FR2390450A1 - Procede de preparation de phenylphosphonate de diphenyle par transposition, de type arbuzov, du phosphite de triphenyle et nouveau produit ainsi obtenu - Google Patents
Procede de preparation de phenylphosphonate de diphenyle par transposition, de type arbuzov, du phosphite de triphenyle et nouveau produit ainsi obtenuInfo
- Publication number
- FR2390450A1 FR2390450A1 FR7813725A FR7813725A FR2390450A1 FR 2390450 A1 FR2390450 A1 FR 2390450A1 FR 7813725 A FR7813725 A FR 7813725A FR 7813725 A FR7813725 A FR 7813725A FR 2390450 A1 FR2390450 A1 FR 2390450A1
- Authority
- FR
- France
- Prior art keywords
- triphenyl phosphite
- transposition
- diphenyl phenylphosphonate
- new product
- preparing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 title abstract 8
- CDOMXXVCZQOOMT-UHFFFAOYSA-N [phenoxy(phenyl)phosphoryl]oxybenzene Chemical compound C=1C=CC=CC=1OP(C=1C=CC=CC=1)(=O)OC1=CC=CC=C1 CDOMXXVCZQOOMT-UHFFFAOYSA-N 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 230000017105 transposition Effects 0.000 title abstract 2
- YCOXTKKNXUZSKD-UHFFFAOYSA-N as-o-xylenol Natural products CC1=CC=C(O)C=C1C YCOXTKKNXUZSKD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- SNHMUERNLJLMHN-UHFFFAOYSA-N iodobenzene Chemical compound IC1=CC=CC=C1 SNHMUERNLJLMHN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910001507 metal halide Inorganic materials 0.000 abstract 1
- 150000005309 metal halides Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4021—Esters of aromatic acids (P-C aromatic linkage)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4084—Esters with hydroxyaryl compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procédé de préparation de phénylphosphonate de diphényle et nouveau produit ainsi obtenu. Ce procédé consiste à préparer un mélange réactionnel comprenant du phosphite de triphényle et des proportions peu importantes de chacun des produits constitués par un catalyseur, formé d'halogénure de métal ou de complexe de phosphite de métal, et de l'iodobenzène, et à chauffer ce mélange à une température au-dessus d'environ 200 degrés C, pour fournir une transposition, de type Arbuzov, du phosphite de triphényle. La présente invention est particulièrement utile pour fournir une transposition du phosphite de triphényle en phénylphosphonate de diphényle, avec un bon rendement.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/795,461 US4113807A (en) | 1977-05-10 | 1977-05-10 | Arbuzov rearrangement of triphenyl phosphite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2390450A1 true FR2390450A1 (fr) | 1978-12-08 |
| FR2390450B1 FR2390450B1 (fr) | 1980-11-07 |
Family
ID=25165561
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7813725A Granted FR2390450A1 (fr) | 1977-05-10 | 1978-05-09 | Procede de preparation de phenylphosphonate de diphenyle par transposition, de type arbuzov, du phosphite de triphenyle et nouveau produit ainsi obtenu |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4113807A (fr) |
| JP (1) | JPS53141248A (fr) |
| CA (1) | CA1093572A (fr) |
| DE (1) | DE2820390C2 (fr) |
| FR (1) | FR2390450A1 (fr) |
| GB (1) | GB1562785A (fr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2829710A1 (de) * | 1978-07-06 | 1980-01-17 | Bayer Ag | Verfahren zur herstellung von aromatischen phosphorverbindungen |
| DE3025377C2 (de) * | 1980-07-04 | 1983-06-23 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Benzolphosphonsäurediphenylester |
| CN111635431B (zh) * | 2020-07-02 | 2023-06-30 | 浙江万盛股份有限公司 | 一种苯基膦酸二苯酯的制备方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3257355A (en) * | 1961-06-01 | 1966-06-21 | Hooker Chemical Corp | Phosphorus containing polymers |
-
1977
- 1977-05-10 US US05/795,461 patent/US4113807A/en not_active Expired - Lifetime
-
1978
- 1978-05-01 CA CA302,334A patent/CA1093572A/fr not_active Expired
- 1978-05-05 GB GB18050/78A patent/GB1562785A/en not_active Expired
- 1978-05-08 JP JP5384978A patent/JPS53141248A/ja active Pending
- 1978-05-09 FR FR7813725A patent/FR2390450A1/fr active Granted
- 1978-05-10 DE DE2820390A patent/DE2820390C2/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CA1093572A (fr) | 1981-01-13 |
| FR2390450B1 (fr) | 1980-11-07 |
| GB1562785A (en) | 1980-03-19 |
| JPS53141248A (en) | 1978-12-08 |
| DE2820390A1 (de) | 1978-11-23 |
| US4113807A (en) | 1978-09-12 |
| DE2820390C2 (de) | 1983-04-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| TP | Transmission of property | ||
| ST | Notification of lapse |