FR2421162A1 - Conversion catalytique du toluene en phenol et formaldehyde - Google Patents
Conversion catalytique du toluene en phenol et formaldehydeInfo
- Publication number
- FR2421162A1 FR2421162A1 FR7907648A FR7907648A FR2421162A1 FR 2421162 A1 FR2421162 A1 FR 2421162A1 FR 7907648 A FR7907648 A FR 7907648A FR 7907648 A FR7907648 A FR 7907648A FR 2421162 A1 FR2421162 A1 FR 2421162A1
- Authority
- FR
- France
- Prior art keywords
- formaldehyde
- toluene
- phenol
- catalytic conversion
- dithiosemibenzil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 title abstract 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title abstract 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title abstract 3
- 230000003197 catalytic effect Effects 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 title 1
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 abstract 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 2
- IPBVNPXQWQGGJP-UHFFFAOYSA-N acetic acid phenyl ester Natural products CC(=O)OC1=CC=CC=C1 IPBVNPXQWQGGJP-UHFFFAOYSA-N 0.000 abstract 1
- BPGDAMSIGCZZLK-UHFFFAOYSA-N acetyloxymethyl acetate Chemical compound CC(=O)OCOC(C)=O BPGDAMSIGCZZLK-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229940049953 phenylacetate Drugs 0.000 abstract 1
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 abstract 1
- 230000001131 transforming effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/54—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of compounds containing doubly bound oxygen atoms, e.g. esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/36—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in compounds containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/035—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with saturated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/890,180 US4156783A (en) | 1978-03-27 | 1978-03-27 | Conversion of benzylidene diacetate to phenyl acetate and methylene diacetate |
| US94574778A | 1978-09-25 | 1978-09-25 | |
| US05/957,273 US4260808A (en) | 1978-11-03 | 1978-11-03 | Catalytic process for the conversion of toluene to equimolar amounts of phenol acetate and methylene diacetate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2421162A1 true FR2421162A1 (fr) | 1979-10-26 |
| FR2421162B1 FR2421162B1 (enrdf_load_stackoverflow) | 1983-01-28 |
Family
ID=27420538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7907648A Granted FR2421162A1 (fr) | 1978-03-27 | 1979-03-27 | Conversion catalytique du toluene en phenol et formaldehyde |
Country Status (7)
| Country | Link |
|---|---|
| JP (3) | JPS54130510A (enrdf_load_stackoverflow) |
| CA (1) | CA1146966A (enrdf_load_stackoverflow) |
| DE (1) | DE2912098A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2421162A1 (enrdf_load_stackoverflow) |
| GB (1) | GB2017098B (enrdf_load_stackoverflow) |
| IT (1) | IT1113044B (enrdf_load_stackoverflow) |
| NL (1) | NL7902258A (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2015119167A1 (ja) * | 2014-02-07 | 2017-03-23 | 住友化学株式会社 | 触媒、及び酸化生成物の製造方法 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU321518A1 (ru) * | В. В. Камзолкини Ю. А. ЛапицкийИнститут нефтехимического синтеза АН СССР | |||
| US1595299A (en) * | 1924-01-07 | 1926-08-10 | Dow Chemical Co | Manufacture of phenols |
| US2799698A (en) * | 1954-12-30 | 1957-07-16 | Hercules Powder Co Ltd | Oxidation of alkyl-substituted aromatic compounds to phenolic compounds |
| FR1489679A (fr) * | 1965-08-18 | 1967-07-21 | Ici Ltd | Procédé de production de composés organiques contenant de l'oxygène |
| US3590081A (en) * | 1966-07-21 | 1971-06-29 | Asahi Chemical Ind | Process for the preparation and recovery of acetic anhydride |
| FR2068133A5 (en) * | 1969-11-28 | 1971-08-20 | Inst Neftechimichesk | Preparation of phenyl esters and phenols |
| GB1244080A (en) * | 1969-12-02 | 1971-08-25 | Inst Neftechimicheskogo Sintez | Preparation of phenyl esters and phenols |
| FR2299303A1 (fr) * | 1975-01-31 | 1976-08-27 | Ube Industries | Procede pour la preparation de cyclohexanone et de phenol-alkyl-substitue ou non substitue |
| FR2440930A1 (fr) * | 1978-11-03 | 1980-06-06 | Suntech | Co-oxydation de methylbenzenes et de benzaldehyde |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1960520C3 (de) * | 1969-12-02 | 1974-04-25 | Institut Neftechimitscheskowo Sintesa Imeni A.W. Toptschijewa Akademii Nauk, Moskau | Verfahren zur Herstellung von Phenolen |
-
1979
- 1979-03-15 CA CA000323630A patent/CA1146966A/en not_active Expired
- 1979-03-20 GB GB7909740A patent/GB2017098B/en not_active Expired
- 1979-03-22 NL NL7902258A patent/NL7902258A/xx not_active Application Discontinuation
- 1979-03-24 JP JP3384579A patent/JPS54130510A/ja active Pending
- 1979-03-26 IT IT21301/79A patent/IT1113044B/it active
- 1979-03-27 DE DE2912098A patent/DE2912098A1/de active Granted
- 1979-03-27 FR FR7907648A patent/FR2421162A1/fr active Granted
-
1988
- 1988-02-25 JP JP63040906A patent/JPS6445339A/ja active Granted
- 1988-02-25 JP JP63040905A patent/JPS6445323A/ja active Granted
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU321518A1 (ru) * | В. В. Камзолкини Ю. А. ЛапицкийИнститут нефтехимического синтеза АН СССР | |||
| US1595299A (en) * | 1924-01-07 | 1926-08-10 | Dow Chemical Co | Manufacture of phenols |
| US2799698A (en) * | 1954-12-30 | 1957-07-16 | Hercules Powder Co Ltd | Oxidation of alkyl-substituted aromatic compounds to phenolic compounds |
| FR1489679A (fr) * | 1965-08-18 | 1967-07-21 | Ici Ltd | Procédé de production de composés organiques contenant de l'oxygène |
| US3590081A (en) * | 1966-07-21 | 1971-06-29 | Asahi Chemical Ind | Process for the preparation and recovery of acetic anhydride |
| FR2068133A5 (en) * | 1969-11-28 | 1971-08-20 | Inst Neftechimichesk | Preparation of phenyl esters and phenols |
| GB1244080A (en) * | 1969-12-02 | 1971-08-25 | Inst Neftechimicheskogo Sintez | Preparation of phenyl esters and phenols |
| FR2299303A1 (fr) * | 1975-01-31 | 1976-08-27 | Ube Industries | Procede pour la preparation de cyclohexanone et de phenol-alkyl-substitue ou non substitue |
| FR2440930A1 (fr) * | 1978-11-03 | 1980-06-06 | Suntech | Co-oxydation de methylbenzenes et de benzaldehyde |
Non-Patent Citations (1)
| Title |
|---|
| CA1972 * |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2017098B (en) | 1983-02-16 |
| JPS6445323A (en) | 1989-02-17 |
| DE2912098C2 (enrdf_load_stackoverflow) | 1989-03-23 |
| JPS6445339A (en) | 1989-02-17 |
| GB2017098A (en) | 1979-10-03 |
| NL7902258A (nl) | 1979-10-01 |
| IT1113044B (it) | 1986-01-20 |
| IT7921301A0 (it) | 1979-03-26 |
| JPS54130510A (en) | 1979-10-09 |
| FR2421162B1 (enrdf_load_stackoverflow) | 1983-01-28 |
| DE2912098A1 (de) | 1979-10-18 |
| CA1146966A (en) | 1983-05-24 |
| JPH036128B2 (enrdf_load_stackoverflow) | 1991-01-29 |
| JPH0260655B2 (enrdf_load_stackoverflow) | 1990-12-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |