du sorbitol en mélange avec un sucrester. La proportion de sucrester peut varier de 1 à 8 parties en poids pour 100 parties en poids de sorbitol ; la proportion de 3 parties en poids étant tout à fait satisfaisante et donc préférée. Le sucrester est de préférence choisi parmi les palmitates et les stéarates de saccharose. Il est possible d'utiliser un mono-ester, ou un di-ester, ou de préférence un mélange de mono- et di-esters. Cependant, on peut utiliser avec avantage les sucresters du commerce comprenant un mélange de mono-, di- et tri-esters.Par exemple, des sucresters particulièrement appropriés disponibles sur le marché sont ceux commercialisés sous le nom de
WASAG-ESTERS, et en particulier ceux qui sont à base de palmitates et stéarates de saccharose. Parmi ces derniers le WASAG-ESTER 11, qui comprend environ 50% de mono-esters et environ 70% de stéarates, a donné d'excellents résultats, et on peut également utiliser avec avantage le WASAG-ESTER 7 qui comprend environ 70% de stéarates et environ 40% de mono-esters, ou le WASAG-ESTER 15 qui comprend environ 30% de stéarates et environ 70% de mono-esters.Consequently, one of the objects of the invention consists of a coated product as defined above, characterized in that the sugar is sorbitol in admixture with a sucrester. The proportion of sucrester can vary from 1 to 8 parts by weight per 100 parts by weight of sorbitol; the proportion of 3 parts by weight being entirely satisfactory and therefore preferred. The sucrester is preferably chosen from palmitates and sucrose stearates. It is possible to use a mono-ester, or a di-ester, or preferably a mixture of mono- and di-esters. However, commercially available sucresters comprising a mixture of mono-, di- and tri-esters can be used with advantage. For example, particularly suitable sucresters available on the market are those marketed under the name
WASAG-ESTERS, and in particular those based on sucrose palmitates and stearates. Among these, WASAG-ESTER 11, which comprises approximately 50% of mono-esters and approximately 70% of stearates, has given excellent results, and it is also possible to use with advantage WASAG-ESTER 7 which comprises approximately 70% of stearates and approximately 40% mono-esters, or WASAG-ESTER 15 which comprises approximately 30% stearates and approximately 70% mono-esters.

Comme on le sait, durant la dragéification l'enrobage est formé par couches successives. Dans le produit selon l'invention, la distribution du sucrester est homogène dans chaque couche individuelle formée de sorbitol en mélange avec le sucrester. Etant donné l'extrème minceur des couches, la distribution du sucrester est prati quement homogène dans toutes les couches ainsi formées. De toute façon, comme on le verra plus clairement dans la suite de la description, cette distribution dépend des modalités d'exécution du procédé de bassinage. As is known, during the coating, the coating is formed in successive layers. In the product according to the invention, the distribution of the sucrester is homogeneous in each individual layer formed of sorbitol in admixture with the sucrester. Given the extreme thinness of the layers, the distribution of the sucrester is practically homogeneous in all the layers thus formed. In any case, as will be seen more clearly in the following description, this distribution depends on the methods of execution of the drenching process.

Un autre objet de l'invention consiste en un sirop aqueux pour la production de produits dragéifiés par bassinage, ce sirop aqueux étant caractérisé par le fait qu'il contient du sorbitol et un sucrester. Les caractéristiques préférées du sirop sont celles déjà indiquées pour le produit fini. Bien entendu, outre le sorbitol et le sucrester, le sirop peut également contenir des substances aromatisantes, des agents gustatifs (par exemple l'acide citrique ou tartrique), des épaississants, des colorants ou des agents de blanchiment. Another subject of the invention consists of an aqueous syrup for the production of coated sugar-coated products, this aqueous syrup being characterized in that it contains sorbitol and a sucrester. The preferred characteristics of the syrup are those already indicated for the finished product. Of course, in addition to sorbitol and the sucrester, the syrup can also contain flavoring substances, taste agents (for example citric or tartaric acid), thickeners, colorants or bleaching agents.

la substance de blanchiment typique est l'amidon de riz, généralement utilisé en proportions de 2-10 Kg pour 100 Kg de sorbitol. Cependant, il est préférable de ne pas inclure l'agent de blanchiment dans le sirop, mais de l'appliquer au contraire sous forme de poudre sèche, de préférence en mélange avec du sorbitol anhydre en poudre (sorbitol glace) dans des étapes interposées entre les étapes de pulvérisation du sirop dans la bassine, comme on le verra par la suite. La poudre sèche, à utiliser dans ces étapes intercalaires de "saupoudrage", peut contenir de 70% à 100% de sorbitol anhydre et, de façon correspondante, de 30% à 0% d'amidon de riz, les proportions préférées étant respectivement de 90% et 10%.the typical bleaching substance is rice starch, generally used in proportions of 2-10 kg per 100 kg of sorbitol. However, it is preferable not to include the bleaching agent in the syrup, but on the contrary to apply it in the form of a dry powder, preferably in admixture with anhydrous sorbitol powder (sorbitol ice) in stages interposed between the steps of spraying the syrup into the basin, as we will see later. The dry powder, to be used in these intermediate "dusting" steps, may contain from 70% to 100% anhydrous sorbitol and, correspondingly, from 30% to 0% of rice starch, the preferred proportions being respectively 90% and 10%.

Un objet ultérieur de l'invention consiste en un procédé pour la fabrication de produits dragéifiés par bassinage, qui comprend une pluralité d'étapes de pulvérisation avec un sirop aqueux contenant un sucre, caractérisé en ce que le sucre est constitué par du sorbitol et que le sirop contient en outre une faible proportion, par rapport au sorbitol, d'un sucrester. De préférence, le sucrester et ses proportions relatives sont comme indiquées ci-dessus pour le produit. En outre, de préférence, le procédé selon l'invention est caractérisé en ce que entre les étapes de pulvérisation avec le sirop, on intercale des étapes de saupoudrage avec du sorbitol anhydre en poudre, avantageusement en mélange avec une quantité mineure d'amidon de riz comme agent de blanchiment.De préférence encore, pour chaque étape de saupoudrage on utilise une quantité de sorbitol, ou de mélange de sorbitol et d'amidon, correspondant à environ la moitié de la quantité de matière sèche du sirop pulvérisé dans l'étape précédente de pulvérisation. En général, le rapport en poids entre "la matière sèche pulvérisée" dans une étape et "la matière sèche de saupoudrage" dans l'étape successive peut varier entre environ 4:1 et environ 1:1. A further object of the invention consists in a process for the manufacture of coated sugar-coated products, which comprises a plurality of spraying steps with an aqueous syrup containing a sugar, characterized in that the sugar consists of sorbitol and that the syrup also contains a small proportion, relative to sorbitol, of a sucrester. Preferably, the sucrester and its relative proportions are as indicated above for the product. In addition, preferably, the method according to the invention is characterized in that between the steps of spraying with the syrup, dusting steps are interspersed with anhydrous sorbitol powder, advantageously in admixture with a minor amount of starch from rice as a bleaching agent. Preferably again, for each dusting step, use an amount of sorbitol, or a mixture of sorbitol and starch, corresponding to approximately half the amount of dry matter of the syrup sprayed in the step. previous spray. In general, the weight ratio between "the dry matter sprayed" in one step and "the dry matter dusting" in the next step can vary between about 4: 1 and about 1: 1.

Exemple
On utilise une bassine ayant un diamètre de 45 cm, tournant autour d'un axe incliné de 30 par rapport à la verticale, à une vitesse de 47 tours/minute. On-introduit dans la bassine 1,9 Kg de noyaux à enrober, constitués par des comprimés cylindriques aux extrémités arrondies, ayant un diamètre de 5 mm et une longueur de 11 mm.Example
A basin having a diameter of 45 cm is used, rotating around an axis inclined by 30 with respect to the vertical, at a speed of 47 revolutions / minute. Was introduced into the basin 1.9 Kg of cores to be coated, consisting of cylindrical tablets with rounded ends, having a diameter of 5 mm and a length of 11 mm.

On prépare séparément un sirop composé de 100 parties en poids de sorbitol anhydre, 3 parties en poids de WASAG-ESTER 11, et 100 parties en poids d'eau. En général, on opère à 50-70 C, en dissolvant d'abord dans l'eau le sucrester, ensuite l'amidon éventuel, puis le sorbitol et enfin tous les éventuels ingrédients restants mentionnés dans la précédente description. Dans cet exemple, outre le sucrester et le sorbitol, on ajoute des arômes (environ 1% en poids). A syrup composed of 100 parts by weight of anhydrous sorbitol, 3 parts by weight of WASAG-ESTER 11 and 100 parts by weight of water is prepared separately. In general, the operation is carried out at 50-70 ° C., first dissolving the sugar ester in water, then the optional starch, then the sorbitol and finally all the possible remaining ingredients mentioned in the preceding description. In this example, in addition to the sucrester and sorbitol, flavorings (about 1% by weight) are added.

On prépare également un mélange de saupoudrage, formé de 90 parties en poids de sorbitol anhydre en poudre (maximum 50 microns) et 10 parties en poids d'amidon de riz. A dusting mixture is also prepared, consisting of 90 parts by weight of anhydrous sorbitol powder (maximum 50 microns) and 10 parts by weight of rice starch.

Le procédé de bassinage comprend 170 cycles constitués par les étapes suivantes
(a) - pulvérisation pendant 5 secondes avec 12 g de sirop à la température de 60-650C
(b) - homogénéisation pendant 90 secondes
(c) - saupoudrage pendant 5 secondes avec 3 g du mélange de saupoudrage
(d) - homogénéisation pendant 120 secondes avec de l'air à 30-350C ;
(e) - séchage pendant 180 secondes avec de l'air à 30-350C ;
(f) - pause pendant 20 secondes.The drenching process includes 170 cycles consisting of the following steps
(a) - spray for 5 seconds with 12 g of syrup at a temperature of 60-650C
(b) - homogenization for 90 seconds
(c) - dusting for 5 seconds with 3 g of the dusting mixture
(d) - homogenization for 120 seconds with air at 30-350C;
(e) - drying for 180 seconds with air at 30-350C;
(f) - pause for 20 seconds.

Lesdits 170 cycles sont suivis par 10 autres cycles, qui cependant ne comprennent pas les étapes (c) et (d), et le produit bassiné est ensuite séché à 30 C pendant 24 heures. Le poids du produit fini est d'environ 2,9 Kg. Said 170 cycles are followed by 10 other cycles, which however do not include steps (c) and (d), and the basified product is then dried at 30 ° C. for 24 hours. The weight of the finished product is approximately 2.9 Kg.

On n'éprouve aucune difficulté à effectuer le bassinage. Les dragées présentent un enrobage blanc, compact, dépourvu d'aspérités et ne comportant aucune granulosité qui puisse être notée dans la bouche durant la consommation. La période de conservation dans des récipients fermés est pratiquement illimitée. There is no difficulty in carrying out the drenching. The dragees have a white coating, compact, devoid of roughness and having no graininess which can be noted in the mouth during consumption. The storage period in closed containers is practically unlimited.

Claims (22)

REVENDICATIONS 1. Produit dragéifié comprenant un noyau recouvert par un enrobage adhérent au noyau, dans lequel au moins une couche de l'enrobage est constituée essentiellement par un sucre, caractérisé en ce que le sucre est du sorbitol en mélange avec un sucrester.1. Coated product comprising a core covered by a coating adhering to the core, in which at least one layer of the coating consists essentially of a sugar, characterized in that the sugar is sorbitol in admixture with a sucrester. 2. Produit dragéifié selon la revendication 1, caractérisé en ce que la proportion de sucrester est de 1 à 8 parties en poids pour 100 parties en poids de sorbitol.2. Coated product according to claim 1, characterized in that the proportion of sucrester is from 1 to 8 parts by weight per 100 parts by weight of sorbitol. 3. Produit dragéifié selon la revendication 1 ou 2, caractérisé en ce que le sucrester est choisi parmi les palmitates et stéarates de saccharose.3. Coated product according to claim 1 or 2, characterized in that the sucrester is chosen from palmitates and stearates of sucrose. 4. Produit dragéifié selon l'une quelconque des revendications précédentes, caractérisé en ce que le sucrester comprend un mélange de mono- et di-esters.4. Coated product according to any one of the preceding claims, characterized in that the sucrester comprises a mixture of mono- and di-esters. 5. Produit dragéifié selon l'une quelconque des revendications précédentes, caractérisé en ce que le sucrester est à base de palmitates et stéarates de saccharose et comprend environ 50% de monoesters et environ 70% de stéarates.5. Coated product according to any one of the preceding claims, characterized in that the sucrester is based on palmitates and sucrose stearates and comprises approximately 50% of monoesters and approximately 70% of stearates. 6. Sirop aqueux pour la production de produits dragéifiés par bassinage, caractérisé en ce qu'il contient du sorbitol et un sucrester.6. Aqueous syrup for the production of coated sugar-coated products, characterized in that it contains sorbitol and a sucrester. 7. Sirop selon la revendication 6, caractérisé en ce que la proportion de sucrester est de 1 à 8 parties en poids pour 100 parties en poids de sorbitol.7. Syrup according to claim 6, characterized in that the proportion of sucrester is from 1 to 8 parts by weight per 100 parts by weight of sorbitol. 8. Sirop selon la revendication 6 ou 7, caractérisé en ce que le sucrester est choisi parmi les stéarates et palmitates de saccharose.8. Syrup according to claim 6 or 7, characterized in that the sucrester is chosen from sucrose stearates and palmitates. 9. Sirop selon l'une quelconque des revendications 6 à 8, caractérisé en ce que le sucrester comprend un mélange de mono- et di-esters.9. Syrup according to any one of claims 6 to 8, characterized in that the sucrester comprises a mixture of mono- and di-esters. 10. Sirop selon l'une quelconque des revendications 6 à 9, caractérisé en ce que le sucrester est à base de palmitates et stéarates de saccharose et comprend environ 50% de mono-esters et environ 70% de stéarates.10. Syrup according to any one of claims 6 to 9, characterized in that the sucrester is based on palmitates and sucrose stearates and comprises approximately 50% of mono-esters and approximately 70% of stearates. 11. Sirop selon l'une quelconque des revendications 6 à 10, caractérisé en ce qu'il contient environ 3 parties en poids de sucrester pour 100 parties en poids de sorbitol.11. Syrup according to any one of claims 6 to 10, characterized in that it contains approximately 3 parts by weight of sucrester per 100 parts by weight of sorbitol. 12. Sirop selon l'une quelconque des revendications 6 à 11, caractérisé en qu'il contient en outre un agent de blanchiment constitué par de l'amidon de riz.12. Syrup according to any one of claims 6 to 11, characterized in that it also contains a bleaching agent consisting of rice starch. 13. Procédé pour la production de produits dragéifiés par bassinage, qui comprend une pluralité d'étapes de pulvérisation à l'aide d'un sirop aqueux contenant un sucre, caractérisé en ce que le sucre est constitué par du sorbitol et que le sirop contient en outre une faible proportion (par rapport au sorbitol) dtun sucrester.13. Process for the production of coated sugar-coated products, which comprises a plurality of spraying steps using an aqueous syrup containing a sugar, characterized in that the sugar consists of sorbitol and that the syrup contains in addition a small proportion (compared to sorbitol) of a sucrester. 14. Procédé selon la revendication 13, caractérisé en ce que la proportion de suorester est de 1 à 8 parties en poids pour 100 parties en poids de sorbitol.14. Method according to claim 13, characterized in that the proportion of suorester is from 1 to 8 parts by weight per 100 parts by weight of sorbitol. 15. Procédé selon la revendication 13 ou 14, caractérisé en ce que le sucrester est choisi parmi les palmitates et stéarates de saccharose.15. The method of claim 13 or 14, characterized in that the sucrester is chosen from palmitates and stearates of sucrose. 16. Procédé selon l'une des revendications 13 à 15, caractérisé en ce que le sucrester comprend un mélange de mono- et di-esters.16. Method according to one of claims 13 to 15, characterized in that the sucrester comprises a mixture of mono- and di-esters. 17. Procédé selon l'une quelconque des revendications 13 à 16, caractérisé en ce que le sucrester est à base de palmitates et stéarates de saccharose et comprend environ 50% de mono-esters et environ 70% de stéarates.17. Method according to any one of claims 13 to 16, characterized in that the sucrester is based on palmitates and sucrose stearates and comprises approximately 50% of mono-esters and approximately 70% of stearates. 18. Procédé selon l'une quelconque des revendications 13 à 17, caractérisé en ce que le sirop comprend environ 3 parties en poids de sucrester pour 100 parties en poids de sorbitol.18. Method according to any one of claims 13 to 17, characterized in that the syrup comprises approximately 3 parts by weight of sucrester per 100 parts by weight of sorbitol. 19. Procédé selon l'une quelconque des revendications 13 à 18, caractérisé en ce que le sirop contient en outre un agent de blanchiment constitué par l'amidon de riz.19. Method according to any one of claims 13 to 18, characterized in that the syrup also contains a bleaching agent consisting of rice starch. 20. Procédé selon l'une quelconque des revendications 13 à 18, caractérisé en ce que l'on interpose entre les étapes de pulvéri sation avec ledit sirop des étapes de saupoudrage avec du sorbitol anhydre en poudre.20. A method according to any one of claims 13 to 18, characterized in that there is interposed between the stages of pulverization with said syrup of the steps of dusting with anhydrous sorbitol powder. 21. Procédé selon la revendication 20, caractérisé en ce que le sorbitol anhydre en poudre est en mélange avec une quantité mineure d'amidon de riz en poudre comme agent de blanchiment.21. The method of claim 20, characterized in that the anhydrous sorbitol powder is mixed with a minor amount of powdered rice starch as a bleaching agent. 22. Procédé selon la revendication 20 ou 21, caractérisé en ce que pour chaque étape de saupoudrage on utilise une quantité de sorbitol ou dudit mélange correspondant à environ la moitié du contenu en matière sèche du sirop pulvérisé durant l'étape précédente de pulvérisation. 22. The method of claim 20 or 21, characterized in that for each dusting step an amount of sorbitol or of said mixture is used corresponding to approximately half of the dry matter content of the syrup sprayed during the preceding spraying step.
FR8014208A 1979-09-12 1980-06-26 Sugar-coated prods. and coating syrups - contg. sorbitol and sugar ester Withdrawn FR2464656A1 (en)

