FR2395944A1 - Procede d'adsorption/desorption pour la production d'hydrogene - Google Patents
Procede d'adsorption/desorption pour la production d'hydrogeneInfo
- Publication number
- FR2395944A1 FR2395944A1 FR7818985A FR7818985A FR2395944A1 FR 2395944 A1 FR2395944 A1 FR 2395944A1 FR 7818985 A FR7818985 A FR 7818985A FR 7818985 A FR7818985 A FR 7818985A FR 2395944 A1 FR2395944 A1 FR 2395944A1
- Authority
- FR
- France
- Prior art keywords
- stage
- adsorption
- hydrogen
- desorption process
- desorption
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000001257 hydrogen Substances 0.000 title abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000002336 sorption--desorption measurement Methods 0.000 title abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 238000000746 purification Methods 0.000 abstract 2
- 239000003463 adsorbent Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 238000011109 contamination Methods 0.000 abstract 1
- 238000003795 desorption Methods 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/048—Composition of the impurity the impurity being an organic compound
Abstract
L'invention concerne un procédé d'adsorption/désorption pour la production d'hydrogène à partir d'un gaz brut qui, en dehors de l'hydrogène, contient des traces d'impuretés fortement adsorba les et des constituants faiblement adsorbables en concentrations plus élevées, lequel procédé consiste à effectuer l'adsorption dans un premier stade de pré-purification VR et dans un second stade de purification principale HR, avec écoulement de l'hydrogène produit et régénération de l'adsorbant du premier stade par augmentation de la température et/ou lavage à la vapeur chaude, et désorption des gaz adsorbés dans le second stade par réduction de la pression, les deux stades étant soumis aux mêmes alternances de la pression, jusqu'à la contamination totale du premier stade.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2729558A DE2729558C3 (de) | 1977-06-30 | 1977-06-30 | Adsorptions/Desorptionsverfahren zur Gewinnung von Wasserstoff |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2395944A1 true FR2395944A1 (fr) | 1979-01-26 |
FR2395944B1 FR2395944B1 (fr) | 1982-03-19 |
Family
ID=6012799
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7818985A Granted FR2395944A1 (fr) | 1977-06-30 | 1978-06-26 | Procede d'adsorption/desorption pour la production d'hydrogene |
Country Status (9)
Country | Link |
---|---|
US (1) | US4432774A (fr) |
JP (1) | JPS5417392A (fr) |
BE (1) | BE868650A (fr) |
DE (1) | DE2729558C3 (fr) |
FR (1) | FR2395944A1 (fr) |
GB (1) | GB2001864B (fr) |
IT (1) | IT1105061B (fr) |
NL (1) | NL187802C (fr) |
ZA (1) | ZA783717B (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0008512A1 (fr) * | 1978-08-21 | 1980-03-05 | Air Products And Chemicals, Inc. | Séparation de mélanges gazeux à composants multiples |
EP0008882A1 (fr) * | 1978-08-21 | 1980-03-19 | Air Products And Chemicals, Inc. | Séparation de mélanges gazeux à composants multiples par adsorption sous pression alternée |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3122701A1 (de) * | 1981-06-06 | 1982-12-23 | Bergwerksverband Gmbh, 4300 Essen | Verfahren zur trennung von gasgemischen mittels druckwechseltechnik |
DE3206516C2 (de) * | 1982-02-24 | 1984-07-05 | Didier Engineering Gmbh, 4300 Essen | Verfahren zur Erzeugung von Ammoniak-Synthesegas |
JPS58190801A (ja) * | 1982-04-28 | 1983-11-07 | Kansai Coke & Chem Co Ltd | コ−クス炉ガスからの高純度水素回収方法 |
US4696680A (en) * | 1985-10-03 | 1987-09-29 | The United States Of America As Represented By The United States Department Of Energy | Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption |
US5163980A (en) * | 1991-10-22 | 1992-11-17 | Kovach J Louis | Water removal from humid gases laden with organic contaminants by series adsorption |
US5403385A (en) * | 1994-02-08 | 1995-04-04 | Alberta Research Council | Serial flow pressure swing adsorption process for gas separation |
JP3462560B2 (ja) * | 1994-03-04 | 2003-11-05 | 日本パイオニクス株式会社 | 水素ガスの精製方法 |
KR970008347B1 (ko) * | 1994-04-12 | 1997-05-23 | 한국에너지기술연구소 | 암모니아 퍼지가스에서 아르곤 및 수소를 고농도로 분리하는 흡착분리방법과 그 장치 |
US5669960A (en) * | 1995-11-02 | 1997-09-23 | Praxair Technology, Inc. | Hydrogen generation process |
FR2758739B1 (fr) * | 1997-01-24 | 1999-02-26 | Ceca Sa | Perfectionnement dans les procedes psa de purification de l'hydrogene |
US20080202590A1 (en) * | 2007-02-24 | 2008-08-28 | Woodward Governor Company | High Efficiency Valve Geometry For Pressure Regulator |
CN116983795A (zh) * | 2023-07-28 | 2023-11-03 | 山西沃能化工科技有限公司 | 一种乙二醇合成尾气制造燃料电池用氢气的装置及方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3150942A (en) * | 1959-10-19 | 1964-09-29 | Chemical Construction Corp | Method of purifying a hydrogen gas stream by passing said gas in series through 13x and 4a or 5a molecular sieves |
FR2070387A5 (fr) * | 1969-12-03 | 1971-09-10 | Air Liquide |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2340398A (en) * | 1942-03-21 | 1944-02-01 | Mathieson Alkali Works Inc | Chemical manufacture |
US2918140A (en) * | 1958-06-20 | 1959-12-22 | Sun Oil Co | Treatment of gas mixtures |
US3221476A (en) * | 1961-12-07 | 1965-12-07 | Chemical Design Inc | Adsorption-desorption method |
NL136381C (fr) * | 1962-02-26 | |||
US3252268A (en) * | 1963-04-01 | 1966-05-24 | Exxon Research Engineering Co | Gas separation by adsorption process |
US3225516A (en) * | 1963-04-15 | 1965-12-28 | C M Kemp Mfg Co | Method and apparatus for purifying gaseous mixtures by cyclic adsorption |
FR2097633A5 (fr) * | 1970-07-16 | 1972-03-03 | Air Liquide | |
DE2055425B2 (de) * | 1970-11-11 | 1979-09-06 | Bayer Ag, 5090 Leverkusen | Adsorptionsverfahren zum Zerlegen von Gasgemischen |
GB1449864A (en) * | 1973-10-24 | 1976-09-15 | Boc International Ltd | Adsorption system |
US3957463A (en) * | 1973-12-12 | 1976-05-18 | Air Products And Chemicals, Inc. | Oxygen enrichment process |
-
1977
- 1977-06-30 DE DE2729558A patent/DE2729558C3/de not_active Expired
-
1978
- 1978-06-26 FR FR7818985A patent/FR2395944A1/fr active Granted
- 1978-06-27 NL NLAANVRAGE7806926,A patent/NL187802C/xx not_active IP Right Cessation
- 1978-06-27 IT IT50059/78A patent/IT1105061B/it active
- 1978-06-28 ZA ZA00783717A patent/ZA783717B/xx unknown
- 1978-06-30 BE BE189000A patent/BE868650A/fr not_active IP Right Cessation
- 1978-06-30 GB GB7828450A patent/GB2001864B/en not_active Expired
- 1978-06-30 JP JP7882378A patent/JPS5417392A/ja active Granted
-
1979
- 1979-11-09 US US06/093,616 patent/US4432774A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3150942A (en) * | 1959-10-19 | 1964-09-29 | Chemical Construction Corp | Method of purifying a hydrogen gas stream by passing said gas in series through 13x and 4a or 5a molecular sieves |
FR2070387A5 (fr) * | 1969-12-03 | 1971-09-10 | Air Liquide |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0008512A1 (fr) * | 1978-08-21 | 1980-03-05 | Air Products And Chemicals, Inc. | Séparation de mélanges gazeux à composants multiples |
EP0008882A1 (fr) * | 1978-08-21 | 1980-03-19 | Air Products And Chemicals, Inc. | Séparation de mélanges gazeux à composants multiples par adsorption sous pression alternée |
Also Published As
Publication number | Publication date |
---|---|
DE2729558A1 (de) | 1979-01-04 |
US4432774A (en) | 1984-02-21 |
GB2001864A (en) | 1979-02-14 |
DE2729558B2 (de) | 1979-05-03 |
BE868650A (fr) | 1978-10-16 |
IT7850059A0 (it) | 1978-06-27 |
JPH0127961B2 (fr) | 1989-05-31 |
IT1105061B (it) | 1985-10-28 |
GB2001864B (en) | 1982-01-20 |
NL187802C (nl) | 1992-01-16 |
FR2395944B1 (fr) | 1982-03-19 |
JPS5417392A (en) | 1979-02-08 |
DE2729558C3 (de) | 1983-12-08 |
NL7806926A (nl) | 1979-01-03 |
ZA783717B (en) | 1979-09-26 |
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