FR2449668A1 - One-step ester prepn. from prim. alcohol - by heating in presence of cupric cpd., pref. oxide or alcoholate, giving high yield and selectivity - Google Patents

One-step ester prepn. from prim. alcohol - by heating in presence of cupric cpd., pref. oxide or alcoholate, giving high yield and selectivity

Info

Publication number
FR2449668A1
FR2449668A1 FR7904926A FR7904926A FR2449668A1 FR 2449668 A1 FR2449668 A1 FR 2449668A1 FR 7904926 A FR7904926 A FR 7904926A FR 7904926 A FR7904926 A FR 7904926A FR 2449668 A1 FR2449668 A1 FR 2449668A1
Authority
FR
France
Prior art keywords
prim
cpd
alcohol
heating
high yield
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7904926A
Other languages
French (fr)
Other versions
FR2449668B1 (en
Inventor
Alain Forestiere
Gerard Leleu
Bernard Sillion
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7904926A priority Critical patent/FR2449668A1/en
Publication of FR2449668A1 publication Critical patent/FR2449668A1/en
Application granted granted Critical
Publication of FR2449668B1 publication Critical patent/FR2449668B1/fr
Granted legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Ester is prepd. of formula CHR1R2-CO-O-CH2-CHR1R2 (II) from a prim. alcohol of formula CHR1R2-CH2OH (I), by heating the later at 170-250 degrees C in the presence of an O2-contg. Cu II cpd., the reaction medium being kept in the liq. phase, where R1 and R2 and H, (cyclo)aliphatic or aromatic gp., or R1 and R2 are linked to form a ring, R1 and R2 together contg. >=5C. Process involves a single step, has very high selectivity and gives high yield (>=90%).
FR7904926A 1979-02-23 1979-02-23 One-step ester prepn. from prim. alcohol - by heating in presence of cupric cpd., pref. oxide or alcoholate, giving high yield and selectivity Granted FR2449668A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7904926A FR2449668A1 (en) 1979-02-23 1979-02-23 One-step ester prepn. from prim. alcohol - by heating in presence of cupric cpd., pref. oxide or alcoholate, giving high yield and selectivity

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7904926A FR2449668A1 (en) 1979-02-23 1979-02-23 One-step ester prepn. from prim. alcohol - by heating in presence of cupric cpd., pref. oxide or alcoholate, giving high yield and selectivity

Publications (2)

Publication Number Publication Date
FR2449668A1 true FR2449668A1 (en) 1980-09-19
FR2449668B1 FR2449668B1 (en) 1984-09-28

Family

ID=9222474

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7904926A Granted FR2449668A1 (en) 1979-02-23 1979-02-23 One-step ester prepn. from prim. alcohol - by heating in presence of cupric cpd., pref. oxide or alcoholate, giving high yield and selectivity

Country Status (1)

Country Link
FR (1) FR2449668A1 (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1480515A (en) * 1966-05-16 1967-05-12 Hydrierwerk Rodleben Veb Process for the manufacture of waxy esters from fatty alcohols, as well as products conforming to those obtained by the present process or similar process

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1480515A (en) * 1966-05-16 1967-05-12 Hydrierwerk Rodleben Veb Process for the manufacture of waxy esters from fatty alcohols, as well as products conforming to those obtained by the present process or similar process

Also Published As

Publication number Publication date
FR2449668B1 (en) 1984-09-28

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