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Cited By (9)

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Publication number Priority date Publication date Assignee Title
FR2486364A1 (en) * 1979-09-24 1982-01-15 Life Savers Inc CHEWING GUM AND OTHER CONFECTIONERY PRODUCTS CARRYING A SUGAR-FREE COATING AND THEIR PREPARATION
FR2522250A1 (en) * 1982-03-01 1983-09-02 Nabisco Brands Inc Applying sugar-free coating to chewing gum and sweets - by coating with aq. soln. of sweet hygroscopic cpd. and then with powder of the cpd.
EP0506251A1 (en) * 1991-03-28 1992-09-30 Wm. Wrigley Jr. Company Coated chewing gum product
EP0625311A1 (en) * 1993-05-17 1994-11-23 Roquette Frˬres Sugar-free, hard-coating-process and so obtained products
US5665406A (en) * 1992-03-23 1997-09-09 Wm. Wrigley Jr. Company Polyol coated chewing gum having improved shelf life and method of making
WO2006040144A1 (en) * 2004-10-15 2006-04-20 Südzucker Aktiengesellschaft Mannheim/Ochsenfurt Improved pan coating process
US20130323377A1 (en) * 2007-08-10 2013-12-05 Südzucker Aktiengesellschaft Mannheim/Ochsenfurt Rice starch in sugar free coatings
US10736334B2 (en) 2013-03-15 2020-08-11 Mars, Incorporated Hard panned coating and confection comprising the same
WO2020201393A1 (en) * 2019-04-05 2020-10-08 Südzucker AG Method for producing a confectionery product having a sugar-free coating

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IT1214875B (en) * 1984-06-21 1990-01-18 Ferrero Spa CONFECTED PRODUCT AND PROCEDURE FOR ITS MANUFACTURE

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FR1137104A (en) * 1955-11-28 1957-05-23 Process for coating products formed into a core, with a view to obtaining dragees and a new industrial product resulting therefrom
US3639564A (en) * 1970-11-16 1972-02-01 Yamanouchi Pharma Co Ltd Method of sugar coating tablets
FR2342668A1 (en) * 1976-03-05 1977-09-30 Ferrero & C Spa P COATED EDIBLE PRODUCT AND PROCESS FOR ITS PREPARATION

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DE2636152C2 (en) * 1976-08-11 1980-11-06 Arcana Chem.-Pharm. Fabrik Gmbh, Spittal, Drau (Oesterreich) Process for the production of coated tablets

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FR1137104A (en) * 1955-11-28 1957-05-23 Process for coating products formed into a core, with a view to obtaining dragees and a new industrial product resulting therefrom
US3639564A (en) * 1970-11-16 1972-02-01 Yamanouchi Pharma Co Ltd Method of sugar coating tablets
FR2342668A1 (en) * 1976-03-05 1977-09-30 Ferrero & C Spa P COATED EDIBLE PRODUCT AND PROCESS FOR ITS PREPARATION

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2486364A1 (en) * 1979-09-24 1982-01-15 Life Savers Inc CHEWING GUM AND OTHER CONFECTIONERY PRODUCTS CARRYING A SUGAR-FREE COATING AND THEIR PREPARATION
FR2522250A1 (en) * 1982-03-01 1983-09-02 Nabisco Brands Inc Applying sugar-free coating to chewing gum and sweets - by coating with aq. soln. of sweet hygroscopic cpd. and then with powder of the cpd.
EP0506251A1 (en) * 1991-03-28 1992-09-30 Wm. Wrigley Jr. Company Coated chewing gum product
US5665406A (en) * 1992-03-23 1997-09-09 Wm. Wrigley Jr. Company Polyol coated chewing gum having improved shelf life and method of making
EP0625311A1 (en) * 1993-05-17 1994-11-23 Roquette Frˬres Sugar-free, hard-coating-process and so obtained products
US5478593A (en) * 1993-05-17 1995-12-26 Roquette Freres Process of sugarless hard coating and products obtained therefrom
FR2705207A1 (en) * 1993-05-17 1994-11-25 Roquette Freres Hard coating process without sugar and products thus obtained.
WO2006040144A1 (en) * 2004-10-15 2006-04-20 Südzucker Aktiengesellschaft Mannheim/Ochsenfurt Improved pan coating process
EA010272B1 (en) * 2004-10-15 2008-08-29 Зюдцукер Акциенгезелльшафт Маннхайм/Окзенфурт Improved pan coating process
AU2005293743B2 (en) * 2004-10-15 2011-03-31 Sudzucker Aktiengesellschaft Mannheim/Ochsenfurt Improved pan coating process
US20130323377A1 (en) * 2007-08-10 2013-12-05 Südzucker Aktiengesellschaft Mannheim/Ochsenfurt Rice starch in sugar free coatings
US10736334B2 (en) 2013-03-15 2020-08-11 Mars, Incorporated Hard panned coating and confection comprising the same
WO2020201393A1 (en) * 2019-04-05 2020-10-08 Südzucker AG Method for producing a confectionery product having a sugar-free coating

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Publication number Publication date
IT7968801A0 (en) 1979-09-12
DE3024913A1 (en) 1981-04-09
IT1121023B (en) 1986-03-26

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