FR2438054A1 - Procede de dedoublement optique de l'acide d,l-2-amino-4-methyl-phosphinobutyrique - Google Patents
Procede de dedoublement optique de l'acide d,l-2-amino-4-methyl-phosphinobutyriqueInfo
- Publication number
- FR2438054A1 FR2438054A1 FR7925384A FR7925384A FR2438054A1 FR 2438054 A1 FR2438054 A1 FR 2438054A1 FR 7925384 A FR7925384 A FR 7925384A FR 7925384 A FR7925384 A FR 7925384A FR 2438054 A1 FR2438054 A1 FR 2438054A1
- Authority
- FR
- France
- Prior art keywords
- amino
- methylphosphinobutyric acid
- acid
- acyl
- methylphosphinobutyric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002253 acid Substances 0.000 title abstract 3
- 230000003287 optical effect Effects 0.000 title abstract 2
- NIBLDNQQTIFBAI-UHFFFAOYSA-N 2-amino-4-methylphosphanylbutanoic acid Chemical compound CPCCC(N)C(O)=O NIBLDNQQTIFBAI-UHFFFAOYSA-N 0.000 abstract 3
- NIBLDNQQTIFBAI-BYPYZUCNSA-N CPCC[C@H](N)C(O)=O Chemical compound CPCC[C@H](N)C(O)=O NIBLDNQQTIFBAI-BYPYZUCNSA-N 0.000 abstract 3
- 241000187747 Streptomyces Species 0.000 abstract 3
- 241000228257 Aspergillus sp. Species 0.000 abstract 2
- 241000589516 Pseudomonas Species 0.000 abstract 2
- 230000000813 microbial effect Effects 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 241000228212 Aspergillus Species 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000008030 elimination Effects 0.000 abstract 1
- 238000003379 elimination reaction Methods 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P13/00—Preparation of nitrogen-containing organic compounds
- C12P13/04—Alpha- or beta- amino acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/14—Hydrolases (3)
- C12N9/78—Hydrolases (3) acting on carbon to nitrogen bonds other than peptide bonds (3.5)
- C12N9/80—Hydrolases (3) acting on carbon to nitrogen bonds other than peptide bonds (3.5) acting on amide bonds in linear amides (3.5.1)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Zoology (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Genetics & Genomics (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Molecular Biology (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- General Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12039078A JPS5547630A (en) | 1978-10-02 | 1978-10-02 | Optical resolution of phosphorus-containing amino acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2438054A1 true FR2438054A1 (fr) | 1980-04-30 |
| FR2438054B1 FR2438054B1 (enExample) | 1985-02-15 |
Family
ID=14785011
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7925384A Granted FR2438054A1 (fr) | 1978-10-02 | 1979-09-27 | Procede de dedoublement optique de l'acide d,l-2-amino-4-methyl-phosphinobutyrique |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS5547630A (enExample) |
| DE (1) | DE2939269C2 (enExample) |
| FR (1) | FR2438054A1 (enExample) |
| GB (1) | GB2031896B (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0054897A3 (en) * | 1980-12-23 | 1982-09-08 | Hoechst Aktiengesellschaft | Process for the enzymatic preparation of l-2-amino-4-methyl-phosphino-butyric acid |
| EP0301391A1 (de) * | 1987-07-25 | 1989-02-01 | Hoechst Aktiengesellschaft | Verbessertes Verfahren zur enzymatischen Herstellung von L-2-Amino-4-methylphosphino-buttersäure |
| EP0374651A1 (de) * | 1988-12-14 | 1990-06-27 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung von L-Phosphinothricin |
| EP0382113A1 (de) * | 1989-02-06 | 1990-08-16 | Hoechst Schering AgrEvo GmbH | Verfahren zur enzymatischen Trennung von 2-Amino-4-methylphosphinobuttersäurederivaten |
| EP0499376A1 (en) * | 1991-01-31 | 1992-08-19 | Hoechst Celanese Corporation | Precipitation-induced asymmetric transformation of chiral alpha-amino acids and salts thereof |
| WO1997041214A1 (en) * | 1996-04-25 | 1997-11-06 | Novartis Ag | Biocatalysts with amine acylase activity |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59219297A (ja) * | 1983-05-27 | 1984-12-10 | Meiji Seika Kaisha Ltd | 光学活性な〔(3−アミノ−3−カルボキシ)プロピル−1〕−ホスフイン酸誘導体の製造法 |
| DE3544376A1 (de) * | 1985-12-14 | 1987-06-19 | Hoechst Ag | Dipeptide mit c-terminalem phosphinothricin, verfahren zu ihrer herstellung und ihre verwendung zur bekaempfung unerwuenschten pflanzenwuchses |
| DE3817191A1 (de) * | 1988-05-20 | 1989-11-30 | Hoechst Ag | Verfahren zur racemisierung von optisch aktiver d-2-n-phenacetylamino-4- methylphosphinobuttersaeure |
| DE4422045A1 (de) * | 1994-06-26 | 1996-01-04 | Hoechst Schering Agrevo Gmbh | Verfahren zur enzymatischen Spaltung von 2-Amino-4-methylphosphinobutansäureamid-Derivaten |
| DE19933362A1 (de) * | 1999-07-20 | 2001-02-08 | Aventis Cropscience Gmbh | Verfahren zur Herstellung von L-Aminosäuren aus ihren racemischen N-Acetyl-D,L-Derivaten durch enzymatische Racemat-Spaltung mittels isolierter, rekombinanter Enzyme |
| PT1481068E (pt) * | 2002-02-26 | 2011-05-09 | Syngenta Ltd | M?todo para produzir selectivamente plantas andro- ou gino-est?reis |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3816254A (en) * | 1970-02-03 | 1974-06-11 | Tanabe Seiyaku Co | Optical resolution of racemic amino acids |
| FR2246519A1 (enExample) * | 1973-09-28 | 1975-05-02 | Denki Kagaku Kogyo Kk | |
| FR2352827A1 (fr) * | 1976-05-26 | 1977-12-23 | Rhone Poulenc Ind | Complexes support-aminoacylase |
-
1978
- 1978-10-02 JP JP12039078A patent/JPS5547630A/ja active Granted
-
1979
- 1979-09-25 GB GB7933176A patent/GB2031896B/en not_active Expired
- 1979-09-27 FR FR7925384A patent/FR2438054A1/fr active Granted
- 1979-09-28 DE DE2939269A patent/DE2939269C2/de not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3816254A (en) * | 1970-02-03 | 1974-06-11 | Tanabe Seiyaku Co | Optical resolution of racemic amino acids |
| FR2246519A1 (enExample) * | 1973-09-28 | 1975-05-02 | Denki Kagaku Kogyo Kk | |
| FR2352827A1 (fr) * | 1976-05-26 | 1977-12-23 | Rhone Poulenc Ind | Complexes support-aminoacylase |
Non-Patent Citations (2)
| Title |
|---|
| CA1969 * |
| CA1980 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0054897A3 (en) * | 1980-12-23 | 1982-09-08 | Hoechst Aktiengesellschaft | Process for the enzymatic preparation of l-2-amino-4-methyl-phosphino-butyric acid |
| EP0301391A1 (de) * | 1987-07-25 | 1989-02-01 | Hoechst Aktiengesellschaft | Verbessertes Verfahren zur enzymatischen Herstellung von L-2-Amino-4-methylphosphino-buttersäure |
| EP0374651A1 (de) * | 1988-12-14 | 1990-06-27 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung von L-Phosphinothricin |
| US5587319A (en) * | 1988-12-14 | 1996-12-24 | Hoechst Aktiengesellschaft | Process for the preparation of L-phosphinothricin using transaminases of different specificities in a linked process |
| EP0382113A1 (de) * | 1989-02-06 | 1990-08-16 | Hoechst Schering AgrEvo GmbH | Verfahren zur enzymatischen Trennung von 2-Amino-4-methylphosphinobuttersäurederivaten |
| US5756800A (en) * | 1989-02-06 | 1998-05-26 | Hoechst Aktiengesellschaft | Process for the enzymatic resolution of 2-amino-4-methyl-phosphinobutyric acid derivatives |
| EP0499376A1 (en) * | 1991-01-31 | 1992-08-19 | Hoechst Celanese Corporation | Precipitation-induced asymmetric transformation of chiral alpha-amino acids and salts thereof |
| WO1997041214A1 (en) * | 1996-04-25 | 1997-11-06 | Novartis Ag | Biocatalysts with amine acylase activity |
| US6235516B1 (en) | 1996-04-25 | 2001-05-22 | Novartis Ag | Biocatalysts with amine acylase activity |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2939269A1 (de) | 1980-04-30 |
| FR2438054B1 (enExample) | 1985-02-15 |
| GB2031896A (en) | 1980-04-30 |
| JPS5547630A (en) | 1980-04-04 |
| GB2031896B (en) | 1983-03-23 |
| JPS6247520B2 (enExample) | 1987-10-08 |
| DE2939269C2 (de) | 1982-07-08 |
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