FR2396099A1 - Zinc recovery from suspensions of zinc cpds. - by electrodeposition onto aluminium cathodes from sulphuric acid-contg. electrolytes - Google Patents
Zinc recovery from suspensions of zinc cpds. - by electrodeposition onto aluminium cathodes from sulphuric acid-contg. electrolytesInfo
- Publication number
- FR2396099A1 FR2396099A1 FR7719852A FR7719852A FR2396099A1 FR 2396099 A1 FR2396099 A1 FR 2396099A1 FR 7719852 A FR7719852 A FR 7719852A FR 7719852 A FR7719852 A FR 7719852A FR 2396099 A1 FR2396099 A1 FR 2396099A1
- Authority
- FR
- France
- Prior art keywords
- cpds
- zinc
- concn
- electrolyte
- suspensions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/16—Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
Zn is recovered by electrolysing a suspension of residual Zn cpds., such as froths and galvanising residues, Zn oxides or hydroxides from the chemical industry and from paints. The Zn is deposited on Al cathodes the anodes being made of a Pb-based alloy. The Zn cpds. are added continuously to the slurry to maintain the concn. of metals. The electrolyte is an aq. soln. of H2SO4 with a concn. of 5-25% an delectrolysis is carried out at a current density of 2.5-20 A/dm2 at 25-60 degrees C and with a Zn concn. in the electrolyte of 20-100 g/l. The Zn may be obtd. as a homogeneous sheet from these residues without dissolving the Zn cpds. separately e.g. by converting them into soluble salts. Thus avoiding filtration of these soln. Impurities e.g. Fe remaining in suspension can be opt. removed by decantation, sedimentation or filtering. Continuous operations can be achieved by adding Zn cpds. at predetermined intervals. The deposit has a high purity (99-99.8%). During melting higher efficiencies are achieved than with Zn deposit from alkaline suspensions. The electrolyte may be re-used several times.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7719852A FR2396099A1 (en) | 1977-06-28 | 1977-06-28 | Zinc recovery from suspensions of zinc cpds. - by electrodeposition onto aluminium cathodes from sulphuric acid-contg. electrolytes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7719852A FR2396099A1 (en) | 1977-06-28 | 1977-06-28 | Zinc recovery from suspensions of zinc cpds. - by electrodeposition onto aluminium cathodes from sulphuric acid-contg. electrolytes |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2396099A1 true FR2396099A1 (en) | 1979-01-26 |
FR2396099B1 FR2396099B1 (en) | 1982-12-17 |
Family
ID=9192686
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7719852A Granted FR2396099A1 (en) | 1977-06-28 | 1977-06-28 | Zinc recovery from suspensions of zinc cpds. - by electrodeposition onto aluminium cathodes from sulphuric acid-contg. electrolytes |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2396099A1 (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2023337A1 (en) * | 1968-11-11 | 1970-08-21 | Humphreys & Glasgow Ltd | |
US3905882A (en) * | 1974-09-25 | 1975-09-16 | Harold G Hudson | Electrolytic zinc salvaging method |
-
1977
- 1977-06-28 FR FR7719852A patent/FR2396099A1/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2023337A1 (en) * | 1968-11-11 | 1970-08-21 | Humphreys & Glasgow Ltd | |
US3905882A (en) * | 1974-09-25 | 1975-09-16 | Harold G Hudson | Electrolytic zinc salvaging method |
Non-Patent Citations (1)
Title |
---|
CA1976 * |
Also Published As
Publication number | Publication date |
---|---|
FR2396099B1 (en) | 1982-12-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |