FR2430417A1 - Procede de production de mercaptans - Google Patents

Procede de production de mercaptans

Info

Publication number
FR2430417A1
FR2430417A1 FR7917128A FR7917128A FR2430417A1 FR 2430417 A1 FR2430417 A1 FR 2430417A1 FR 7917128 A FR7917128 A FR 7917128A FR 7917128 A FR7917128 A FR 7917128A FR 2430417 A1 FR2430417 A1 FR 2430417A1
Authority
FR
France
Prior art keywords
mercaptans
reaction
agents
acetophenones
agriculture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7917128A
Other languages
English (en)
Other versions
FR2430417B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pennwalt Corp
Original Assignee
Pennwalt Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pennwalt Corp filed Critical Pennwalt Corp
Publication of FR2430417A1 publication Critical patent/FR2430417A1/fr
Application granted granted Critical
Publication of FR2430417B1 publication Critical patent/FR2430417B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C07C319/04Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by addition of hydrogen sulfide or its salts to unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14The ring being saturated
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00Systems containing two condensed rings
    • C07C2602/36Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/42Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S204/00Chemistry: electrical and wave energy
    • Y10S204/902Production of desired compound by wave energy in presence of a chemically designated nonreactant chemical treating agent, excluding water, chloroform, carbon tetrachloride, methylene chloride or benzene
    • Y10S204/912Oxygen treating agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

L'invention concerne la production de mercaptans par réaction d'un hydrocarbure à insaturation éthylénique avec l'hydrogène sulfuré, utilisé en excès molaire, sous l'effet catalytique des rayons ultraviolets, le mercaptan désiré étant recueilli dans le mélange réactionnel. La réaction est perfectionnée par sa conduite en présence d'une quantité efficace d'activateur choisi dans la classe des acétophénones. On obtient ainsi de bien plus grandes vitesses de réaction. Les mercaptans obtenus par le procédé de l'invention ont de très nombreuses applications industrielles, par exemple dans le domaine des adhésifs, des agents chimiques pour l'agriculture, des agents de terminaison et de transfert de chaînes de polymères et des additifs de réticulation.
FR7917128A 1978-07-03 1979-07-02 Procede de production de mercaptans Granted FR2430417A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/921,693 US4140604A (en) 1978-07-03 1978-07-03 Process for preparing mercaptans

Publications (2)

Publication Number Publication Date
FR2430417A1 true FR2430417A1 (fr) 1980-02-01
FR2430417B1 FR2430417B1 (fr) 1983-12-09

Family

ID=25445834

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7917128A Granted FR2430417A1 (fr) 1978-07-03 1979-07-02 Procede de production de mercaptans

Country Status (13)

Country Link
US (1) US4140604A (fr)
JP (1) JPS559087A (fr)
AR (1) AR223978A1 (fr)
BE (1) BE877402A (fr)
BR (1) BR7904192A (fr)
CA (1) CA1118712A (fr)
DE (1) DE2926887C2 (fr)
ES (1) ES482114A1 (fr)
FR (1) FR2430417A1 (fr)
GB (1) GB2024819B (fr)
IT (1) IT1120460B (fr)
MX (1) MX151516A (fr)
NL (1) NL7905129A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2823206A1 (fr) * 2001-04-05 2002-10-11 Atofina Procede photochimique semi-continu et dispositif pour sa mise en oeuvre
US10239040B2 (en) 2013-02-04 2019-03-26 Chevron Phillips Chemical Company Lp Flow reactor vessels and reactor systems

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2608599B1 (fr) * 1986-12-17 1989-03-31 Elf Aquitaine Synthese de dithiols
FR2627184B1 (fr) * 1988-02-17 1990-07-13 Elf Aquitaine Procede de preparation de dithiols
FR2866024A1 (fr) * 2004-02-06 2005-08-12 Arkema Procede de fabrication de dodecylmercaptans.
CN101535245A (zh) * 2006-10-17 2009-09-16 巴斯夫欧洲公司 将h2s加成到萜烯上以制备用于自由基聚合的新型分子量调节剂的方法
CN101704772B (zh) * 2009-11-19 2013-07-31 郑州大学 一种异丙硫醇的制备方法
US8461293B2 (en) 2010-08-03 2013-06-11 Chevron Phillips Chemical Company Lp Methods of mercaptanizing olefinic hydrocarbons and compositions produced therefrom
US20140131618A1 (en) 2012-11-15 2014-05-15 Chevron Phillips Chemical Company Lp Methods of Mercaptanizing Unsaturated Compounds and Compositions Produced Therefrom
US9522975B2 (en) 2015-01-29 2016-12-20 Chevron Phillips Chemical Company Lp Mercaptanized vinylnorbornene compositions and methods of making same
US9447481B1 (en) 2015-10-07 2016-09-20 Chevron Phillips Chemical Company Lp Dipentene dimercaptan compositions and use thereof as a mining chemical collector
US10189779B2 (en) * 2016-09-12 2019-01-29 Chevron Phillips Chemical Company, Lp Methods for producing thiol compounds and sulfide compounds using diphenylamine or a phenol compound
EP3992180A1 (fr) * 2020-10-29 2022-05-04 Chevron Phillips Chemical Company LP Procédés de production de composés thiols et de composés sulfures à l'aide de diphénylamine ou d'un composé phénol mono-alkyle

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3682804A (en) * 1969-11-13 1972-08-08 Dow Chemical Co Method of preparing mercaptans using high energy radiation

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2398481A (en) * 1942-02-23 1946-04-16 Shell Dev Process for catalyzed abnormal addition reactions
US3050452A (en) * 1960-08-08 1962-08-21 Phillips Petroleum Co Preparation of organic sulfur compounds
US3248315A (en) * 1964-07-06 1966-04-26 Phillips Petroleum Co Thiol production
US4052283A (en) * 1974-12-23 1977-10-04 Hooker Chemicals & Plastics Corporation Sensitized production of sulfhydryl compounds using ultraviolet radiation
FR2424907A1 (fr) * 1978-05-05 1979-11-30 Elf Aquitaine Perfectionnement a la synthese de mercaptans

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3682804A (en) * 1969-11-13 1972-08-08 Dow Chemical Co Method of preparing mercaptans using high energy radiation

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2823206A1 (fr) * 2001-04-05 2002-10-11 Atofina Procede photochimique semi-continu et dispositif pour sa mise en oeuvre
WO2002081080A1 (fr) * 2001-04-05 2002-10-17 Atofina Procede photochimique semi-continu et dispositif pour sa mise en oeuvre
US10239040B2 (en) 2013-02-04 2019-03-26 Chevron Phillips Chemical Company Lp Flow reactor vessels and reactor systems

Also Published As

Publication number Publication date
MX151516A (es) 1984-12-06
BR7904192A (pt) 1980-03-25
NL7905129A (nl) 1980-01-07
BE877402A (fr) 1979-11-05
DE2926887A1 (de) 1980-01-24
CA1118712A (fr) 1982-02-23
JPS559087A (en) 1980-01-22
DE2926887C2 (de) 1988-05-26
US4140604A (en) 1979-02-20
GB2024819B (en) 1982-07-28
IT1120460B (it) 1986-03-26
IT7949573A0 (it) 1979-06-28
ES482114A1 (es) 1980-04-01
AR223978A1 (es) 1981-10-15
GB2024819A (en) 1980-01-16
FR2430417B1 (fr) 1983-12-09
JPH024589B2 (fr) 1990-01-29

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Legal Events

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ST Notification of lapse